全文获取类型
收费全文 | 293篇 |
免费 | 11篇 |
国内免费 | 59篇 |
专业分类
化学 | 197篇 |
晶体学 | 2篇 |
力学 | 8篇 |
综合类 | 1篇 |
数学 | 42篇 |
物理学 | 113篇 |
出版年
2023年 | 12篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 12篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2015年 | 11篇 |
2014年 | 4篇 |
2013年 | 19篇 |
2012年 | 7篇 |
2011年 | 12篇 |
2010年 | 9篇 |
2009年 | 12篇 |
2008年 | 16篇 |
2007年 | 23篇 |
2006年 | 10篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 8篇 |
2002年 | 8篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 13篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 5篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有363条查询结果,搜索用时 15 毫秒
61.
The evolution of an infinite population of interacting point entities placed in is studied. The elementary evolutionary acts are death of an entity with rate that includes a competition term and independent fission into two entities. The population states are probability measures on the corresponding configuration space and the result is the construction of the evolution of states in the class of sub-Poissonian measures, that corresponds to the lack of clusters in such states. This is considered as a self-regulation in the population due to competition. 相似文献
62.
Abstract The two 1-aryl-5-methyl-1,2,3-triazole derivatives were prepared by the 1-aryl-5-methyl-1,2,3-triazol-4-carboxylic acids 3. The yielded products 4a–b were confirmed by NMR, MS, IR spectra. We investigated the crystalline structure of compounds 4a and 4b. Compound 4a, C9H8BrN3, Mr = 238.09, crystallizes in the monoclinic space group P2(1)/n with unit cell parameters a = 11.660(2), b = 7.668(2), c = 11.818(2) ?, α = 90.00, β = 116.01(3), γ = 90.00o. V = 949.6(3) ?3, Z = 4, Dx = 1.665 Mg m−3. The final R was 0.0477. Compound 4b, C13H11N3, Mr = 209.25, crystallized in the orthorhombic space group Pbca with unit cell parameters a = 10.373(2) ?, b = 11.691(2) ?, c = 17.579(4) ?, α = 90.00o, β = 90.00o, γ = 90.00o, V = 2131.8(7) ?3, Z = 8, D
m = 1.304 Mg m−3. The final R was 0.0565.
Index Abstract The two 1-aryl-5-methyl-1,2,3-triazole derivatives were prepared by the 1-aryl-5-methyl-1,2,3-triazol-4-carboxylic acids 3. The yielded products 4a–b were confirmed by NMR, MS, IR spectra. We investigated the crystalline structure of compounds 4a and 4b. Compound 4a, C9H8BrN3, Mr = 238.09, crystallizes in the monoclinic space group P2(1)/n with unit cell parameters a = 11.660(2), b = 7.668(2), c = 11.818(2) ?, α = 90.00, β = 116.01(3), γ =90.00o. V = 949.6(3) ?3, Z = 4, Dx = 1.665 Mg m−3. The final R was 0.0477. Compound 4b, C13H11N3, Mr = 209.25, crystallized in the orthorhombic space group Pbca with unit cell parameters a = 10.373(2) ?, b = 11.691(2) ?, c = 17.579(4) ?, α = 90.00o, β = 90.00o, γ = 90.00o, V = 2131.8(7) ?3, Z = 8, D
m = 1.304 Mg m−3. The final R was 0.0565.
相似文献
63.
64.
In this article we make a full study of the class of non-degenerate real planar quadratic differential systems having all
points at infinity (in the Poincaré compactification) as singularities. We prove that all such systems have invariant affine
lines of total multiplicity 3, give all their configurations of invariant lines and show that all these systems are integrable
via the method of Darboux having cubic polynomials as inverse integrating factors. After constructing the topologically distinct
phase portraits in this class we give invariant necessary and sufficient conditions in terms of the 12 coefficients of the
systems for the realization of each one of them and give representatives of the orbits under the action of the affine group
and time rescaling. We construct the moduli space of this class for this action and give the corresponding bifurcation diagram.
Dedicated to Professor Zhifen Zhang on the occasion of her 80th birthday 相似文献
65.
Jacek Thiel Władysław Boczoń Waleria Wysocka 《Monatshefte für Chemie / Chemical Monthly》2000,131(10):1073-1081
Summary. The bisquinolizidine carbinolamine 17-hydroxylupanine was synthesized de novo from lupanine using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; its structure was established by NMR techniques. The equatorial
position of the hydroxy group as well as the prevailing boat form of ring C were determined. As expected, the carbinolamine
converted into the C17=N16 anhydronium perchlorate upon treatment with HClO4. NMR analysis of the salt revealed a conformational equilibrium within rings A and D, whereas rings B and C remain rigid.
Received March 13, 2000. Accepted March 21, 2000 相似文献
66.
利用多组态Dirac-Fock(MCDF)方法与准相对论组态相互作用方法,分别详细计算了低Z、中Z和高Z原子(离子)各个壳层上电子的束缚能、平均轨道半径、总束缚能、激发能、精细结构能级以及类Ne等电子系列离子的2p53s 1,3P1-2p6 1S0跃迁能,并且对这两种方法的结果进行了数值比较. 相似文献
67.
68.
69.
用组态相互作用方法,研究了Nb30+,Na-like2p53l3l′(l,l′=0,1,2)内壳层电子激发跃迁的自电离速率和自电离分支比,结果表明自电离速率对自电离分支比的贡献最大。 相似文献
70.
实验获得了碳族原子铅的偶宇称J=0和2的束缚Rydberg态能级,利用六通道模型分析了铅原子J=2的束缚Rydberg系列之间强烈的组态相互作用对电离光谱的影响. 相似文献