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41.
在离子通道性质的研究中,由于可极化力场计算量巨大,长期以来使用最广泛的依旧是经典力场. 本文考察了可极化力场在描述离子通道gramicidin A(gA)二聚状态下离子输运性质方面的可靠性. 利用AMOEBA可极化力场对单通道gA和双通道gA进行增强采样模拟,从电导、扩散系数和自由能等方面描述了gA二聚化对钾离子和钠离子穿越通道过程的影响. 计算结果显示,可极化力场模拟获得的钾离子和钠离子穿越通道的电导与实验数值吻合. 进一步的数据分析揭示了蛋白质二聚化影响gA通道离子输运性质的分子机制,即蛋白二聚化通过调整gA蛋白周围的环境(磷脂头基、通道外离子和体相水分子的分布)而不是直接调整gA蛋白的构象来加速钾离子和钠离子穿越通道. 相似文献
42.
Shunzo Katayama 《Journal of solution chemistry》1976,5(4):241-248
Thermodynamic ion-association constants for calcium, cobalt, zinc, and cadmium sulfates in aqueous solutions were determined by means of conductivity measurements at various temperatures between 0°C and 45°C. The standard Gibbs energy, enthalpy, and entropy for the reaction M
2+
+SO
4
2–
M
2+
·SO
4
2–
(M=Ca, Co, Zn, and Cd) were calculated from the temperature dependence of the ion-association constants. The values obtained are as follows: G
298
o
=–12.42 kJ-mole
–1
, H
o
=6.11 kJ-mole
–1
, and S
298
o
=62.1 J-
o
K
–1
-mole
–1
for Ca
2+
·SO
4
2–
; G
298
o
=–12.84 kJ-mole
–1
, H
o
=5.00 kJ-mole
–1
, and S
298
o
=59.8 J-
o
K
–1
-mole–1 for Co
2+
·SO
4
2–
; G
298
o
=–12.65 kJ-mole
–1
, H
o
=8.65 kJ-mole
–1
, and S
298
o
=71.4 J-
o
K
–1
-mole
–1
for Zn
2+
·SO
4
2–
; G
298
o
=–13.28 kJ-mole
–1
, H
o
=8.39 kJ-mole
–1
, and S
298
o
=72.7 J-
o
K
–1
-mole
–1
for Cd
2+
·SO
4
2–
. 相似文献
43.
Giuseppe Petrella Mario Petrella Maurizio Castagnolo Angelo Dell'Atti Angelo De Giglio 《Journal of solution chemistry》1981,10(2):129-138
Conductances of sodium bromide, iodide, and perchlorate, potassium chloride, and tetraphenylboride (BPh
4
–
) as well as triisoamyl-n-butylammonium iodide (i-Am3BuNI) have been measured in aqueous mixtures containing up to 20 mole percent dimethylsulfoxide (DMSO) at 25°C. Experimental data were analyzed by the 1965 Fuoss-Onsager-Skinner (FOS) equation. Single-ion limiting equivalent conductances were calculated by assuming that 0 (i–Am
3
BuN
+=0 (BPh
4
–
). The variations of the limiting ionic Walden products are discussed on the basis of acid-base type interactions for cations, and on the basis of structural effects for anions. 相似文献
44.
三叠片型换能器是正交偶极声波测井仪器的重要组成部分。换能器的性能直接影响声波测井数据的质量。本文在前人工作基础上,针对三叠片型声波测井发射换能器长度方向的一阶弯曲振动工作模式,利用有限元方法,模拟了换能器结构尺寸和边界条件变化对换能器性能的影响。结果显示,结构尺寸和边界条件对换能器的谐振频率和电导值均有不同程度的影响。参考数值模拟结果,选取合适的结构尺寸参数和边界固定方式,可以调整和选择正交偶极声波测井仪器发射换能器工作频率和最大发射效率。本文研究结果对三叠片型换能器的优化设计有较好的指导意义。 相似文献
45.
T.Y. Ko C.H. Yang K. W. Sun H.W. Chang B. Sarkar C.W. Liu 《Central European Journal of Chemistry》2009,7(2):197-204
In this paper we present the methods to chemically synthesize the Sb2Se3 nanorods and study the electrical and optical properties of a single Sb2Se3 nanorod with an average size of 70 nm in diameter and a length of about 1 μm to 2 μm. The techniques we devised can immobilize
and allocate a single nano-object on an electron beam (E-beam) patterned smart substrate. It can also overcome the limitation
of the spatial resolution of conventional optical techniques (∼ 1 mm) to obtain optical spectroscopy in an individual nano-object
less than 100 nm in size. We also demonstrate the techniques in using E-beam defined metallic coordination markers as electrodes
to measure the conductance of a single Sb2Se3 nanorod.
