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951.
952.
Summary This work describes the dynamic equilibrium of an ionpair, reverse-phase liquid chromatography system. A given adsorbed quantity of an anionic surfactant can lead to different capacity factors and selectivity for anionic solutes.This paper was presented as a poster-communication at the 7th International Symposium on Column Liquid Chromatography, Baden-Baden, May 3–6, 1983. 相似文献
953.
Julio Cárdenas-Rodríguez Christine M. Howison Terry O. Matsunaga Mark D. Pagel 《Magnetic resonance imaging》2013
Dynamic Contrast Enhancement (DCE) MRI has been used to measure the kinetic transport constant, Ktrans, which is used to assess tumor angiogenesis and the effects of anti-angiogenic therapies. Standard DCE MRI methods must measure the pharmacokinetics of a contrast agent in the blood stream, known as the Arterial Input Function (AIF), which is then used as a reference for the pharmacokinetics of the agent in tumor tissue. However, the AIF is difficult to measure in pre-clinical tumor models and in patients. Moreover the AIF is dependent on the Fahraeus effect that causes a highly variable hematocrit (Hct) in tumor microvasculature, leading to erroneous estimates of Ktrans. To overcome these problems, we have developed the Reference Agent Model (RAM) for DCE MRI analyses, which determines the relative Ktrans of two contrast agents that are simultaneously co-injected and detected in the same tissue during a single DCE-MRI session. The RAM obviates the need to monitor the AIF because one contrast agent effectively serves as an internal reference in the tumor tissue for the other agent, and it also eliminates the systematic errors in the estimated Ktrans caused by assuming an erroneous Hct. Simulations demonstrated that the RAM can accurately and precisely estimate the relative Ktrans (RKtrans) of two agents. To experimentally evaluate the utility of RAM for analyzing DCE MRI results, we optimized a previously reported multiecho 19F MRI method to detect two perfluorinated contrast agents that were co-injected during a single in vivo study and selectively detected in the same tumor location. The results demonstrated that RAM determined RKtrans with excellent accuracy and precision. 相似文献
954.
Dynamic mechanical properties of chlorinated butyl rubber blends 总被引:1,自引:0,他引:1
Cong Li 《European Polymer Journal》2006,42(10):2507-2514
The binary blends are prepared by chlorinated butyl rubber (CIIR) and 3,9-bis[1,1-dimethyl-2{β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy}ethyl]-2, 4, 8,10-tetraoxaspiro[5,5]-undecane (AO-80), which are investigated by dynamic mechanical analysis and thermal analysis. It is shown that CIIR/AO-80 blends clearly exhibit two kinds of relaxations, which are attributed to the relaxation of CIIR-rich matrix and AO-80-rich domains, respectively, and attenuated total reflection (ATR)-FTIR spectrum indicates that the existence of intermolecular hydrogen bonds between AO-80 and CIIR. When AO-80 is replaced by petroleum resins, only one loss peak appears, and the position of it is related to the softening point and the content of the petroleum resin. In order to regulate the damping property of CIIR/petroleum resin blend, the ternary blend of CIIR/petroleum resin/AO-80/is prepared and a second peak appears at higher temperature indicating that a good damping material is obtained. 相似文献
955.
David T.R. StewartMary Dawn Celiz Glorimar VicenteLuis A. Colón Diana S. Aga 《Trends in analytical chemistry : TRAC》2011,30(1):113-122
Quantum dot (QD) nanoparticles (NPs) are of great interest to various researchers due to their wide range of applications, from photovoltaic sensitizers to in vivo fluorescent probes. There is a need to characterize environmental fate, degradation, and ecotoxicity of QDs because these NPs may be introduced into the environment upon disposal of waste products containing QDs following the anticipated increase in their production and use. Because the properties of QDs are defined primarily by their composition and size, it is imperative that QD size be measured accurately and quickly. Current methods for measuring the size of QDs tend to be relatively slow, require large amounts of sample and may not be suitable for environmental or biological samples. Capillary zone electrophoresis (CZE), with its inherently high separation efficiency based on the size-to-charge ratio of analytes, holds promise for efficient size determination of NPs in aqueous samples.This review examines the potential use of CZE in characterizing and separating QDs compared to the conventional methods employed in determining size distribution of NPs. We briefly discuss the advantages and the limitations of commonly used techniques for size characterization.In addition to published literature, we present results from our laboratory using CZE with laser-induced fluorescence (LIF) to examine the effect of natural organic matter and buffer composition on the electrophoretic mobility of QDs. The use of CZE in environmental studies can provide insights into the degradation and the potential impacts of QDs upon exposure to environmental and biological matrices. 相似文献
956.
