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81.
The transient absorption properties of several commercially available TiO2 photocatalysts were investigated by femtosecond diffuse-reflectance spectroscopy. Using femtosecond diffuse-reflectance spectroscopy, the quantities and rates of the initial trapping processes of holes and electrons generated by the photoexcitation of TiO2 photocatalysts were investigated. It was found that the total amounts of trapped electrons for the pure-anatase and pure-rutile TiO2 became smaller with increasing particle size, but increased again when the particles’ diameters were larger than 50 nm. The anatase–rutile mixed TiO2 photocatalysts were found to have smaller amounts of trapped electrons compared with pure-anatase and pure-rutile TiO2 photocatalysts. The lifetimes of trapped holes of various TiO2 photocatalysts were also investigated, and it was found that the lifetimes were proportional to the anatase–rutile mixed ratios. 相似文献
82.
分布布喇格反射镜的反射特性 总被引:1,自引:1,他引:1
采用等效法布里珀罗(FP)腔方法对分布布喇格反射镜(DBR)的特性进行了研究,计算并讨论了上下两层DBR结构非对称模型反射率的变化.设计了DBR反射镜的反射谱中心波长为850nm的结构.随着DBR周期数的增加,腔反射率峰值逐渐增加.上下两层DBR反射镜的厚度由反射率和中心波长决定.实验表明,下DBR的周期数为30对左右,上DBR的周期数为20对左右,易实现激光输出.非对称的双层DBR的反射特性表明理论计算与实验结果基本一致. 相似文献
83.
84.
A spectrophotometer system for spectral characterization of materials in the infrared has been built around a bench-top Fourier transform instrument. Its capabilities include the measurement of directional-hemispherical reflectance from 1 to 18 μm. The spectral reflectance measurement is performed with an integrating sphere with an incidence angle of 8°. Both relative and absolute measurements can be made. Several methods can be used to determine the absolute value of the directional-hemispherical reflectance of samples. The primary method used is independent of the integrating sphere theory and the requisite assumptions associated with its use. The calibration of a standard reference material (SRM) is described. This SRM has a reflectance value near 0.9 over the complete calibration range 2–18 μm. As part of the calibration procedure the spatial uniformity of the sphere throughput and the bi-directional reflectance distribution function (BRDF) of the SRM material are evaluated. 相似文献
85.
Alexandra Fidalgo Tessy M. Lopez Laura M. Ilharco 《Journal of Sol-Gel Science and Technology》2009,49(3):320-328
Wet sol–gel silica matrices produced under different hydrolysis conditions were used as delivery devices to the active principle
of an antiepileptic drug (phenytoin sodium), encapsulated during the condensation stage. Post-incorporation into dry silica
powder was an alternative loading procedure. It was proven by infrared spectroscopy that neither the silica network nor the
drug loose integrity by encapsulation. The kinetics of in vitro drug release was studied at 37 °C, to water and to artificial
cerebrospinal fluid (ACSF). Emphasis has been given to the release to ACSF under dynamic conditions (with fluid renovation,
emulating what occurs in the brain). Different delivery regimes were identified and correlated with the loading method and
the matrix structure. Matrices with lower total porosity and smaller average pore size proved to be better for a long term
release. Renovation of ACSF is relevant to assure a constant concentration of phenytoin in the vicinity of the device. 相似文献
86.
Alfi Khatib Vikneswari Perumal Qamar Uddin Ahmed Bisha Fathamah Uzir Faridah Abas Suganya Murugesu 《Analytical letters》2017,50(12):1977-1991
Momordica charantia is widely consumed edible fruit. The food and pharmaceutical industries use it as a natural antioxidant. However, the quality control of M. charantia-based medicinal products is questionable due to the complexity of metabolites in this fruit. Hence, this study has developed a statistical model in predicting the antioxidant value through the 2, 2-diphenyl-1 picrylhydrazyl radical scavenging activity and ferric reducing antioxidant power based on infrared spectroscopy with attenuated total reflectance. This technique was reliably used for quality control. Six ethanol extracts (0, 20, 40, 60, 80, and 100% in water) of this plant’s fruit were prepared. The radical scavenging and ferric reducing antioxidant power activities were measured and the chemical profiling of the extracts was fingerprinted by infrared spectroscopy between 4,000 and 600?cm?1 at a resolution of 4?cm?1. Statistical analysis was developed by correlating the bioactivity and infrared spectra of each extract using orthogonal partial least square discriminant analysis. The C–N, C?O, C–O, C–H, and OH infrared signals were positively correlated with biological activity. The antioxidant activity of the fruit of M. charantia may be due to the presence of several antioxidants that work synergistically. 相似文献
87.
The purpose of this Note is to propose new diffusive capillary models of Korteweg type and discuss their mathematical properties. More precisely, we introduce viscous models which provide some additional information on the behavior of the density close to vacuum. We actually prove that if some compatibility conditions between diffusion and capillarity are satisfied, some extra regularity information on a quantity involving the density is available. We obtain a non-trivial equality deduced from the special structure of the momentum equation. This Note generalizes to some extent the authors' previous works on the Korteweg model (with constant capillary coefficient) and on the shallow water equation. To cite this article: D. Bresch, B. Desjardins, C. R. Mecanique 332 (2004). 相似文献
88.
基于近红外光纤漫反射技术,利用偏最小二乘法分别建立了复方氯丙那林胶囊的三种药效成分盐酸氯丙那林、盐酸溴己新和盐酸去氯羟嗪的快速同时测定方法。所建立的盐酸氯丙那林、盐酸溴己新和盐酸去氯羟嗪的定量分析多元校正模型的相关系数分别为99.7%、99.4%和99.0%,校正集的均方根残差分别为0.028、0.145和0.250,预测均方根误差分别为0.055、0.120和0.210。由于该方法是在不经任何预处理的情况下的光纤快速同时分析,因此可用于复方氯丙那林的过程质量控制。 相似文献
89.
本文研究了生物组织的改进的δ-P1近似漫反射光学模型,推导了含有等效光源一阶矩的双点源近似空间分辨漫反射解Rδ-P1(ρ).研究表明,考虑等效光源一阶矩的光学模型,较好地描述了具有强的前向散射特性和较大吸收系数的生物组织散射特性;与漫射近似下的漫反射率RSDA(ρ)相比,新的光学模型能较好地描述光源附近的漫辐射强度分布,并且由于解析表达式中含有散射相函数的二阶参量γ,这对
关键词:
组织光学
1近似')" href="#">δ-P1近似
等效光源
微区漫反射 相似文献
90.
基于HJ-1-CCD数据的地表反射率反演与验证 总被引:4,自引:0,他引:4
环境一号卫星OCD相机(HJ-1-CCD)30m的空间分辨率在地物识别中具有潜在优势,然而由于缺少短波红外通道,利用暗像元法反演地表反射率较为困难.基于北京与珠三角地区的地物光谱试验,获得暗像元的植被指数与红、蓝波段反射率比值,构建基于辐射传输模型的大气校正算法.为了验证算法精度,将北京地区卫星反演值与实测的草坪、水体... 相似文献