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111.
Yusuf Akbaba Halis Türker Balaydın Süleyman Göksu Ertan Şahin Abdullah Menzek 《Helvetica chimica acta》2010,93(6):1127-1135
3,4‐Dibromo‐5‐[2‐bromo‐3,4‐dihydroxy‐6‐(methoxymethyl)benzyl]benzene‐1,2‐diol ( 2 ), a natural product, has been synthesized for the first time starting from (3‐bromo‐4,5‐dimethoxyphenyl)methanol ( 5 ) in five steps and with an overall yield of 34%. The reaction of some methoxymethyl‐substituted aryl methyl ethers with BBr3, followed by the addition of MeOH, afforded the corresponding methoxymethyl‐substituted arylphenols in high yields. 相似文献
112.
A series of dibenzo-18-crown-6 lariat ethers containing two C7H15 (11), (CH2)2C6F13 (14), (CH2)2C8F17 (15), NHC7H15 (18) and NHCH2C6F13 (19) sidearms were prepared and the single crystal X-ray structure of cis-4,4′-di(1H,1H,2H,2H-perfluorodecyl)-dibenzo-18-crown-6 (15a) is reported. The “light fluorous” dibenzo-18-crown-6 ether (14) has emerged as a stable and robust PTC catalyst, which can be recycled efficiently by fluorous solid-phase extraction, and gives better PTC catalytic activity compared to the parent, non-fluorinated PTC catalyst, dibenzo-18-crown-6, and the alkylated derivative (11) in aliphatic and aromatic nucleophilic substitutions. 相似文献
113.
Rajoshree Bandyopadhyay 《Journal of organometallic chemistry》2010,695(7):1012-10984
The treatment of tin(II) trifluoromethanesulfonate with three differently-sized crown ethers [12]crown-4, [15]crown-5 and [18]crown-6 results in the formation of tin complexes that exhibit dramatically different structural features. The compounds are investigated using experimental techniques and density functional theory calculations. 相似文献
114.
Dmitry S. Perekalin Valentin V. Novikov Maddalena Corsini Alexander R. Kudinov 《Journal of organometallic chemistry》2010,695(8):1200-1204
The reactions of benzo-15-crown-5 and dibenzo-18-crown-6 with 1 equiv. of [(mes)Ru(MeNO2)3]2+ (mes = 1,3,5-C6H3Me3) give the mononuclear complexes [(mes)Ru(η6-benzo-15-crown-5)]2+ (1) and [(mes)Ru(η6-dibenzo-18-crown-6)]2+ (2) in 50% yield. Similar reaction with 2 equiv. of [(mes)Ru(MeNO2)3]2+ produces the dinuclear complex [(μ-η6:η6-dibenzo-18-crown-6)Ru2(mes)2]4+ (3) in 96% yield as a 2:3 mixture of cis- and trans-isomers. Structures of 2(OTf)2 and trans-3(OTf)4 were confirmed by X-ray diffraction. The NMR titration showed that mononuclear dications 1 and 2 bind Na+ ion less effective (Ka = 600 and 250 M-1) than free benzo-15-crown-5 and dibenzo-18-crown-6 (Ka = 2 × 105 and 5 × 106 M−1). The dinuclear tetracation 3 does not bind Na+ within measurable limits of NMR titration method. The electrochemical behaviour of complexes 1-3 was studied in propylene carbonate solution. They exhibit a partially chemically reversible Ru(II)/Ru(I) reduction, which in the case of the dinuclear complex 3 proceeds through two slightly separated steps. The redox activity of the complexes is substantially unaffected by the presence of sodium ion. 相似文献
115.
Three sorbent materials (A18C6-MS, DA18C6-MS and AB18C6-MS) based on the crown ether ligands, 1-aza-18-crown-6, 1,4,10,13-tetraoxa-7,16-diazacyclo octadecane and 4′-aminobenzo-18-crown-6, respectively, were prepared by the chemical immobilization of the ligand onto mesoporous silica support. The sorbents were characterized by FT-IR, scanning electron microscopy-energy dispersive X-ray microanalysis, elemental analysis and nitrogen adsorption-desorption test. The applicability of the sorbents for the extraction of biogenic amines by the batch sorption method was extensively studied and evaluated as a function of pH, biogenic amines concentration, contact time and reusability. Under the optimized conditions, all the sorbents exhibited highest selectivity toward spermidine (SPD) compared to other biogenic amines (tryptamine, putrescine, histamine and tyramine). Among the sorbents, AB18C6-MS offer the highest capacity and best selectivity towards SPD in the presence of other biogenic amines. The AB18C6-MS sorbent can be repeatedly used three times as there was no significant degradation in the extraction of the biogenic amines (%E > 85). The optimized procedure was successfully applied for the separation of SPD in food samples prior to the reversed-phase high performance liquid chromatography separation. 相似文献
116.