The object of this work is to simulate the dynamic fracture propagation in fibre-reinforced cementitious composites, in particular, in steel fibre reinforced concrete (SFRC). Beams loaded in a three-point bend configuration through a drop-weight impact device are considered. A single cohesive crack is assumed to propagate at the middle section; the opening of this crack is governed by a rate-dependent cohesive law; the fibres around the fracture plane are explicitly represented through truss elements. The fibre pull-out behaviour is depicted by an equivalent constitutive law, which is obtained from an analytical load–slip curve. The obtained load–displacement curves and crack propagation velocities are compared with their experimental counterparts. The good agreement with experimental data testifies to the feasibility of the proposed methodology and paves the way to its application in a multi-scale framework. 相似文献
957.
分别制备了不同磺酸基含量的磺化碱木质素(SAL)、不同交联度和分子量的磺化碱木质素聚氧乙烯醚(SAL-PEG),采用动态光散射(DLS)法分别研究磺酸基含量和PEG非离子长链对SAL和SAL-PEG溶液行为的影响规律.结果表明,不同磺酸基含量(1.28~2.09 mmol/g)的SAL在1.0 g/L的水溶液中存在聚集行为,磺酸基含量的增加使SAL的分子舒展程度增加,聚集程度越弱;Na Cl的加入使SAL的分子舒展程度减小,聚集体发生解聚.不同PEG含量的SAL-PEG在1.0 g/L的水溶液中主要以单分子状态存在,聚集行为较弱,分子的流体动力学半径与其分子量和交联度成正比;Na Cl的加入使SAL-PEG的PEG非离子长链却被严重压缩,分子流体动力学半径显著减小,减小程度与其分子量和交联度成正比,但SAL-PEG的聚集程度仍然较弱. 相似文献
958.
A projector which uses a rotating slide structure to project aperiodic sinusoidal fringe patterns at high frame rates and with high radiant flux is introduced. It is used in an optical three-dimensional (3D) sensor based on coded-light projection, thus allowing the analysis of fast processes. Measurements of an inflating airbag, a rope skipper, and a soccer ball kick at a 3D frame rate of more than 1300 independent point clouds per second are presented. 相似文献
959.
Luminita A. Tudorica Karen Y. Oh Nicole Roy Mark D. Kettler Yiyi Chen Stephanie L. Hemmingson Aneela Afzal John W. Grinstead Gerhard Laub Xin Li Wei Huang 《Magnetic resonance imaging》2012
Three dimensional bilateral imaging is the standard for most clinical breast dynamic contrast-enhanced (DCE) MRI protocols. Because of high spatial resolution (sRes) requirement, the typical 1–2 min temporal resolution (tRes) afforded by a conventional full-k-space-sampling gradient echo (GRE) sequence precludes meaningful and accurate pharmacokinetic analysis of DCE time-course data. The commercially available, GRE-based, k-space undersampling and data sharing TWIST (time-resolved angiography with stochastic trajectories) sequence was used in this study to perform DCE-MRI exams on thirty one patients (with 36 suspicious breast lesions) before their biopsies. The TWIST DCE-MRI was immediately followed by a single-frame conventional GRE acquisition. Blinded from each other, three radiologist readers assessed agreements in multiple lesion morphology categories between the last set of TWIST DCE images and the conventional GRE images. Fleiss’ κ test was used to evaluate inter-reader agreement. The TWIST DCE time-course data were subjected to quantitative pharmacokinetic analyses. With a four-channel phased-array breast coil, the TWIST sequence produced DCE images with 20 s or less tRes and ~ 1.0×1.0×1.4 mm3 sRes. There were no significant differences in signal-to-noise (P=.45) and contrast-to-noise (P=.51) ratios between the TWIST and conventional GRE images. The agreements in morphology evaluations between the two image sets were excellent with the intra-reader agreement ranging from 79% for mass margin to 100% for mammographic density and the inter-reader κ value ranging from 0.54 (P<.0001) for lesion size to 1.00 (P<.0001) for background parenchymal enhancement. Quantitative analyses of the DCE time-course data provided higher breast cancer diagnostic accuracy (91% specificity at 100% sensitivity) than the current clinical practice of morphology and qualitative kinetics assessments. The TWIST sequence may be used in clinical settings to acquire high spatiotemporal resolution breast DCE-MRI images for both precise lesion morphology characterization and accurate pharmacokinetic analysis. 相似文献
960.
In this paper, we develop a device model of an organic thin film transistor (OTFTs) in which the active layers are made of octithiophene. This model is based on variable range hopping theory, i.e., a carrier may either hop over a small distance with a high activation energy or hop over a long distance with a low activation energy. The model takes into account all the operating regimes in direct current and transient mode; the transistor symmetry is also considered. The model has been developed using a physical basis where the model parameters can easily be extracted. The current–voltage characteristics of short-channel organic TFTs have been calculated starting from the solution of the drain current equation for an enhancement mode p-channel MOSFET. A good agreement between theory model and experimental results is obtained. Different transport parameters are extracted by using a fitting method. We have extracted the mobility of charge in saturation regime using differential method. Based on first and second derivative of transfer characteristic we extracted a serial resistance, intrinsic mobility and threshold voltage. The mobility in saturation regime is reproduced using the VRH model. Finally, we give a simple small-signal equivalent circuit. 相似文献