方酸作桥联配体的双核铕螯合物的电致发光

利用方酸作为桥联配体合成了一种双核铕鳌合物Eu_2（DBM）_4（Sq）Phen_2 ．用TPD作空穴传输材料、Eu_2（DBM）_4（Sq）Phen_2作发光材料和载流子传输材料、 8-羟基喹啉和铝（AlQ）作电子传输材料，设计了不同电致发光电特性，结果表明 Eu_2（DBM）_4（Sq）phen_2是一种同时具有空穴和电子传输能力的红色电致发光 材料，在器件结构为ITO/TPD,50nm/Eu_2（DBM）_4（Sq）Phen2，20nm/ALQ，50nm/LiF， 1nm/Al,200nm时，获得了在16V,6.9mA下有最大亮度91cd／m~2的电致发光器件.     

不同光谱预处理对激光诱导击穿光谱检测猪肉中铅含量的影响

为了研究适合激光诱导击穿光谱(LIBS)检测猪肉中重金属铅(Pb)元素含量的光谱预处理方法,将配制的84个猪肉腿肌样品分为校正集和预测集,以相关系数(R)、内部交叉验证均方差(RMSECV)和预测均方根误差(RMSEP)作为评价指标,比较了5种光谱预处理方法对偏最小二乘法(PLS)建模预测效果的影响.结果表明,多元散射校正(MSC)预处理效果最好,定标模型预测值与实验室分析元素检测值的相关系数(R)达到0.9908,RMSECV为0.302,RMSEP为0.282,主成分数为16,18个预测集样品的验证结果的平均相对预测误差(ARPE)为7.8％.说明MSC是LIBS检测猪肉Pb含量的有效光谱预处理方法,该研究为进一步实现食品中重金属快速定量分析提供了方法和数据参考.     

基于主成分回归分析和偏最小二乘回归法的樱桃糖度检测的研究

选用烟台大樱桃为研究对象,采用便携式光谱仪对樱桃糖度进行检测,利用极差标准归一化方法和小波滤波,对其可见-近红外光谱数据进行预处理,分别运用主成分回归分析(PCR)法和偏最小二乘回归(PLSR)法建立了樱桃糖度定量分析模型,并对两种模型进行了比较。实验结果表明:在600~1 100nm波段范围内对樱桃糖度进行检测是可行的,并且PLSR模型的性能优于PCR模型。     

Characterization of a Stable Adaptive Calibration Model Using Near-Infrared Spectroscopy and Partial Least Squares with a Kalman Filter

The calibration model of near-infrared (NIR) spectra established using the Kalman filter-partial least square (partial least squares combined with a Kalman filter) method can be adapted to outdated equipment, environmental changes, external samples, and other applications. However, the variance of the measurement noise estimation for NIR spectrum measurements cannot be easily obtained using Kalman filter-partial least squares; therefore, the variance in the measurement noise is often assumed to be zero for the Kalman filter-partial least square calibration model, which affects the stability of the model. In this study, the measured input and output data were used effectively, and the gamma test method for estimating the measurement noise variance was used to improve the stability of the Kalman filter-partial least square calibration model. First, an accurate estimation of the measurement noise variance was obtained, and accurate modeling was then performed using Kalman filter-partial least squares. Finally, 600 abandoned drilling fluid samples were used to confirm the validity of the proposed method. The Kalman filter-partial least square and gamma test-Kalman filter-partial least square methods are compared. Testing of external samples 401–600 demonstrated that the stability of the Kalman filter-partial least square model decreased. The root mean square error of the prediction of the Kalman filter-partial least square model was 27.135, which was worse than that of the gamma test-Kalman filter-partial least square model (20.307). The validation results show that the proposed method has better stability in tracking the evolution of the NIR spectrometer’s measurement state.     

