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91.
P. Jandera 《Chromatographia》1988,26(1):417-422
Summary The simultaneous dependence of the retention in oligomeric series on the number of repeat structural units and on the mobile phase composition may be described by very similar equations for reversed-phase and for normal-phase systems.In reversed-phase systems, the separation selectivity of the individual oligomers is determined mainly by the size and by the polarity of the repeat structural unit, but the influence of a bulky and polar structural residue may also become important so that even reversed order of elution may be observed for oligomeric series with the same oligomeric units but significantly different end groups. For example, oligoethylene glycols are eluted in the order of increasing size of the oligomers, whereas ethoxylated nonylphenols are eluted in the order of decreasing size.In normal-phase systems, the separation selectivity in oligomeric series depends on the adsorption energy and on the adsorbed area of the oligomeric unit. If the oligomeric unit is small, the concentration of the polar solvent in the binary organic mobile phase has only a minor effect on retention and selectivity, which may be controlled by taking account of the nature of the adsorbent and of the polar solvent or by varying the proportion of two polar solvents in a ternary mobile phase. 相似文献
92.
A simple and reliable HPLC method was developed for the simultaneous quantitative analysis of diethylene glycol (DEG) and propylene glycol (PG) in pharmaceutical products by precolumn derivatization. The derivatization reagent p-toluenesulfonyl isocyanate (TSIC, 10 microL, 20% in ACN v/v) was added to 100 microL of the sample, and then 10 muL of water was added. The resulting derivatives were separated using a C(18)analytical column and a mobile phase composed of 0.01 M KH(2)PO(4)buffer (adjusted to pH 2.5 with phosphoric acid) and ACN (47:53 v/v) at 1 mL/min and 25 degrees C. For detection, UV light at 227 nm was used. The derivatization conditions including reaction time, temperature, and concentration of TSIC were optimized. The calibration curves were linear from 0.062 to 18.6 microg/mL (r(2)= 0.9999) and from 0.071 to 21.3 microg/mL (r(2) = 0.9999) for DEG and PG, respectively. The RSD values of intra- and interday assays were all below 4% for DEG and PG. The proposed method was then successfully applied to analyze two Armillarisin A injection samples and two spiked syrup samples. 相似文献
93.
The effects of the cosurfactants diethylene glycol monoalkyl ether [C
i
H2
i
+1O(CH2CH2O)
j
OH (C
i
E
j
; i=4, 6 and j=1, 2)] on the formation of an oil-in-water styrene (ST) microemulsion and the subsequent free radical polymerization were
studied. For comparison, the data for the C
i
H2
i
+1OH (C
i
OH; i=4, 6) systems obtained from the literature were also included in this work. Sodium dodecyl sulfate was used as the surfactant.
The pseudo three-component phase diagram (macroemulsion, microemulsion and lamellar gel phases) was constructed for each cosurfactant.
The primary parameters selected for the polymerization study are the concentrations of cosurfactant and styrene. The number
of latex particles nucleated is much smaller than that of the microemulsion droplets initially present in the reaction system.
Limited flocculation of the latex particles occurs to some extent during polymerization. Among the cosurfactants investigated,
the C4OH-containing polymerization system is the least stable. By contrast, the diethylene glycol monoalkyl ether group of C
i
E
j
tends to enhance the latex stability. C
i
E
j
is more effective in stabilizing the ST microemulsion and the subsequent polymerization in comparison with the C
i
OH counterpart.
Received: 24 December 1999 Accepted: 9 February 2000 相似文献
94.
The speed of sound (u) has been obtained at a frequency of 8.3 MHz in {CH3CH2OCH2CH2OH + HOCH2CH2(OCH2CH2)nOH}for n = 0, 1, 2, and 3 over the whole composition range of studied binary liquid mixtures, at T = 298.15 K. The speed of sound values were combined with those of our previous results for densities and viscosities to obtain isentropic compressibility (κs), free volume (Vf), and intermolecular free length (Lf). From all these data excess isentropic compressibility (κsE), excess free volume (VfE) and excess intermolecular free length (LfE) as well as the deviations of the speed of sound (Δu) were obtained. The results are interpreted in terms of molecular interactions occurring in the solutions. 相似文献
95.
聚合物对非离子十二烷基聚氧乙烯聚氧丙烯醚浊点的影响 总被引:1,自引:0,他引:1
测定了水溶性高分子聚乙二醇(PEG1000、PEG2000、PEG6000)和聚乙烯吡咯烷酮(PVP-K30、PVP-K90)对三种非离子表面活性剂十二烷基聚氧乙烯聚氧丙烯醚C12H25O(EO )m(PO)nH(LS36,m=3,n=6,LS45,m=4,n=5;LS54,m=5,n=4)浊点的影响。结果表明,聚乙二醇(PEG) 可使三种表面活性剂水溶液浊点降低;而聚乙烯吡咯烷酮(PVP)随其浓度增加,表面活性剂溶液浊点先升高然后又下降;浊点下降程度与聚合物浓度和分子量有关。 相似文献
96.