相似文献
46.
Conductance due to inter-tube transfer in incommensurate double-wall tubes is numerically studied. The conductance is usually much smaller than e2/π and its average and fluctuation are independent of the length. This behavior arises because the inter-tube transfer oscillate around zero in a complex plain as a function of position in a quasi-periodic manner and therefore cancel each other when being summed up except near tube edges. 相似文献
47.
M.J. Majid 《Physics letters. A》2019,383(9):879-887
We present a new procedure to investigate the I–V characteristics and the conductance for strained SWCNTs. These electronic transport properties have been studied theoretically at zero temperature for zig-zag, armchair and chiral SWCNTs under the effect of the uniaxial tension and torsional strain. The analytical expression of the energy spectrum in the tight binding approximation has been used to calculate the induced current and the conductance through Landauer–Büttiker formalism. It is shown that the conductance for unstrained CNTs at initial values of the voltage can take discrete values which are equal to zero and 4 () for semiconducting and conducting SWCNTs respectively. The emergence of the kinks in the I–V characteristics is due to the discrete electronic spectrum in the SWCNTs. The location and number of kinks are changeable under the effect of strain process. The conductance in a strained armchair CNT decreases to zero under torsional strain, consequently, it will transform the conducting SWCNTs at a threshold value of strain to a semiconducting SWCNT. In contrast, by applying the uniaxial tension on the armchair CNT, the conductance does not change absolutely. There is a different behavior can be observed by applying the strain on zig-zag CNT, where the conductance decreases rapidly and slightly under the influence of uniaxial tension and torsional strain, respectively. We found that the conductance of chiral CNT is not significantly affected by applying the strain under consideration. More interestingly, the band structure of chiral CNT under uniaxial tension and torsional strain have been investigated within the tight binding approximation. 相似文献
48.
The conducting and mechanical properties of ultrasmall metallic structures are calculated using the electronic scattering matrix, evaluated in the free electron approximation. Force oscillations of the order
are predicted when a metallic quantum wire is stretched to the breaking point, which are synchronized with quantized jumps in the conductance. Coherent backscattering from impurities is shown to lead to fine structure (a “quantum fingerprint”) in the force oscillations.
1997 Elsevier Science B.V. All rights reserved. 相似文献
49.
Precise conductance measurements have been performed for lithium perchlorate, lithium tetrafluoroborate, lithium hexafluoroarsenate, sodium perchlorate, and sodium tetraphenylborate in 2-methoxyethanol–water mixtures at four different mole fractions, i.e., 0.056, 0.136, 0.262, and 0.486 of 2-methoxyethanol (69.73 D 26.55) at 25°C in the concentration range 0.0004–0.0642 mol-dm–3. The limiting molar conductivity °, the association constant K
A, and the association distance R for the solvent mixtures have been evaluated from the conductance concentration data using the 1978 Fuoss conductance equation. The single-ion conductances have been estimated using the reference electrolyte tetrabutylam-monium tetraphynylborate(Bu4NBPh4). The analysis of the data indicates that for most salts ion association is appreciable in the solvent mixtures with a mole fraction of the cosolvent of 0.262 or higher. The results have been interpreted in terms of ion-solvent interactions and structural changes in the mixed solvent media. 相似文献
50.
高效毛细管电泳-电导检测对四环素衍生物分离测定的研究 总被引:9,自引:0,他引:9
运用毛细管电泳-电导检测方法对4种四环素衍生物——土霉素(OTC)、金霉素(CTC)、强力霉素(DOC)和四环素(TC)的分离进行了研究。在3.5mmol/L三羟基氨基甲烷(Tris)-7.5mmol/L柠檬酸(Cit)pH4.0的运行缓冲液中,4种四环素衍生物在15min内获得完全分离。四环素衍生物的线性范围分别为5.0-500μg/mL OTC,3.6-420μg/mL CTC,4.5-470μg/mL DOC和2.5-400μg/mL TC。检测限(S/N=3)分别为OTC2.0μg/mL,CTC 1.8μg/mL,DOC2.5μg/mL和TC1.0μg/mL。采用本法对实际样品强力霉素片中强力霉素和土霉素片中土霉素进行测定,回收率分别为97.2%和96.4%。 相似文献