Differential Pulse Polarographic Determination of Nitrate in AUT Solution

A differential pulse polarographic method for the determination of nitrate ion has been developed. With 0.5 M CaCl₂ as supporting electrolyte, NO^?₃ is reduced to give a peak with E_1/2=–1.836 Volt vs. the Ag/AgCl electrode. The differential pulse polarographic peak height is proportional to the nitrate concentration from 20 to 60 ppm. The detection limit for nitrate is 2 ppm in pure aqueous solution. In the determination of 40 ppm nitrate a relative precision (relative standard deviation) of less than 2% was achieved. Nitrite interferes seriously and should be absent if accurate results are required. The method has been applied to the determination of nitrate in Ammonium Uranyl Tricarbonate (AUT) Solution, results obtained by this method are compared to those obtained by ion chromatography. The agreement between the two sets of results suggests that the DPP method can be used with a fair degree of confidence.     

Semilinear Differential Inclusions in Separable Banach Spaces

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两种群竞争模型的奇摄动群

本文应用多重尺度法构造出非线性微分方程组的解的渐近展开式。并用微分不等式的技巧，证明原问题的解的存在性，且给出解的一致有效渐近估计．     

脉冲离散效应对光纤中基于交叉相位调制的脉冲压缩的影响

通过数值模拟，分析了脉冲离散效应对单模光纤正群速色区基于暗孤子交叉不相位调制的脉冲压缩的影响，并提出了减轻这种影响的办法，作者发现，即使暗孤子与被压缩脉冲的中心波长相差很小，离散效应对脉冲压缩的影响也很大，离散效应不仅导致脉冲压缩比的减小和压缩后脉冲峰值功率的降低，而且还导致脉冲压缩所需最佳光纤长度的增加以及压缩后的脉冲呈现不对称性，还发现，若采取本文提出了的非同步耦合法，则可以明显地弥补离散效应     

单个波长到多个波长的变换实验

报道一种波长变换的新方法.采用此方法不需要任何泵浦光便能够直接将信号光变换成在特定谱宽内的任意多个任意波长的变换光,这对于将来的波分复用光网络提供了较大的方便.此波长变换的原理是利用色散位移光纤的非线性效应产生超连续光谱(SC)信号,由于这种SC信号携带有变换光信号,对这种连续谱进行滤波便能够得到所需要的任意频率的变换信号.此变换方式具有变换频带宽,偏振不敏感的优点。     

伴有边界摄动的三阶拟线性向量微分方程边值问题的奇摄动

本文研究伴有边界摄动的三阶拟线性向量微分方程边值问题的奇摄动,在适当的假设下,利用对角化技巧和不动点原理证明了摄动问题解的存在唯一性并给出解的任意阶的一致有效的渐近展开式和余项的估计。     

乙酰丙酮稀土四苯基卟啉配合物的电化学研究

本文指出我国环境保护产业发展中存在的问题，论述了“入关“对我国环境保护产业的影响及应采取的经济和税收政策。     

Investigation of the electrocatalytic behavior of single-wall carbon nanotube films on an Au electrode

The voltammetric behavior of uric acid (UA) was studied with an Au electrode modified with single-wall carbon nanotubes (SWNTs). In 0.1 M HAc-NaAc buffer solution (pH 5.0), the SWNT-modified electrode shows high electrocatalytic activity toward UA oxidation. The electro-oxidation of UA is an irreversible diffusion-controlled process with a diffusion coefficient (D) of 8.85×10⁻⁶ cm² s⁻¹. The peak current increases linearly with the concentration of UA in the range of 4.0×10⁻⁶-7.0×10⁻⁴ M. The detection limit is 1.0×10⁻⁶ M. The SWNT was characterized with scanning electron microscopy (SEM). Furthermore, the SWNT-modified electrode has favorable electrocatalytic activity toward dopamine and norepinephrine. This SWNT-modified electrode can also separate the electrochemical responses of uric acid, norepinephrine and ascorbic acid.