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91.
对形如Nt×Nl型准二维无序系统,只考虑格点之间的最近邻跳跃积分,采用特殊的格点编号方案,在单电子近似下,系统的哈密顿量可表示为简明对称矩阵,借助豪斯荷尔德变换将其约化为对称三对角矩阵,再利用负本征值理论及传输矩阵等方法,对系统态密度、局域长度及电导等电子结构特性进行数值计算. 重点研究了准一维四平行链和五平行链无序系统, 将结果与一维单链、准一维双链及三链系统进行对比,发现随维度的增加,系统的能带有所展宽,能态密度分布发生很大的变化,其峰值数量呈偶数规律增加. 并且在能带中心处存在有局域长度大于系统大小的扩展态,处于这些态下的系统具有较大电导. 从单链到多链,相当于扩大了系统的关联范围,使系统出现了类似非对角长程关联的行为.
关键词:
准二维无序系统
态密度
局域长度
电导 相似文献
92.
93.
在测量微安表内阻的众多方法中,替代法是最简单的方法。本文全面分析了影响测量结果不确定度的因素,求出了实验测量的最佳条件,计算了普通仪器组合下测量结果的相对不确定度。 相似文献
94.
95.
Summary An attempt is made to explain the masses of Z and W± bosons by means of a screening mechanism analogous to charge screening in metals. It considers the effect of the electroweak
force on the distribution of negativekinetic-energy neutrinos, which fills the whole universe (neutrino Fermi sea). The large
weak-boson masses appear to be a direct consequence of the vanishing neutrino mass. 相似文献
96.
Isabel Echeverria Ping-Chung Su Sindee L. Simon Donald J. Plazek 《Journal of Polymer Science.Polymer Physics》1995,33(17):2457-2468
Creep and differential scanning calorimetry (DSC) measurements have been used to study the physical aging behavior of a polyetherimide. Isothermal aging temperatures ranged from 160°C to Tg with aging times ranging from 10 min to 8 days. The only measurable effect of physical aging on the short-time creep curves is a shift of the creep compliance to longer times. Andrade plots of the compliance versus the cube root of time are linear at short times with the slope β decreasing with increasing aging time to a constant value once equilibrium is reached. Log β3 is related directly to the degree to which the creep curves shift to longer times with physical aging, and is used in this work as a measure of physical aging. A reduced curve of log β3 versus log aging time is obtained for the aging temperatures investigated by appropriate vertical and horizontal shifts. The enthalpy change during aging increases linearly with the logarithm of the aging time, ta, leveling off at equilibrium at values which increase with decreasing aging temperature. Hence, both nonequilibrium and equilibrium temperature shift factors can be calculated from the DSC data. Good agreement is observed between the equilibrium temperature shift factors obtained from the creep and DSC data. The temperature dependence of the nonequilibrium temperature shift factors is found to be an order of magnitude smaller than that of the equilibrium shift factors. The time scales to reach equilibrium for enthalpy and for mechanical measurements are found to be the same within experimental error. © 1995 John Wiley & Sons, Inc. 相似文献
97.
Experiments employing photoreflectance spectroscopy have uncovered band bending due to electrically active defects at the Si(1 1 1)–SiO2 interface after sub-keV Ar+ ion bombardment. The band bending of about 0.5 eV resembles that for Si(1 0 0)–SiO2, and both interfaces exhibit two kinetic regimes for the evolution of band bending upon annealing due to defects healing. The healing takes place about an order of magnitude more quickly at the (1 1 1) interface, however, probably because of less fully saturated bonding and higher compressive stress. 相似文献
98.
D. M. Bhardwaj D. C. Jain S. Dalela Ravi Kumar N. L. Saini K. B. Garg 《Physica B: Condensed Matter》2004,350(4):366-374
We have made the XAFS measurements at the Cr–K-edge on natural Indian ruby single crystals (corundum) and its two irradiated samples with fluence 1×1012 Ni6+ and 5×1012 Ni6+ ions/cm2. Irradiated samples show interesting changes in their physical appearance. XANES measurements show progressive decrease in Δoct value on increase of Ni fluence in irradiated samples. EXAFS measurements on these samples show decrease in Cr–O distance on increase of Ni fluence. Lowering of Δoct value is correlated with the increase of Cr–O distance. 相似文献
99.
Marko D. Mihovilovic Bernhard Müller Markus Spina Arjumand I. Durrani Peter Stanetty Georg Dazinger Karl Kirchner 《Monatshefte für Chemie / Chemical Monthly》2006,137(6):785-794
Summary. Recombinant Escherichia coli overexpressing Pseudomonas sp. NCIMB 9872 cyclopentanone monooxygenase (CPMO, EC 1.14.13.16) and Acinetobacter sp. NCIMB 9871 cyclohexanone monooxygenase (CHMO, EC 1.14.13.22) have been utilized in whole-cell Baeyer-Villiger biotransformations of prochiral bicycloketones. A significant difference in substrate acceptance and stereoselectivity was
observed for bicyclo[3.3.0] and bicyclo[4.3.0] substrates. A plausible mechanism of these transformations was established
by means of high level DFT/B3LYP calculations suggesting an essential difference in electronic requirements for a successful
enzymatic conversion, which was similarly encountered in recombinant whole-cell mediated biooxidations. Some of the lactones
produced in the biocatalytic Baeyer-Villiger oxidation represent key intermediates for the synthesis of indole alkaloids. 相似文献
100.
S. A. Savkov 《Fluid Dynamics》2003,38(3):501-506
A dependence of the heat transfer between coaxial cylinders on the energy accommodation coefficient is obtained. The known methods of solving a kinetic equation are compared. 相似文献