全文获取类型
收费全文 | 10727篇 |
免费 | 1538篇 |
国内免费 | 1054篇 |
专业分类
化学 | 4880篇 |
晶体学 | 112篇 |
力学 | 463篇 |
综合类 | 121篇 |
数学 | 465篇 |
物理学 | 7278篇 |
出版年
2024年 | 27篇 |
2023年 | 94篇 |
2022年 | 302篇 |
2021年 | 302篇 |
2020年 | 352篇 |
2019年 | 284篇 |
2018年 | 259篇 |
2017年 | 438篇 |
2016年 | 505篇 |
2015年 | 495篇 |
2014年 | 700篇 |
2013年 | 827篇 |
2012年 | 629篇 |
2011年 | 635篇 |
2010年 | 554篇 |
2009年 | 621篇 |
2008年 | 720篇 |
2007年 | 718篇 |
2006年 | 600篇 |
2005年 | 498篇 |
2004年 | 500篇 |
2003年 | 460篇 |
2002年 | 407篇 |
2001年 | 331篇 |
2000年 | 298篇 |
1999年 | 260篇 |
1998年 | 229篇 |
1997年 | 216篇 |
1996年 | 181篇 |
1995年 | 180篇 |
1994年 | 155篇 |
1993年 | 105篇 |
1992年 | 97篇 |
1991年 | 49篇 |
1990年 | 60篇 |
1989年 | 49篇 |
1988年 | 43篇 |
1987年 | 34篇 |
1986年 | 24篇 |
1985年 | 20篇 |
1984年 | 15篇 |
1983年 | 4篇 |
1982年 | 13篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1966年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
Behavior of cellulose in NaOH/Urea aqueous solution characterized by light scattering and viscometry
Cellulose was dissolved in 6 wt % NaOH/4 wt % urea aqueous solution, which was proven by a 13C NMR spectrum to be a direct solvent of cellulose rather than a derivative aqueous solution system. Dilute solution behavior of cellulose in a NaOH/urea aqueous solution system was examined by laser light scattering and viscometry. The Mark–Houwink equation for cellulose in 6 wt % NaOH/4 wt % urea aqueous solution at 25 °C was [η] = 2.45 × 10?2 weight‐average molecular weight (Mw)0.815 (mL g?1) in the Mw region from 3.2 × 104 to 12.9 × 104. The persistence length (q), molar mass per unit contour length (ML), and characteristic ratio (C∞) of cellulose in the dilute solution were 6.0 nm, 350 nm?1, and 20.9, respectively, which agreed with the Yamakawa–Fujii theory of the wormlike chain. The results indicated that the cellulose molecules exist as semiflexible chains in the aqueous solution and were more extended than in cadoxen. This work provided a novel, simple, and nonpollution solvent system that can be used to investigate the dilute solution properties and molecular weight of cellulose. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 347–353, 2004 相似文献
12.
13.
随机化交通灯的二维元胞自动机交通模型 总被引:8,自引:0,他引:8
元胞自动机交通模型以简单的规则反映交通系统中的多种因素,可以分析各种交通现象,且可在计算机上方便、高效地运作·Biham-Middleton-Levine模型(BML模型)实现了二维交通问题的元胞自动机模型的模拟研究·本文对BML模型作了改进,解除了该模型中关于交通灯同步变化的限制·在新模型中,每个路口的交通灯可以自由选定起始工作时间和变化节奏,于是可以更全面、准确地反映交通灯对交通系统性能的影响·本文还对新模型中出现的若干新效应作了解释· 相似文献
14.
This paper presents a unified analysis of decomposition algorithms for continuously differentiable optimization problems defined on Cartesian products of convex feasible sets. The decomposition algorithms are analyzed using the framework of cost approx imation algorithms. A convergence analysis is made for three decomposition algorithms: a sequential algorithm which extends the classical Gauss-Seidel scheme, a synchronized parallel algorithm which extends the Jacobi method, and a partially asynchronous parallel algorithm. The analysis validates inexact computations in both the subproblem and line search phases, and includes convergence rate results. The range of feasible step lengths within each algorithm is shown to have a direct correspondence to the increasing degree of parallelism and asynchronism, and the resulting usage of more outdated information in the algorithms. 相似文献
15.
