pH配位滴定法同时测定铜和锌

本文将多元线性回归法应用于ｐＨ配位滴定法中，提出了金属离子混合液中各组分同时测定的方法原理，并对铜，锌合成样品进行了测定，得到满意的结果。     

Electrochemical sensor for the detection and presumptive identification of quinolone and tetracycline residues in milk

A novel application of an electrochemical biosensor is here employed as analytical method for the detection and presumptive identification of antimicrobial drug residues in milk. The measurement was based on carbon dioxide production rate in relation to inhibition of microbial grow (Escherichia coli ATCC 11303). In this pilot study quinolone and tetracycline residues have been taken into consideration because use of these last in livestock production has been identified as area of particular concern. The experimental approach and analytical method developed appear adequate for the purpose, and compared to older screening methods as, for example, the microbial inhibition assays and immunoassays, offers the advantages of (i) very short analysis time (about 120 min); (ii) smaller sample amount (approximately 0.5 mL); (iii) no sample treatment (iv) good precision; and (v) the possibility of following, in a continuous manner, the inhibition process. Moreover, sensitivity of electrochemical biosensor system is resulted very high considering that for all quinolones and tetracyclines investigated it has been possible detect a residue concentration below or equal to 25 μg L⁻¹. Under this point of view, it must be considered that the maximum residue limits fixed by UE for quinolones and tetracyclines in milk are, at present, all higher of this concentration.     

Influence of Aprotic Solvent on Selectivity of an Amperometric Sensor with Nafion Membrane

This paper presents the results of investigation on selectivity of the sulfur dioxide amperometric sensor with Nafion membrane in the presence of carbon monoxide and nitrogen dioxide as the interferents. There have been compared selectivity coefficients, for the sensors containing the following internal electrolytes: solution of sulfuric acid (concentration 5 mol dm^?3) in pure water (A) and solution of sulfuric acid (concentration 5 mol dm^?3) in mixed solvent dimethylsulfoxide‐water with an DMSO: H₂O mole ratio of 1 : 2 (B). Values of the selectivity coefficients have been calculated based on the calibration curves. Analysis of both calibration curves and selectivity coefficients plays a significant role in optimization of a working point of a particular sensor. The investigated sensor operates in a three‐electrode system, where the working and counter electrodes are vacuum sublimation deposited on the membrane surface.     

用硅双结型色敏器件测量色温

提出了一种用硅双结型色敏器件测量色温的方法．在合理的测控电路下，硅双结型色敏器件的电流对数比与实验灯泡的色温值呈良好的单值对应，经单片机处理后可以得到分段线性关系．通过对电流对数比与波长随线的数据拟合，结果表明，用硅双结型色敏器件测量色温，其测量温度可以到10^4K以上，精度可以达到10K．本文的方法与传统方法相比减少了工作量，降低了费用，具有通用性和实用价值．     

Fast characterization of foodstuff by headspace mass spectrometry (HS-MS)

The field of the rapid characterization of products by HS-MS is reviewed. The general principle of HS-MS systems consists of introducing volatile components present in the HS of a sample without prior chromatographic separation into the ionization chamber of a mass spectrometer. The spectrum resulting from simultaneous ionization and fragmentation of the mixture of molecules introduced constitutes a “fingerprint” that is characteristic of the product being analyzed. Exploitation of this spectral information allows one determine the composition of the sample.     

pH值对壳聚糖/羧甲基壳聚糖水凝胶溶胀行为的影响

利用壳聚糖与羧甲基壳聚糖制备了一系列新型的水凝胶，研究了pH值对水凝胶溶胀度、微观结构和基团结构的影响．结果表明，壳聚糖与羧甲基壳聚糖水凝胶的溶胀行为和微观结构均表现出pH值敏感性，但随着羧基的引入，水凝胶的最低溶胀度从pH7．O移向pH3．O．红外光谱证明，水凝胶的pH敏感行为是由基团结构的变化引起的．     

太阳米粒结构相关哈特曼-夏克波前传感模拟研究

基于互相关因子和绝对差分算法以及相关哈特曼－夏克波前传感器的基本原理，根据室内模拟太阳米料结构研究了低对比度扩展目标情况下应用相关哈特曼－夏克波前传感器探测波前误差的可行性，结果表明，相关哈特曼－夏克波前传感器能够有效探测光学波前误差。     

高分辨率蓝光光学显微测量系统

本系统用波长为405nm的超亮度蓝色发光二极管作为光学显微镜的照明光源，结合CCD图像传感技术和图像采集技术，实现了对显微图像的实时观察和存取的计算机化。观察到的DVD盘片的清晰显微图像表明，其光学分辨率优于400nm。运用自编的图像分析软件对采集到的CD RW光盘图像进行分析和标定，测定其道间距为1.6μm。因此，本系统在显微观测领域，特别是对观测和分析接近普通光学显微镜分辨极限尺寸的微结构，有重要的实用价值。     

Tape Casting of Graphite Material: A New Electrochemical Sensor

Tape casting is a feasible method for preparing ceramic tapes with different electrical and magnetic properties for multilayer ceramic devices. This paper describes the tape casting process for the preparation of a new kind of self‐standing carbon electrodes (SSCE) using different ratios of graphite and the organic additives generally used in the non‐aqueous tape casting process.