Solvent effect on condensation of pyramidal [AsSe3]3–: solvothermal syntheses of new selenidoarsenates containing transition metal(II) complexes with 1,10-phenanthroline

The reactions As₂O₃, Se and 1,10-phenanthroline (phen) with NiCl₂ and ZnCl₂ in water at 140°C for 5 days afforded selenidoarsenates [Ni(phen)₃]₂[As₈Se₁₄] (1) and [Zn(phen)₃]₂[As₈Se₁₄] (2), respectively. The reactions with CoCl₂ and NiCl₂ in CH₃OH aqueous solution produced polyselenidoarsenates [Co(phen)₃][As₂Se₆] (3) and [Ni(phen)₃][As₂Se₆] (4). All transition metal ions are octahedrally coordinated by six nitrogen atoms and all arsenics are trigonal pyramidally coordinated by three seleniums. In 1 and 2, eight [AsSe₃]^3? trigonal pyramids joined via edge-sharing to form [As₈Se₁₄]^4? with condensation grade of 0.571. [As₈Se₁₄]^4? contains two As₃Se₃ and one As₆Se₆ heterocycles. The formations of the selenidoarsenate anion [As₈Se₁₄]^4? in 1 and 2 and polyselenidoarsenate [As₂Se₆]^2? in 3 and 4 show solvent effect on condensation of trigonal bipyramidal [AsSe₃]^3? units under solvothermal conditions.     

A geometric interpretation of the transition density of a symmetric Lévy process

We study for a class of symmetric Lévy processes with state space R n the transition density pt（x） in terms of two one-parameter families of metrics, （dt）t>0 and （δt）t>0. The first family of metrics describes the diagonal term pt（0）; it is induced by the characteristic exponent ψ of the Lévy process by dt（x, y） = ^1/2tψ（x-y）. The second and new family of metrics δt relates to ^1/2tψ through the formulawhere F denotes the Fourier transform. Thus we obtain the following "Gaussian" representation of the transition density: pt（x） = pt（0）e- δ2t （x,0） where pt（0） corresponds to a volume term related to tψ and where an "exponential" decay is governed by δ2t . This gives a complete and new geometric, intrinsic interpretation of pt（x）.     

向量均衡问题的K-T条件

利用映射的Fréchet可微的概念研究具约束的向量均衡问题的弱有效解,Henig有效解,超有效解以及全局有效解的最优性条件,在不具任何凸性条件下给出了的向量均衡问题的K-T必要性条件,在加上凸性条件下给出了向量均衡问题的K-T充分性条件。     

Uncertainty Relations in Terms of Fisher Information

By virtue of the well-known concept of Fisher information in the theory of statistical inference, we obtain an inequality chain which generalizes and refines the conventional Heisenberg uncertainty relations.     

直接缩合法合成低分子量聚乳酸的研究

本文采用聚合反应－共沸精馏耦合的方法,直接缩合合成低分子量聚乳酸,系统研究了分子筛对聚合反应的影响,以及不同催化剂对聚合物产率及分子量的影响。采用ＩＲ、ＧＰＣ、＾１ＨＮＭＲ等测试手段时聚乳酸进行了表征,并与丙交酯法所得聚乳酸进行了比较,结果表明,锡（Ｓｎ）是理想的乳酸缩合聚合催化剂,而直接将分子筛加入到聚合反应体系中可有效地提高聚合物分子量。采用γ－Ａｌ２Ｏ３负载的催化剂可以得到分子量较高且分散和     

二[4-羟基-5,6-二氢-6-烷基(芳基)-2H-吡喃-2-酮-3-]烃的合成及生物活性的研究

采用5,6-二氢-6-烷基(芳基)-2H-吡喃-2,4-二酮和醛进行缩合反应,合成了二[4-羟基-5,6-二氢-6-烷基(芳基)-2H-吡喃-2-酮-3-]烃.其结构经¹HNMR和元素分析证实.对反应条件(反应温度、反应时间)进行了探讨.生物活性初步测定表明,该类化合物具有一定的杀菌和抗烟草花叶病毒的活性.     

α-和β-四烷氧取代酞菁的合成及性能研究

利用3-烷氧取代邻苯二腈和4-烷氧取代邻苯二腈与相应的金属盐反应制备了两大系列(α-和β-)四烷氧取代酞菁.讨论了温度对中间体烷氧取代邻苯二腈合成的影响,探讨了酞菁的两种环合方法,并对β-烷氧酞菁的环合历程进行了初步的考察.研究了不同取代位置和酞菁的最大吸收波长之间的关系,结果表明, α-取代烷氧取代酞菁导致λmax红移值较大,而相应β位取代情况下红移值较小,说明给电子基团在α位对酞菁骨架的π共轭结构微扰作用比β位大.同时研究了溶解度及热失重与酞菁结构的关系.     

纳米白藜芦醇脂质体的物理化学稳定性研究

纳米载药脂质体的物理化学稳定性,是其实际应用中的关键问题。文章采用薄膜旋转蒸发法-超声法制备了白藜芦醇纳米脂质体（RES-Lip）,采用透射电子显微镜观察其微观形貌,并考察RES-Lip的物理化学稳定性。通过电导法测定了RES-Lip的相变温度（Tm）,及其在凝聚过程的凝聚速率常数（Kco）和表观活化能（Eco）;采用动态透析-紫外分光光度法,研究了温度和pH对RES-Lip降解的影响。结果表明,RES-Lip为球形囊泡结构,粒径小于100 nm;RES-Lip的相变温度为64℃;凝聚速率常数Kco随体系温度升高而升高;表观活化能Eco为86.056 kJ/mol;RES-Lip的降解符合一级动力学模型,降解的表观活化能Ea为59.3157 kJ/mol,降解过程是吸热、自发、熵增过程。本实验制备得到的RES-Lip在4℃、pH=7.40的条件下储存,稳定性较好。     

The one-dimensional soliton state of Bose-Einstein condensate

Under certain conditions, the Bose-Einstein condensate confined in a two-dimensional harmonic trap is associated with a one-dimensional nonlinear Schrödinger equation and a soliton solution. The influence of the initial condition on the solution is discussed. The critical initial number of condensed atoms to maintain a soliton is evaluated. In the Li case, this number is of the order of thousand. The energy per particle of the solitons is also calculated.     

Heat transfer analysis according to condensation flow structures in a minichannel

An experimental investigation of complete condensation flow is undertaken for a range of mass flow rates between 3.4 and 13.8 kg/m² s. The associated flow regimes are visualized using an ombroscopic technique. Two major flows are observed (with or without release of bubbles). A critical value of the mass flow rate is obtained at the transition between these two regimes. The visualization also enables a local parameter to be determined: the void fraction. The influence of the presence of a bubbly zone is highlighted by the heat transfer and pressure drops. Finally, the dependence of the critical value of the mass flow rate on the temperature of the secondary flow is obtained.