非线性电路振荡周期分岔及费根鲍姆常数的测量

设计一种实验装置 ,能显示非线性电路中振荡周期分岔与混沌现象 ;同时 ,测出了该实验装置非线性电阻的伏安特性 ;利用该装置介绍一种测量费根鲍姆常数 (Feigen baumConstant)的方法     

恒载超声雾化制取金属粉末的改进方法

本文提出一种改进的超声雾化制取金属粉末方法。克服了因变幅杆负载变化所引起的粉末产率的周期变化，给出装置的框图及有关的参数和实验结果。     

Accuracy and CPU time of JE-TLM,PLRC-TLM and CRC-TLM methods for plasma medium

The current density (JE), the piecewise linear recursive convolution (PLRC) and the constant convolution recursive (CRC) techniques are developed and integrated into the transmission line matrix (TLM) algorithm. A comparison of these three schemes according to the criteria of accuracy and CPU time is presented. Numerical experiments show that JE provides the most accurate solution and requires the least CPU time; PLRC is nearly as accurate but consumes more CPU time than CRC.     

Stripping chronopotentiometric detection of copper using screen-printed three-electrode system—application to acetic-acid bioavailable fraction from soil samples

Single-use sensors, incorporating a three-electrode configuration (graphite carbon-working electrode; carbon-counter electrode and silver/silver chloride-reference electrode), have been fabricated on a polyester substrate using low cost screen-printing (thick-film) technology. These electrodes coupled with constant current stripping chronopotentiometry (CCSCP), has provided a convenient screening tool for on-site detection of trace levels of copper. Modification of the graphite carbon surface based on in situ deposition of mercury film has been carried out. By appropriate choice of supporting medium and applied constant stripping current, well-resolved and reproducible response for copper was obtained. The stripping response for copper following 2 min deposition was linear over the concentration range examined (10-2000 ppb) with detection limit of 6 ppb using 2 M hydrochloric acid (HCl). Successful applications of the sensing device to acetic-acid bioavailable fraction of a certified reference material (CRM 601, a lake sediment) and soil samples are demonstrated.     

ELECTRON IMPACT STUDIES ON NITROAROYLTHIOPHENES

Abstract

A comparative electron impact study on 2-(2′-nitrobenzoyl)thiophene¹(1), 2-(2′-nitrobenzoyl)-3-methylthiophene²(2) and the corresponding 4′-nitrobenzoyl derivatives (3 and 4)^3,4 is presented. The results suggest that the presence of nitro group β-to the carbonyl affects the general fragmentation pattern recorded in the literature for 2-acyl and 2-aroylthiophenes.     

Relaxational and Associative Aspects of X…HO Bond Complexes

Relaxational and associative aspects of X…HO bond complexes in ternary liquid mixtures of aromatic halogen compounds, namely, chlorobenzene and bromobenzene with ethanol in benzene have been studied at 10 GHz frequency and a temperature range of 30-60°C using dielectric relaxation data. Due to the observed high values of distribution parameter, the relaxation mechanism has been further resolved in terms of two separate relaxation times. The dipole moment, association equilibrium constant and thermodynamic parameters associated with the complexes have also been determined. All the results indicate the occurrence of weak molecular interaction in both the systems. This is in agreement with the ultrasonic results on these systems, reported earlier by Kannappan and Palani.     

COMPLEXATION BEHAVIOR OF POLY(ACRYLIC ACID) AND POLY(ETHYLENE OXIDE) IN WATER AND WATER-METHANOL

To investigate the effects of solvent type and temperature on the interpolymer complexation via hydrogen bonding, a study was made on the complex system of poly(acrylic acid) (PAA) and poly(ethylene oxide) (PEO) in two kinds of solvent systems, pure water and water-MeOH (30 wt%) mixed solvent, at various temperatures using the Ubbelohde viscometer, pH-meter, and UV spectrophotometer. The repeating unit mole ratio at the most optimum complexation as confirmed by the reduced viscosity measurement was shifted from [PEO]/[PAA] ≈ 1.25:1 to 1.5:1 by the addition of methanol to water. From the UV measurement, the deviation from the “isosbestic point” (where the absorbance of the solution remains constant) has presented another evidence for the solvent effect on complexation. In addition, the analysis of the changes in thermodynamic properties upon complexation as well as the fraction of carboxyls associated with PEO oxygens and the complex stability constant as estimated by potentiometric titration at several temperatures reveals that the complex formation in mixed solvent became more unfavorable compared to that in pure solvent at high temperatures above 30°C. This could be explained by considering that in water the hydrophobic interaction as well as the hydrogen bonding may greatly contribute to the stabilization of the polymer complex formed, while in water-methanol the main stabilizing force would be the hydrogen bonding alone.     

基于单片机的超声冲击装置频率跟踪控制和恒幅控制

对超声波冲击以提高焊接接头疲劳强度的装置进行了研究，研制出一台可用于实际冲击处理的样机。该样机以单片机为核心，采用自适应带通滤波器提取超声换能器工作的基波信号，在此基础上获得电流和电压的相位差，根据相位差用模糊控制方法来实现自动频率跟踪；通过电流控制执行机构的输出端振幅，使之恒定不变，对超声冲击处理的质量进行控制。该装置能够适应超声冲击这种负载变化十分剧烈的场合，并可实现准确的频率跟踪和保证冲击处理的质量及效率。