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131.
The effect of pressure on the conductivity of fast ion conducting AgI-Ag2O-MoO3 glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application
of cluster model to the ionic glasses.
Contribution No. 258 from the Solid State and Structural Chemistry Unit. 相似文献
132.
Magnetic nanocomposites can be controlled and tailored to provide the desired mechanical, physical, chemical, and biomedical properties depending on the final applications. The coating of ferrite nanoparticles with polymers affords the possibility of minimizing agglomeration in large-scale commercial synthesis of nanocomposite materials. The process of coating not only provides effective encapsulation of individual nanoparticles, but also controls the growth in size, thus, yielding a better overall size distribution. In this paper, in-situ polymerization of aniline was carried out in different concentration of the ferrofluid with the aim to obtain agglomerate free nanocomposites. The role of the ferrite concentration was investigated by the spectral, morphological, conductivity, and magnetic properties of Fe3O4/polyaniline (PANI) nanocomposites. XRD revealed the presence of spinel phase of Fe3O4 and the particle size was calculated to be 14.3 nm. Spectral analysis confirmed the formation of PANI encapsulated Fe3O4 nanocomposite. Conductivity of the nanocomposites was found to be in the range of 0.001–0.003 S/cm. Higher saturation magnetization of 3.2 emu/g was observed at 300 K, revealing a super paramagnetic behavior of this nanocomposite. 相似文献
133.
It is shown that the interfacial attraction between low-energy bodies immersed in aqueous media, known as “hydrophobic” interaction, can be quantitatively accounted for by, mainly, the hydrogen-bonding energy of cohesion of water, plus, to a very minor extent, a van der Waals-Lifshitz attraction between the Immersed law-energy bodies. 相似文献
134.
Comparison of Bottom-up Filling in Electroless Plating with an Addition of PEG,PPG and EPE 总被引:1,自引:0,他引:1
The bottom‐up filling capabilities of electroless copper plating bath with an addition of additives, such as polyethylene glycol (PEG), polypropylene glycol (PPG) and triblock copolymers of PEG and PPG with ethylene oxide terminal blocks termed EPE, were investigated by the cross‐sectional scanning electron microscopy (SEM) observation of sub‐micrometer trenches. Though three additives had inhibition for electroless copper deposition, the suppression degrees of three additives were different. EPE‐2000 had the strongest suppression for electroless copper deposition, and the suppression of PEG‐2000 was the weakest. The bottom‐up filling capability of electroless copper was investigated in a plating bath containing different additives with the concentration of 2.0 mg/L. The cross‐sectional SEM observation indicated the trenches with the width of 280 nm and the depth of 475 nm were all completely filled by the plating bath with an addition of EPE‐2000, but the trenches were not completely filled by the plating bath with an addition of PEG‐2000 or PPG‐2000, and some voids appeared. Linear sweep voltammetry measurement indicated that three additives all inhibited the cathodic reduction reaction and the anodic oxidation reaction, and the inhibition of EPE‐2000 was the strongest among three additives, which agreed with that of the deposition rate of electroless copper. Significant differences in surface roughness of deposited copper film were observed by UV‐visible near‐infrared for different suppressors, and the bright and smooth of deposited copper film were in accordance with the inhibition of three additives. 相似文献
135.
A. Radulescu D. Schwahn J. Stellbrink M. Monkenbusch L. J. Fetters D. Richter 《Journal of Polymer Science.Polymer Physics》2011,49(2):144-158
Multiblock ethylene‐1‐butene copolymers (PEB‐n) with graded ethylene content (where n is the number of ethyl branches per 100 backbone carbons) represent efficient cold filter plugging point (CFPP) depressants for crude oils and middle distillates. The aggregation behavior and the interaction with wax molecules of a tetrablock PEB‐2.6/PEB‐6.0/PEB‐10.9/PEB‐13.2 and triblock PEB‐6.5/PEB‐8.9/PEB‐10.1 copolymers in decane solutions were investigated over a wide temperature range by combining different small‐angle neutron scattering techniques and optical microscopy. The experimental results revealed in the decrease of temperature formation and evolution of multisized structural levels showing a hierarchical organization on the length scale from 1 nm up to 10 μm. One‐dimensional polymer aggregates arising as initial structures associate and branch that lead to the occurrence of complex macroaggregates with diffusive interfaces and sizes of several microns. The one‐dimensional copolymer structure shows longitudinal density modulation and micellar‐like substructures in neat polymer solutions. When wax is added, this structure becomes more homogeneous in decrease of temperature as a consequence of the cocrystallization of wax and copolymer. The wax crystallization in board‐like objects of much smaller size than required by the CFPP criterion of oil and refinery industry (filter mesh size of 45 μm) is templated and controlled by the assembling features of the crystalline–amorphous PEB‐n multiblock copolymers. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
136.