An equivalent nonlinearization method for analysing response of nonlinear systems to random excitations

I.IntroductionInthelasttwodecades,theresponseofstochasticallyexcitednonlinearsystemshavebeenresearcheddeeplyandwidely.Manyexactandapproximatemethodsofpredictingtheresponseofnonlinearsystemstorandomexcitationshavebeenprop0sedl']'l21.Becauseofv4riousreasons…     

FUNDAMENTALS OF TRANSMISSION FLUCTUATION SPECTROMETRY WITH VARIABLE SPATIAL AVERAGING

Transmission signal of radiation in suspension of particles performed with a high spatial and temporal resolution shows significant fluctuations,which are related to the physical properties of the particles and the process of spatial and temporal averaging.Exploiting this connection,it is possible to calculate the particle size distribution (PSD) and particle concentration.This paper provides an approach of transmission fluctuation spectrometry (TFS) with variable spatial averaging,The transmission fluctuations are expressed in terms of the expectancy of transmission square (ETS) and are obtained as a spectrum,which is a function of the variable beam diameter.The reversal point and the depth of the spectrum contain the information of particle size and particle concentration,respectively.     

滑带土动力学性质试验研究

为了研究地震高烈度区老滑坡的复活变形原因,本文对滑坡滑带土的动力学特性进行了系列研究。本次试验采用扰动土样,制样基本物理指标按滑带土的现场测试指标确定,在不固结不排水条件下,运用MTS810Teststar程控液压伺服土动三轴仪对单个样品逐级放大动应力的分级试验方法进行。侧向压力 (围压 )分别采用 100kPa、20 0kPa、300kPa三级,通过施加轴向振动荷载 (力 )模拟地震作用,振动波形为正弦波,频率为 1Hz,振幅随试样性质确定。研究结果表明,滑带土在动荷载作用下的动力学性质与其静荷载作用下的力学性质有着较大的差异,主要表现在滑带土的动应力与动应变关系的非线性、滞后性及变形积累特点,动弹性模量与动强度的显著降低以及动阻尼比的显著增大特性。这揭示了动力作用下的滑坡复活原因之一,同时为滑坡稳定性评价和动力作用下的变形机制模拟分析提供了基础资料,也为分析滑带土动力本构模型提供了基本内容。     

建立P-S-N曲线的双加权最小二乘法

为充分利用成组疲劳试验数据和疲劳强度试验数据,获得较高精度的P-S-N曲线,提出了一种建立P-S-N曲线的双加权最小二乘法。该方法充分考虑了疲劳试验方法、疲劳试验数据分散性和试件样本容量对P-S-N曲线建立的影响,构建了不同来源误差的分配模型。它首先利用疲劳试验的最小样本容量判据处理成组试验数据,导出试验数据分布p分位点的置信区间长度,并进行第一次加权拟合。再结合疲劳强度试验数据,进行第二次加权拟合,推导出了任意可靠度下的P-S-N曲线。作者对17组金属材料和PMMA(聚甲基丙烯酸甲酯)材料进行了统计分析以验证所建立的P-S-N曲线的拟合能力、合理性和预测精度,结果表明建立的P-S-N曲线具有较高的精度和可信度。     

双重点最小二乘配点无网格法

配点类无网格法需要计算近似函数的二阶导数,因而在移动最小二乘(MLS)近似中至少要采用二次基函数。本文利用Voronoi图对双重点移动最小二乘近似法进行了改进,建立了基于Voronoi图的双重点移动最小二乘近似(VDG),并利用加权最小二乘法离散微分方程,导出了双重点最小二乘配点无网格法(MD GLS)。该方法将求解域用节点离散,并以节点为生成点建立Voronoi图,取Voronoi多边形的顶点为辅助点。近似函数及其二阶导数的计算过程可分解为两个步骤:首先用场函数节点值拟合辅助点处近似函数的一阶导数,再以辅助点处近似函数的一阶导数值拟合节点处近似函数的二阶导数。由于在每一步中只需计算MLS形函数及其一阶导数,这种近似方法需要较少的影响点和较小的影响域。同时借助于Voronoi结构的优良几何性质,可以快速地搜索影响点。研究表明,与基于MLS的加权最小二乘无网格法(MWLS)相比,这种方法可以显著提高计算效率,并且在精度和收敛性方面也有所改善。     

基于半参数回归模型的最小一乘局部线性算法

根据最小一乘准则,推导出最小一乘局部线性估计的计算方法,并通过对模拟数据的计算和分析,对比最小一乘核算法和最小二乘局部线性算法,验证了最小一乘局部线性算法是一种有效的,稳健的估计方法,并且有降低边界效应的作用．