Urushiol polymer containing B--N bond (PUBN) was synthesized with urushiol-boronpolymer and diethylene triamine. Its structure was characterized by XPS, IR, UV, HPLC,DTA-TG and elemental analysis. The physico-mechanical and anticorrosive propertiesof the polymer were also investigated. The results show that the coating of PUBN canbe hardened in 2h at room temperaure and its film has excellent physico-mechanicalproperties and good anticorrosive properties. 相似文献
97.
ABSTRACTAssociation models like Cubic Plus Association (CPA) equation of state and other Statistical Associating Fluid Theory variants have found widespread use, especially over the recent 30 or so years, and this is not limited anymore to universities and researchers. Industry is beginning slowly to adopt such models for some applications and a few of the association models are now provided by commercial simulators. Association models account explicitly for hydrogen bonding (and other complex) phenomena, and for this reason, they are potentially more useful and more successful than traditional models like cubic equations of state and activity coefficient models. Still, for practical applications, all models are judged by their results and these depend on the availability of experimental data, the number and type of adjustable parameters and the performance of the models for phase equilibria and occasionally also for other properties. We will consider four case studies in this work which, will illustrate some of the capabilities and limitations of these association models in different applications. We will offer a ‘model developer’s’ point of view showing in several cases all stages of model development in order to illustrate what worked, what did not and how it was corrected (when possible). The ‘physics’ and ‘application’ aspects of the models will be in all cases discussed. All results will be shown with the CPA equation of state, although we expect that the overall conclusions will be the same for a wide range of association models. 相似文献
98.
Synthetic preparations,thermal properties and crystallization characterization of PLLA‐PPG block copolymers/clay nanocomposites 下载免费PDF全文
In this study, intercalation of the polymer or pre‐polymer from solution was used to blend different proportions of polylactic acid‐propylene glycol (LPG) copolymers (polypropylene glycols (PPG) of : 700, 1000, 2000) and lipophilic montmorillonite (clay) in order to investigate the melting and the crystalline nature of LPG copolymers/clay nanocomposites via a differential scanning calorimeter (DSC). In addition, changes in the intermolecular force and crystal morphology of the nanocomposites under different crystallization conditions were also studied. For the results, it was observed from a thermogravimetric analyzer that increasing the clay content elevated the weight loss temperature. In non‐isothermal experiments using a DSC, it was discovered that the melting temperature and crystallization temperature of the LPG copolymers also increased with increasing amounts of added clay. The crystallinity of LPG2000 + 1.5 wt% clay was enhanced by 17.00%; in addition, it was found in the crystallinity study that adding clay slowed down the crystallization rate of the LPG copolymers. Moreover, it was found via X‐ray diffractometer (XRD) that the intensity of the diffraction peaks of the 1.5 wt% specimen was stronger than that of the 0.5 wt% specimens. The results imply that copolymers with a longer chain length provide greater space for the crystals to grow, thus making it easier for larger crystals to grow. Conversely, the added clay generates an inhibitory effect in copolymers, reducing the d‐spacing (d) in the XRD. Therefore, adding clay would change the crystallization behavior and the morphology of the LPG copolymers. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
99.
Darja?Rudan-Tasic Cveto?KlofutarEmail author 《Monatshefte für Chemie / Chemical Monthly》2005,136(7):1171-1182
Summary. The electrical permittivity of 1,4-dioxane and benzene solutions of some poly(oxyethylene) glycols up to the average molecular weight of 1590 were measured at 298.15 K. From the experimental data the limiting apparent specific polarization and partial molar polarization were calculated. The electrical dipole moment of the investigated solutes was estimated according to the Debye, Onsager, and Kirkwood theoretical approaches. The calculated dipole moments increase linearly with the square root of the number of monomeric units. The group dipole moment of the polar monomeric unit was calculated from the corresponding limiting partial molar volume, the refraction and polarization of the solute. The factor g, which takes into account the degree of flexibility of the chain, was estimated and found to be greater than 0.92, which means that the lower members of the poly(oxyethylene) glycols possess almost free rotation within the chain backbone of polymer. 相似文献
100.
Summary This paper describes the separation of carbohydrates/glycerol/ethylene glycol/diethylene glycol in alcoholic liquids by TLC.
An in situ reaction already proven in carbohydrate analysis is used for the detection among other things, of diethylene glycol
in low, unpermitted concentrations and is compared with vanadium pentoxide derivatisation also described in the literature.
Only the vanadium pentoxide reaction yields satisfactory results for diethylene glycol.
The information capacity of HPTLC chromatograms is also demonstrated by the simultaneous analysis of 19 samples. Chromatogram
filing is an important consideration, since the lifespans of chromatograms derivatised by the two methods vary considerably.
Plates or sheets treated with dichlorofluorescein can still be evaluated over a period of years, whereas plates treated with
vanadium pentoxide are unusable after only a few weeks. An advantage of the latter procedure, however, is the amenability
of the chromatograms to normal photocopying. 相似文献