Synchronous Dual Electrolyte Additive Sustains Zn Metal Anode with 5600 h Lifespan

Despite conspicuous merits of Zn metal anodes, the commercialization is still handicapped by rampant dendrite formation and notorious side reaction. Manipulating the nucleation mode and deposition orientation of Zn is a key to rendering stabilized Zn anodes. Here, a dual electrolyte additive strategy is put forward via the direct cooperation of xylitol (XY) and graphene oxide (GO) species into typical zinc sulfate electrolyte. As verified by molecular dynamics simulations, the incorporated XY molecules could regulate the solvation structure of Zn²⁺, thus inhibiting hydrogen evolution and side reactions. The self-assembled GO layer is in favor of facilitating the desolvation process to accelerate reaction kinetics. Progressive nucleation and orientational deposition can be realized under the synergistic modulation, enabling a dense and uniform Zn deposition. Consequently, symmetric cell based on dual additives harvests a highly reversible cycling of 5600 h at 1.0 mA cm⁻²/1.0 mAh cm⁻².     

双峰倍增配平法用于同步、导数-同步荧光法同时测定邻羟基苯甲酸和间羟基苯甲酸

邻羟基苯甲酸（ｏＨＢＡ）和间羟基苯甲酸（ｍＨＢＡ）荧光光谱严重重叠，同步及导数技术虽使选择性有所改善，但仍不能完全分辨开重叠谱。用双峰倍增配平计算法结合同步、一阶导数－同步荧光法对双组分体系（邻羟基苯甲酸／间羟基苯甲酸，ｐＨ１２介质）同时测定。结合计算的两种测定方法精密度、回收率和不同组分间浓度比范围均优于一阶导数－同步荧光法。     

Sol-gel polyimide-silica composite membrane: gas transport properties

The effect of introduction of silica particles prepared by the sol-gel technique on the gas transport properties of a polyimide film was studied. The sorption and permeation of N₂, O₂, CO₂, H₂ and CH₄ were studied and correlated with morphological changes in the polymer structure. From sorption isotherms, we observed that the composite membrane presents higher solubility coefficients than the polyimide one. The solubility coefficient ratio between the composite and the polyimide is about 1.5–2.0. The isotherms were analyzed in terms of the dual mode sorption. The Henry's coefficient and the Langmuir's affinity and saturation constants were obtained allowing to calculate the Langmuir to Henry concentration ratios as function of the gas pressure. These ratios decrease until zero within a certain pressure range as long as the Langmuir's mode is acting and they are higher for the polyimide membrane when compared with the composite one. This study was completed with calorimetric measurements during the sorption. The gas interaction energy in kJ/mol decreases within the same pressure range as previously described. The measured energies are higher for the polyimide film when compared with the composite one because the polyimide membrane presents a stronger energetic effect caused by a higher Langmuir's contribution. From permeation studies at 3.15⁵ Pa, the composite membrane showed higher permeability coefficients and permselectivities than the polyimide one. All these results were explained, taking into account the difference on the imidization degree of both membranes and the morphological changes which may be induced by the silica nodules in the organic/inorganic interphases.     

甲基化的β-环糊精与十六烷基三甲基溴化胺的相互作用

环糊精与表面活性剂的相互作用已有许多研究,但多局限于β－环糊精（β－CD）,而修饰的β－环糊精与表面活性剂的相互作用研究较少[1－3]．分子内扭转电荷转移（TICT）激发态对介质极性高度敏感性,已成功地用于探针环糊精与表面活性剂的相互作用[4]．研究表明,β－CD能够诱     

The combinatorial properties of the hyperplanes of DW(5, q) arising from embedding

In De Bruyn Discrete math(to appear), one of the authors proved that there are six isomorphism classes of hyperplanes in the dual polar space DW(5, q), q even, which arise from its Grassmann-embedding. In the present paper, we determine the combinatorial properties of these hyperplanes. Specifically, for each such hyperplane H we calculate the number of quads Q for which is a certain configuration of points in Q and the number of points for which is a certain configuration of points in . By purely combinatorial techniques, we are also able to show that the set of hyperplanes of DW(5, q), q odd, which arise from its Grassmann-embedding can be divided into six subclasses if one takes only into account the above-mentioned combinatorial properties. A complete classification of all hyperplanes of DW(5, q), q odd, which arise from its Grassmann-embedding, i.e. the division of the above-mentioned six classes into isomorphism classes, will unlike in De Bruyn (to appear) most likely need a group-theoretical approach. Postdoctoral Fellow of the Research Foundation—Flanders (Belgium).     

On optimal periodic dividend strategies in the dual model with diffusion

The dual model with diffusion is appropriate for companies with continuous expenses that are offset by stochastic and irregular gains. Examples include research-based or commission-based companies. In this context, Bayraktar et al. (2013a) show that a dividend barrier strategy is optimal when dividend decisions are made continuously. In practice, however, companies that are capable of issuing dividends make dividend decisions on a periodic (rather than continuous) basis.In this paper, we consider a periodic dividend strategy with exponential inter-dividend-decision times and continuous monitoring of solvency. Assuming hyperexponential gains, we show that a periodic barrier dividend strategy is the periodic strategy that maximizes the expected present value of dividends paid until ruin. Interestingly, a ‘liquidation-at-first-opportunity’ strategy is optimal in some cases where the surplus process has a positive drift. Results are illustrated.     

Correlation coefficient of dual hesitant fuzzy sets and its application to multiple attribute decision making

A dual hesitant fuzzy set (DHFS) consists of two parts, that is, the membership hesitancy function and the nonmembership hesitancy function, supporting a more exemplary and flexible access to assign values for each element in the domain, and can handle two kinds of hesitancy in this situation. It can be considered as a powerful tool to express uncertain information in the process of group decision making. Therefore, we propose a correlation coefficient between DHFSs as a new extension of existing correlation coefficients for hesitant fuzzy sets and intuitionistic fuzzy sets and apply it to multiple attribute decision making under dual hesitant fuzzy environments. Through the weighted correlation coefficient between each alternative and the ideal alternative, the ranking order of all alternatives can be determined and the best alternative can be easily identified as well. Finally, a practical example of investment alternatives is given to demonstrate the practicality and effectiveness of the developed approach.     

Presentation for the Partial Dual Symmetric Inverse Monoid

We give a monoid presentation in terms of generators and define relations for the partial analogue of the finite dual symmetric inverse monoid.     

On Weak Dual Rickart Modules and Dual Baer Modules

We introduce and study the notion of wd-Rickart modules (i.e. modules M such that for every nonzero endomorphism ? of M, the image of ? contains a nonzero direct summand of M). We show that the class of rings R for which every right R-module is wd-Rickart is exactly that of right semi-artinian right V-rings. We prove that a module M is dual Baer if and only if M is wd-Rickart and M has the strong summand sum property. Several structure results for some classes of wd-Rickart modules and dual Baer modules are provided. Some relevant counterexamples are indicated.