13-Crown-4,16-crown-5,dibenzo-12-crown-4 and dibenzo-14-crown-4 were synthesized by a one-pot microwave-assisted procedure in good yields.Irradiation of diols and dichlorides in the presence of sodium hydroxide in DMSO gave title crown ethers presumably within a template effect. 相似文献
117.
Ljerka Tuek-Boi Christophe Pannecouque Erik De Clercq Jan Balzarini 《Polyhedron》2009,28(16):3449-3458
The eco-friendly synthesis, spectroscopic (IR, MS, 1H and 13C NMR) study and biological (cytostatic, antiviral) activity of sodium and potassium benzeneazophosphonate complexes, obtained by reaction in the solid state under microwave irradiation of the alkali salts of ethyl [α-(4-benzeneazoanilino)-N-benzyl]phosphonic acid and [α-(4-benzeneazoanilino)-N-4-methoxybenzyl]phosphonic acid with crown ethers containing 18-membered (dibenzo-18-crown-6 and bis(4′-di-tert-butylbenzo)-18-crown-6), 24-membered (dibenzo-24-crown-8) and 30-membered (dibenzo-30-crown-10) macrocyclic rings, have been described. The simple work-up solvent free reaction is an efficient green procedure for the formation of mononuclear crown ether complexes in which the sodium/potassium ion is bound to oxygen atoms of the macrocycle and the phosphonic acid oxygen. The free crown ethers, alkali benzeneazophosphonate salts and their complexes were evaluated for their cytostatic activity in vitro against murine leukemia L1210, murine mammary carcinoma FM3A and human T-lymphocyte CEM and MT-4 cell lines, as well as for their antiviral activity against a wide variety of DNA and RNA viruses. The investigated compounds showed no specific antiviral activity, whereas all the free crown ethers and their complexes demonstrated cytostatic activity, which was especially pronounced in the case of bis(4′-di-tert-butylbenzo)-18-crown-6 and its complexes. 相似文献
118.
Junfeng Zhou Xiaochen Dong Tao Chen Qiang Yang Qiaohua Tan Jianjun Wang 《European Polymer Journal》2007,43(5):2088-2095
A series of well-defined two-armed polymers containing a crown ether core, poly(stearyl methacrylate)-crown ether-poly(stearyl methacrylate) (PSMA-crown-PSMA), with different molecular weight were synthesized via atom transfer radical polymerization (ATRP). The resultant polymers were characterized by 1H NMR and GPC. The self-assembly behaviors of this kind of polymer in selective solvents were studied by TEM, and it was found that polymers with different molecular weight can directly self-assemble into hollow spheres, solid spheres and a monolayer film with regular pores by varying molecular weight and water content. The possible molecular packing motels for their self-assembly behaviors were proposed. 相似文献
119.
We quantitatively modeled the volume phase transition of a hydrogel containing a crystalline colloidal array with a crown
ether ligand which binds Pb2+. The hydrogel volume response and the wavelength diffracted depend on the Pb2+ concentration and on both the ionic strength and the valence of the nonbinding ionic species. We successfully modeled the
response of this hydrogel Pb2+ sensor to ionic strength and the cation valence of the added salts.
Figure Cation identity dependence of crown ether photonic crystal Pb+ sensing 相似文献
120.
Chuqiao Tu Kazimierz Surowiec Richard A. Bartsch 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(3-4):361-366
A di-ionizable p-tert-butylcalix[4]arene-1,3-thiacrown-5 ether extractant was synthesized. Its cone conformation and polyether ring attachment
regioselectivity were verified by NMR spectroscopy. The metal ion-complexing properties of this ligand were evaluated by solvent
extractions of metal cations from aqueous solutions into chloroform. The ligand was found to be an efficient extractant with
Ba2+ selectivity in competitive solvent extraction of alkaline earth metal cations. It also exhibits high extraction ability for
Pb2+ and for Hg2+ in single species solvent extractions. 相似文献