Pd OECC薄膜的表面增强拉曼散射

利用较高检测灵敏度的 SERS技术 ,对浓度较低的 Pd OECC吸附在银表面上的薄层在室温下进行了拉曼谱的测量。得到 Pd OECC在强光破坏前后的 SERS光谱。在强光照射下 ,β-胡萝卜素分子的 SERS光谱的散射强度明显降低 ,且线宽增加 ,说明强光照射不但改变了β-胡萝卜素的构象 ,而且也改变了 β-胡萝卜素分子所处的微环境。其结果与强光照射前后吸收光谱的变化相一致。另外 ,没有观察到 Pd OECC薄层与银镜相互作用的其它新振动峰或Pd OECC中其它振动峰峰型的变化 ,可见 Pd OECC在银镜表面保持原来的状态 ,这证明SERS技术在光合作用光破坏机理研究中的可行性     

一种大粒子溶液光散射图的改进作法

用光散射法测定高聚物的分子量及分子尺寸时,对于分子尺寸大于λ/20的“大粒子”分子,其光散射计算的基本公式为:     

激光诱导直接化学光刻

本文利用Ar~+激光倍频257.3nm进行扫描蚀刻Si、GaAs和Zn片,获得的最小光刻线宽为1.2μm,给出蚀刻深度与光强/扫描速度的关系曲线等参量,首次利用光刻技术估计卤素自由基的扩散系数、自由路程以及激光聚焦光斑大小,以及观察到阈值现象。     

两端对称负折射率缺陷复合光子晶体:多通道滤波和光开关

采用传输矩阵法对两端对称负折射率缺陷复合光子晶体结构[D(AB)mD]N的透射特性进行了研究.结果表明:当N=2时,该结构透射谱的禁带出现两个完全共振透射峰,当N增加时,每个共振透射峰又分裂为N-1条；当复合光子晶体的层数m逐渐增加时,透射峰的品质因子逐渐提高,且分裂的共振透射峰距离逐渐减少；既为该结构实现高品质的多通...     

生物合理设计光系统Ⅱ抑制剂研究：Ⅳ.新型取代氰基丙烯酸乙酯类化合？…

基于包获的受体光合作用Ｄ１蛋白结构模型，运用生物合理设计方法，设计并合成了保留氰基丙烯酸酯类化合物基本结构框架的标题化合物，对所合成的化合物进行了光合作用希尔反应抑制活性的初步测试，结果表明，部分化合物显示出一定的活性。     

Ruby fluorescence pressure scale： Revisited

Effect of non-hydrostatic stress on X-ray diffraction in a diamond anvil cell (DAC) is studied. The pressure gradient in the sample chamber leads to the broadening of the diffraction peaks, which increase with the hkl index of the crystal. It is found that the difference between the determined d-spacing compressive ratio d/d0 and the real d-spacing compressive ratio dr/d0 is determined by the yield stress of the pressure transmitting media (if used) and the shear modulus of the sample. On the basis of the corrected experiment data of Mao et al. (MXB86), which was used to calibrate the most widely used ruby fluorescence scale, a new relationship of ruby fluorescence pressure scale is corrected, i.e., P = (1904/9.827)[(1+λ/λ0)9.827-1].     

Quantum phase transitions of fermionic atoms in an anisotropic triangular optical lattice

The effect of anisotropy caused by a confining potential on the properties of fermionic cold atoms in a triangular optical lattice is systematically investigated by using the dynamical cluster approximation combined with the continuous time quantum Monte–Carlo algorithm.The quantum phase diagrams which reflect the temperature–interaction relation and the competition between the anisotropic parameter and the interaction are presented with full consideration of the anisotropy of the system.Our results show that the system undergoes a transition from Fermi liquid to Mott insulator when the repulsive interaction reaches a critical value.The Kondo effect also can be observed in this system and the pseudogap is suppressed at low temperatures due to the Kondo effect.A feasible experiment protocol to observe these phenomena in an anisotropic triangular optical lattice with cold atoms is proposed,in which the hopping terms are closely related to the lattice confining potential and the atomic interaction can be adjusted via the Feshbach resonance.     

光前驱波

文章回顾了近一百年来光前驱波的研究历史及最新的进展.自爱因斯坦的狭义相对论发表以来,真空中的光速不变原理已经被广泛地接受.然而对光在介质中的传播速度,由于复杂的色散关系,却一直存在不同的解读,尤其是对光载信息传播速度以及单个光子的运动.光前驱波的研究旨在回答这个问题.作者和其研究团队在最近的研究中找到了前驱波在光学波段的清晰的证据,并首次发现了单光子波包里的光前驱波.研究结果表明,光载信息传播速度不可能超光速,单光子的运动满足真空光速极限原理,即便是在所谓的“超光速”(群速度超光速)介质中.