全文获取类型
收费全文 | 516篇 |
免费 | 5篇 |
国内免费 | 45篇 |
专业分类
化学 | 478篇 |
晶体学 | 4篇 |
力学 | 11篇 |
综合类 | 3篇 |
数学 | 1篇 |
物理学 | 69篇 |
出版年
2023年 | 9篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 10篇 |
2019年 | 11篇 |
2018年 | 2篇 |
2017年 | 13篇 |
2016年 | 8篇 |
2015年 | 4篇 |
2014年 | 12篇 |
2013年 | 16篇 |
2012年 | 20篇 |
2011年 | 20篇 |
2010年 | 18篇 |
2009年 | 30篇 |
2008年 | 38篇 |
2007年 | 29篇 |
2006年 | 29篇 |
2005年 | 22篇 |
2004年 | 10篇 |
2003年 | 32篇 |
2002年 | 16篇 |
2001年 | 17篇 |
2000年 | 19篇 |
1999年 | 16篇 |
1998年 | 17篇 |
1997年 | 12篇 |
1996年 | 13篇 |
1995年 | 13篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 9篇 |
1989年 | 10篇 |
1988年 | 9篇 |
1987年 | 7篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1982年 | 4篇 |
1981年 | 7篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 5篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有566条查询结果,搜索用时 0 毫秒
71.
Cardelli C. Conti G. Gianni P. Porta R. 《Journal of Thermal Analysis and Calorimetry》2000,62(1):135-151
The mixing enthalpies of blends of polymethylmethacrylate (PMMA) with poly(styrene-co-acrylonitrile) (SAN) were investigated
by analogue calorimetry through the determination of the excess enthalpies of pseudobinary model mixtures corresponding to
the addition of methyl-i-butyrate to a binary mixture of acetonitrile or propionitrile plus toluene or ethylbenzene.
A group contribution procedure, based on UNIQUAC equation, was also devised and the polymeric mixing enthalpies were calculated
from properly defined group contributions. Enthalpies for polymeric interactions were introduced into the Flory-Huggins equation
and the miscibility window of PMMA-SAN mixtures was calculated.
The results show a qualitative agreement with the experimental miscibility data and indicate that both the analogue calorimetry
and the group contribution procedures yield correct results when acetonitrile, and not propionitrile, is chosen as the model
for the polyacrylonitrile repeat unit of the copolymer.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
72.
B. Emmoth 《辐射效应与固体损伤》2013,168(1-4):365-379
At doses close to threshold for exfoliation or bubble formation the surfaces have been investigated by SEM and, after isolation of surface layers, also by RBS. Swelling as a function of energy and material has been determined. The data are interpreted in the form of volume occupied by a helium atom. We find an indication for a volume decrease with increasing energy. A special example of blister formation is also discussed, where we find evidence for a non-uniform fracture plane. 相似文献
73.
Sonia Freire H. Casas Esther Rilo Luisa Segade O. Cabeza E. Jiménez 《Journal of Thermal Analysis and Calorimetry》2005,80(2):285-288
Summary In this paper we present excess molar volumes and excess molar enthalpies of binary and ternary mixtures containing propyl propanoate, hexane and cyclohexane as components at 298.15 K. Excess molar volumes were calculated from the density of the pure liquids and mixtures. The density was measured using an Anton Paar DMA 60/602 vibrating-tube densimeter. Excess molar enthalpies were obtained using a Calvet microcalorimeter 相似文献
74.
Virender K. Sharma Karolina M. Siskova Radek Zboril Jorge L. Gardea-Torresdey 《Advances in colloid and interface science》2014
This review paper presents the overview of processes involved in transformation of organic-coated silver nanoparticles (AgNPs) in biological systems and in the aquatic environment. The coating on AgNPs greatly influences the fate, stability, and toxicity of AgNPs in aqueous solutions, biological systems, and the environment. Several organic-coated AgNP systems are discussed to understand their stability and toxicity in biological media and natural water. Examples are presented to demonstrate how a transformation of organic-coated AgNPs in an aqueous solution is affected by the type of coating, pH, kind of electrolyte (mono- or divalent), ionic strength, organic ligands (inorganic and organic), organic matter (fulvic and humic acids), redox conditions (oxic and anoxic), and light. Results of cytotoxicity, genotoxicity, and ecotoxicity of coated AgNPs to food chain members (plants, bacteria, and aquatic and terrestrial organisms) are reviewed. Key factors contributing to toxicity are the size, shape, surface coating, surface charge, and conditions of silver ion release. AgNPs may directly damage the cell membranes, disrupt ATP production and DNA replication, alternate gene expressions, release toxic Ag+ ion, and produce reactive oxygen species to oxidize biological components of the cell. A progress made on understanding the mechanism of organic-coated AgNP toxicity using different analytical techniques is presented. 相似文献
75.
76.
77.
Vapor liquid equilibrium (VLE) is successfully predicted from excess enthalpy HE data for binary ether + n-alkane or cyclohexane mixtures. Parameters for the continuous linear association model (CLAM) and for the UNIQUAC Model for the excess Gibbs energy GE were determined from HE data measured at a low temperature (ambient temperature). These parameters are used to predict VLE data at low and high temperatures. The dependence of the accuracy of predictions on the set of HE data chosen to evaluate the parameters and on the model for GE are discussed. 相似文献
78.
Enthalpies of crystallization of NH4Al(SO4)2·12H2O from aqueous solutions at 25°C, measured using a calorimetric method and determined from previously published data on the concentration dependence of the enthalpy of solution, are reported. The results are compared with the values obtained from the temperature dependence of solubility and from vapor pressure data by using the Williamson equation. The integral and partial molar enthalpies of solution in concentrated and diluted solutions are given. 相似文献
79.
Giuseppina Castronuovo Vittorio Elia Filomena Velleca 《Journal of solution chemistry》1996,25(1):51-59
Enthalpies of dilution of binary and ternary aqueous solutions containing L-and D-proline, cis-L- and cis-D-4-hydroxy proline, trans-L-4-hydroxy proline, have been determined by flow calorimetry at 25°C. Pairwise self-and cross-interaction coefficients of the virial expansion of the excess enthalpies were evaluated. They are positive for solutions of unsubstituted prolines. On the contrary, upon the introduction of a hydroxy group, they become negative, reaching the largest value for the cis-L-lcis-D-4-hydroxy proline system. The results are interpreted in terms of preferential configurations, stabilized by interactions between the hydrophilic groups. 相似文献
80.