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101.
102.
氯柱硼镁石在氯化镁水溶液中相转化平衡液相的红外光谱分析 总被引:5,自引:0,他引:5
采用差示FTIR光谱技术,研究了氯柱硼镁石在30℃下浓度为0.5,12和18%MgCl_2水溶液中溶解及相转化平衡饱和水溶液中硼氧配阴离子的FTIR光谱。给出了溶液中硼氧配阴离子的FTIR光谱振动频率的归属,515cm~(-1)为单和二硼氧配阴离子特征峰,630cm~(-1)为三硼氧配阴离子特征峰,550cm~(-1)为四硼氧配阴离子特征峰。对饱和水溶液中硼氧配阴离子的存在形式及其相互作用以及与相转化析出固相的关系进行了讨论。 相似文献
103.
The order reduction method of the rotational relativistic Birkhoffian is studied.For a rotational relativistic Birkhoffian system.the cyclic integrals can be found by using the perfect differential method.Through these cyclic integrals,the order of the system can be reduced.If the rotational relativistic Birkhoffian system has a cyclic integral,then the Birkhoffian equations can be reduced at least two degrees and the Birkhoffian form can be kept.An example is given to illustrate the application of the results. 相似文献
104.
Intra-cavity phase anisotropy causes each laser longitudinal mode to split into two orthogonally polarized frequencies. When the frequency difference generated by small anisotropy is about 40 MHz or less, only one frequency of the splitting mode oscillates while the other is always in lock-in state due to strong mode competition. In that case the longitudinal mode spacing deviates from its original value. And the spacing of two adjacent longitudinal modes shows differential variations depending on direction of cavity length tuning and mode polarization. In this paper, the relationship between spacing variation and small intra-cavity anisotropy is demonstrated experimentally and theoretically. The equivalent fast axis of anisotropy is determined additionally by its correlation with laser intensity tuning of the two orthogonally polarized components. The novel measurement method is successfully tested in several applications. 相似文献
105.
Self-assembly of alkylphosphonic acids on stainless steel was investigated under different conditions. Four different alkylphosphonic acids exhibiting alkyl chain of various size were synthesized and studied: butylphosphonic acid (C4P), octylphosphonic acid (C8P), decylphosphonic acid (C10P), and hexadecylphosphonic acid (C16P). Electrochemistry experiments were extensively carried out in order to determine electrochemical surface blocking of adsorbed layers in function of grafting time. In term of surface blocking, an 8 h modification time was optimal for all alkylphosphonic acids. Longer immersion times lead to degradation of adsorbed layers. For the first time, grafting of C16P was studied under high frequency ultrasound irradiation. Interestingly, grafting process is highly accelerated under sonication and well-covering C16P modified substrates are obtained after 1 h of immersion under ultrasound irradiation. This would allow to elaborate high-quality alkylphosphonic acids modified samples within much shorter times. Water contact angles measurements and X-ray Photoelectrons Spectroscopy (XPS) confirmed presence of adsorbed alkylphosphonic acids on stainless steel surface. A very tight link between electrochemical blocking, surface hydrophobicity and species chemical grafting was established. 相似文献
106.
The effect of heat treatment on the optical and electrical properties of Ge15Sb10Se75 and Ge25Sb10Se65 thin films in the range of annealing temperature 373-723 K has been investigated. Analysis of the optical absorption data indicates that Tauc's relation for the allowed non-direct transition successfully describes the optical processes in these films. The optical band gap (Egopt.) as well as the activation energy for the electrical conduction (ΔE) increase with the increase of annealing temperature (Ta) up to the glass transition temperature (Tg). Then a remarkable decrease in both the Egopt. and ΔE values occurred with a further increase of the annealing temperature (Ta>Tg). The obtained results were explained in terms of the Mott and Davis model for amorphous materials and amorphous to crystalline structure transformations. Furthermore, the deduced value of Egopt. for the Ge25Sb10Se65 thin film is higher than that observed for the Ge15Sb10Se75 thin film. This behavior was discussed on the basis of the chemical ordered network model (CONM) and the average value for the overall mean bond energy 〈E〉 of the amorphous system GexSb10Se90−x with x=15 and 25 at%. The annealing process at Ta>Tg results in the formation of some crystalline phases GeSe, GeSe2 and Sb2Se3 as revealed in XRD patterns, which confirms our discussion of the obtained results. 相似文献
107.
介绍了严格最佳和准最佳(ν,k,1)光正交码的定义,阐述了它们与(ν,k,1)循环差集族的关系。基于Wilson均匀分布差引理和初等数论的基本理论,提出一种最佳(ν,k,1)循环差集族的构造方法,即构造定义在ν阶有限域上满足特定约束条件的k元集合。将该方法用于光正交码的设计中,可以有效地设计一些严格最佳(ν,k,1)光正交码,其中,码长ν为素数,码重k的取值为4、5和6。最后结合具体实例,给出严格最佳(ν,k,1)光正交码的计算机辅助设计方法。同其他设计方法相比,该设计方法既简单又实用,尤其对严格最佳(ν,k,1)光正交码而言,设计效率较高;随着码重k的增加,码的设计效率逐渐降低。 相似文献
108.
用于计算图像分形维的差分盒计数法(DBC)和鲁棒差分盒计数法(RDBC)都对脉冲噪声和斑点噪声较敏感,为此本文提出一种抗噪差分盒计数法(NRDBC),利用剪切局部标准差(TLSD)来计算图像分形维,由于TLSD可有效滤除脉冲噪声和斑点噪声、且对高斯噪声敏感性小,因此NRDBC能对有噪图像进行可靠的分形维估计。利用多分辨率的DBC、RDBC和NRDBC对混有高斯噪声、脉冲噪声和斑点噪声的7种Brodatz纹理以及3种海底的侧扫声纳图像进行了分类实验,结果表明,本文提出的NRDBC可获得更高的识别率和更好的抗噪性。 相似文献
109.
研究Birkhoff系统的约化.首先,列出系统的运动微分方程及其循环积分;其次,构造Birkhoff系统的Routh函数组,利用循环积分约化Birkhoff系统的运动微分方程,并使约化后的动力学方程仍保持Birkhoff方程的形式;最后,举例说明结果的应用.
关键词:
Birkhoff系统
约化
循环积分 相似文献
110.
系统信噪比一直是制约激光探测武器性能的关键性因素之一。为提高系统探测信噪比,利用阿达玛变换方法,在计算模板大小(17.48×17.48mm)和码元数N=255的基础上,详细介绍了Sn循环矩阵的生成,最后选择液晶空间光调制器充当编码模板。通过在液晶面板上不同位置施加不同的电压,利用旋光效应对通过的激光衍射条纹进行控制,按其通过与否(1/0)进行编码。在这一方法指导下进行了系统的仿真实验研究并获得成功。实验结果表明:将阿达玛变换应用于激光光谱测量,在不增加测量次数的情况下,可以有效地提高系统的信噪比。 相似文献