Krzysztof Jankowski Anna Jerzak Anna Sernicka-Poluchowicz Ludwik Synoradzki 《Analytica chimica acta》2001,440(2):67-221
A method for multielement determination of major elements in polymer additives by microwave induced plasma atomic emission spectrometry (MIP-AES) has been elaborated. Microwave digestion with nitric acid was selected for sample preparation because of its speed and versatility. Sodium nitrate was added to the digestion mixture in order to reduce phosphorus losses. The precision obtained varied between 2 and 4.5% depending on the element determined. The accuracy of the method was studied by analyzing the Spex 5-element oil standard. The method was applied to a variety of commercial and in-house prepared compositions. 相似文献
137.
Scott D. Noblitt Florian M. Schwandner Susanne V. Hering Jeffrey L. Collett Jr. Charles S. Henry 《Journal of chromatography. A》2009,1216(9):1503-1510
A sensitive and selective separation of common anionic constituents of atmospheric aerosols, sulfate, nitrate, chloride, and oxalate, is presented using microchip electrophoresis. The optimized separation is achieved in under 1 min and at low background electrolyte ionic strength (2.9 mM) by combining a metal-binding electrolyte anion (17 mM picolinic acid), a sulfate-binding electrolyte cation (19 mM HEPBS), a zwitterionic surfactant with affinity towards weakly solvated anions (19 mM N-tetradecyl,N,N-dimethyl-3-ammonio-1-propansulfonate), and operation in counter-electroosmotic flow (EOF) mode. The separation is performed at pH 4.7, permitting pH manipulation of oxalate's mobility. The majority of low-concentration organic acids are not observed at these conditions, allowing for rapid subsequent injections without the presence of interfering peaks. Because the mobilities of sulfate, nitrate, and oxalate are independently controlled, other minor constituents of aerosols can be analyzed, including nitrite, fluoride, and formate if desired using similar separation conditions. Contact conductivity detection is utilized, and the limit of detection for oxalate (S/N = 3) is 180 nM without stacking. Sensitivity can be increased with field-amplified sample stacking by injecting from dilute electrolyte with a detection limit of 19 nM achieved. The high-sensitivity, counter-EOF operation, and short analysis time make this separation well-suited to continuous online monitoring of aerosol composition. 相似文献
138.
Ann‐Christine Albertsson Geta David Clara Strandberg Doina Bilba Carmen Paduraru 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):5889-5898
Poly(trimethylolpropane trimethacrylate) microspheres with a narrow size distribution were obtained by precipitation polymerization. They were subsequently modified by surface grafting with acrylic acid in a polar ethanol–water reaction medium, without stabilizer, yielding core‐shell particles with diameters in the micrometer range. The resulting polymeric material was characterized by SEM and potentiometric titration, FTIR spectroscopy, and thermal analysis. It was shown that the particle characteristics (size, size distribution, and functionality) obtained by this straightforward procedure can be controlled by modifying the synthesis parameters (monomer concentration, agitation rate, and temperature). The high functionality, the chemical and physico‐mechanical stability, as well as the possibility to control the performances of the resulting polymeric materials by synthesis allow its applications in various areas. Envisaging separation and catalysis domains, Cu(II), Cd(II), and Cr(III) uptake capacity from aqueous solutions was investigated under noncompetitive conditions as a function of synthesized particle functionality, time, and pH range. It was also found that the addition of the carboxylated microparticles to polyethylene stabilized with α‐tocopherol improved the thermo‐oxidative behaviour of the polymeric material. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5889–5898, 2005 相似文献
139.
140.
Dragana Vasiljevic Jelena Djuris Sergej Jakimenko Svetlana Ibric 《Journal of Dispersion Science and Technology》2017,38(12):1732-1737
In presented research, multiple W/O/W emulsions were developed by using experimental design method. A 24-1 fractional factorial design was performed by varying the following input parameters: primary polymeric emulsifier (PEG 30-dipolyhydroxystearate) concentration (0.8% and 2.4%), secondary polymeric emulsifier (Poloxamer 407) concentration (0.8% and 1.2%), electrolyte magnesium sulfate heptahydrate (0.08% and 0.4%) and electrolyte sodium chloride (0.08% and 0.4%). Multiple emulsions were prepared by a two-step emulsification process. Obtained emulsions were characterized with rheological measurements, conductivity and centrifugation tests. Factorial analysis revealed that the concentration of the primary emulsifier was the predominant factor influencing the phase separation, conductivity and maximal apparent viscosity. Additionally, electrolyte magnesium sulfate heptahydrate was more efficient in stabilizing these systems, compared to sodium chloride. The applied fractional factorial design method enabled determination of the optimal concentrations of the primary and secondary emulsifier, as well as the concentration of electrolytes, in order to obtain W/O/W emulsions with desired maximal apparent viscosities, low values of conductivity and without phase separation after centrifugation. 相似文献