I.IntroductionThepcrformanccsofAcousto-optic(AO)dcviccareoftenlimitcdbythepropertiesofAOmcdiawhenitisusedinAOsigna1processingsystems.Thespectrumanalyzersandcorre1ationreceivers,forinstancc,areexpcctcdtoimprovcthereso1utionanddynamicrangcwhilereducingtheproccssorvolume.Rccent1y,ancwclassofmateria1s,themercurousha1ides,promiscstocontributeimportantsolutionstosuchnccdsandisrefincdtopractica1uti1izations.Themecurousha1ideweconsidcrinthispapcrismecurouschloride(Hg,C1,).Thesing1ecrystalofHg,Cl… 相似文献
16.
Khaled A. Aamer Gregory N. Tew 《Journal of polymer science. Part A, Polymer chemistry》2007,45(6):1109-1121
Supramolecular block‐random copolymers containing [Ir(terpy)2]3+ in the side chain were synthesized via postfunctionalization of a P(S‐b‐ACterpy) block copolymer. Absorbance and emission spectra compared to a model compound show that the polymer backbone has a minor effect on the polymer absorbance but produces a larger shift for the phosphorescence signals to higher wavelength. Dynamic light scattering of the metal complex containing copolymer studied in various solvents showed monomodal aggregation with decreasing aggregate size as the solvent dielectric constant increased. The copolymer precursor P(S‐b‐ACterpy) shows multimodal aggregation in different solvents with the major population consisting of single chains. This difference in behavior between the two polymers is attributed to the electrolytic nature of the complex and the amphiphilicity induced by the charged metal complex. Supramolecular copolymers like these will continue to have interesting self‐organizational properties and may find applications in multicomponent systems for photoinduced charge separation processes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1109–1121, 2007 相似文献
17.
A. Di Maio A. Rocco P. Ferraro M. De Rosa P. De Natale S. De Nicola A. Finizio G. Pierattini G. Coppola M. Iodice V. Striano 《Optics and Lasers in Engineering》2007,45(3):385
In view of the growing interest for non-destructive tests of materials, geodynamical monitoring and in general remote sensing, there is a great effort to bring practical optical sensors from research labs to industrial and environmental applications. In this paper, we employ digital holographic technique as an efficient tool for evaluating the strain measurement capability of fiber Bragg gratings (FBG). A cantilever beam has been employed as a test structure under loading test. The strain measurements results obtained by fiber-based sensors have been compared to those obtained by using full-field digital holographic technique and point-wise strain gauge sensors glued on the same cantilever beam. A simple theoretical model is also presented to interpret and compare the experimental results coming from different techniques. 相似文献
18.
长江中下游的主要防洪工程是长江干堤 ,长江堤防线路长、工程浩大、堤基工程地质水文地质条件复杂 ,涉及大量的已有地质数据和资料。今后在整治加固堤防的工程地质勘察工作中 ,还需随时进行数据的收集、存储、检索、分析、统计和维护 ,随时调用这些数据进行综合处理、编制报告和图件 ;在防汛期间可以针对堤防险工险段的险情 ,随时查询和调用有关的资料、数据或者图件 ,提供采取抢险措施决策的地质依据。这既提高了地质数据的利用价值和利用率 ,又保证了信息的准确性、完整性和共享性。因此 ,建立合理的长江堤防工程地质信息处理模型及其成熟的技术方法具有重要的意义。 相似文献
19.
20.
1 Introduction Inrecentyears,boththetheoreticalandexperimentalinvestigationsonlasercoolingandtrappinghavebecomeoneofthemajorfieldsinatomic,molecularandoptical physics[1~ 8] .Thedevelopmentoflasercoolingandtrappingtechnologyisimportantfortheapplicationssu… 相似文献