直接内重整熔融碳酸盐燃料电池中甲烷蒸汽重整催化剂探索性研究

选择甲烷蒸汽重整催化剂用于直接内重整熔融碳酸盐燃料电池(DIR-MCFC)中,并考察了DIR-MCFC的性能,讨论了电池放电量、气体压力、燃料气进料水/碳比(S/C)等因素对该催化剂性能的影响.结果表明,重整催化剂能够满足电池放电需求;放电量大小影响电池内的H2含量,但对CH4含量影响不大;当气体压力为0.36MPa时...     

焙烧温度对Ni/CuO-ZrO2-CeO2-Al2O3催化剂在甲烷自热重整反应中积炭行为的影响

以Na₂CO₃为沉淀剂,在pH=9时,采用并流沉淀法制备了Ni/CuO-ZrO₂-CeO₂-Al₂O₃催化剂,催化剂中活性组分Ni的负载量(质量分数)为10%．采用TPO、SEM和XPS等方法研究了载体焙烧温度对催化剂积炭行为的影响．结果表明,载体焙烧温度为800 oC制备的Ni/CuO-ZrO₂-CeO₂-Al₂O₃催化剂不存在高温烧炭峰,可以避免由于积炭而降低反应的活性．反应40 h后,催化剂表面出现表面碳酸盐和非活性丝状积炭,这些物种可能会导致催化剂活性降低．     

中国催化重整技术进展

催化重整是将石脑油转化为高辛烷值汽油、芳烃,并副产大量氢气的过程,催化重整技术的进步关系到石油炼制与石油化工行业技术的战略安全与竞争力,因此受到极大重视.本文从催化材料、催化反应活性中心及反应机理、催化重整工艺、催化重整反应和再生动力学、关键设备、工程控制技术等方面阐述了我国在理论研究、工业开发及工业应用方面取得的技术进步和成果,对未来的技术进步途径进行了分析与展望.     

Methodik und Ergebnisse von Tracerexperimenten über katalytische Reaktionen von Kohlenwasserstoffen

Tracermethoden können wichtige Beiträge zur Aufklärung katalytischer Kohlenwasserstoffreaktionen liefern. In dieser Arbeit werden einige Ergebnisse mehrjähriger Untersuchungen mit ¹⁴C-markierten Verbindungen zusammenfassend dargestellt. Es wird speziell auf Benzenbildungsreaktionen bei der Leichtbenzin-Reformierung und auf Reaktionsmechanismen bei der Isomerísierung von C₈-Aromaten eingegangen.     

Analytical solution to a mode of mixed elastohydrodynamic lubrication with mixed contact regimes: Part I. Without consideration of contact adhering layer in the inlet zone

In 2005, Zhang presented a Grubin-like inlet zone analysis to the isothermal line contact elastohydrodynamic lubrication under relatively heavy loads when the hydrodynamic film thickness in the Hertzian zone approaches zero and the EHL fluid is Newtonian [Zhang, Y.B. A justification of the load-carrying capacity of elastohydrodynamic lubrication film based on the Newtonian fluid model. Industrial Lubrication and Tribology, 2005, Vol. 57, pp. 224–232]. His results showed that in this EHL, when the rolling speed is lower than the characteristic rolling speed (U_ch =) 0.0372W^1.50/G, the Hertzian zone is in physical adsorbed layer boundary lubrication while the inlet zone is in conventional hydrodynamic lubrication. This mode of EHL represents a mode of mixed EHL with mixed contact regimes, where hydrodynamic films with different rheological behaviors occur in different areas of the contact. The present paper presents an analysis to this mode of mixed EHL by using the Grubin type method when the contact adhering layer in the inlet zone is neglected. Pressures, film thicknesses and load partition in the contact are obtained from this analysis. It is also found that the formula for the characteristic rolling speed U_ch = 0.0372W^1.50/G obtained by Zhang [Zhang, Y.B. A justification of the load-carrying capacity of elastohydrodynamic lubrication film based on the Newtonian fluid model. Industrial Lubrication and Tribology, 2005, Vol. 57, pp. 224–232] may be valid for the dimensionless load W > 1.0E−7, while it may be invalid for the dimensionless load W < 1.0E−8. In part II [Zhang, Y.B. Analytical solution to a mode of mixed elastohydrodynamic lubrication with mixed contact regimes: Part II. Considering the contact adhering layer effect in the inlet zone. Journal of Molecular Liquids, 2006, Vol. 117. (doi:10.1016/j.molliq.2006.04.007)] will be presented an analysis to other two modes of mixed EHL with mixed contact regimes for relatively heavy loads, low rolling speeds and Newtonian fluids, where the conventional hydrodynamic lubrication, physical adsorbed layer boundary lubrication and oxidized chemical layer boundary lubrication can simultaneously occur in the inlet zone while the oxidized chemical layer boundary lubrication or the fresh metal-oxidized chemical boundary layer dry contact occur in the Hertzian zone, considering the contact adhering layer effect in the inlet zone.     

Organic contaminants removal by oxygen ECR plasma

Recently electron cyclotron resonance (ECR) plasma have been explored for wafer cleaning applications, since it is known to do less damage to silicon surface than conventional plasma. Organic contaminants removal efficiency and plasma radiation damage of the ECR plasma cleaning have been investigated. In oxygen ECR plasma cleaning, the plasma exposure time needed to remove the organic contaminants on the silicon surface down to the detection limit is 40 s, but the one to reach the lowest surface roughness is 10 s. The leakage current level of the MOS capacitor made using the Si substrate exposed to oxygen ECR plasma for 40 s is 8 × 10⁻⁹ A. The optimum exposure time determined by considering the contaminants removal efficiency and the plasma radiation damage (or the leakage current level) is 40 s. Organic contaminants seem to be removed through both sputter-off mechanism by oxygen ion bombardment and evaporation mechanism by chemical reactions with excited oxygen atoms.     

助剂对负载型镍催化剂重整活性和抗积炭性能的影响

应用ＸＲＤ和催化活性评价手段，考察了助剂对Ｃ２重整制合成气的负勒型Ｎｉ催化剂的重整活性和其抗积炭性能的影响。实验结果表明，ＮｉＯ在γ－Ａｌ２Ｏ３表面上最大分散量随ＭｇＯ、Ｌａ２Ｏ３助剂的添加没程度地增大，助剂能影响负载型Ｎｉ催化剂 论性能，ＭｇＯ、Ｌａ２Ｏ３的添加对改善Ｎｉ催化剂的重整活性和抗积炭性能有明显效果，并与助剂的种类添加次序有关。     

Hydrogen Production by Steam Reforming of Ethanol: A Two Step Process

A two-layer fixed-bed catalytic reactor for hydrogen production by steam reforming of ethanol is proposed. In this reactor ethanol is first converted to acetaldehyde over a Cu-based catalyst and then acetaldehyde is converted to a hydrogen-rich mixture over a Ni-based catalyst. It is shown that the use of such type of reactor prevents coke formation and provides hydrogen yields closed to equilibrium.