Electrocatalytic Reduction of Chromium(VI) by Thionin: Electrochemical Properties and Mechanistic Study

The electrochemical properties of aqueous thionin (an electroactive water soluble dye) of pH 1–12 were investigated by cyclic voltammetry at a boron doped diamond(BDD) electrode. A well defined reversible redox couple was observed in acidic, neutral and alkaline solutions. The standard potential and kinetic parameters for thionin were obtained by fitting experimental cyclic voltammograms to those generated by the DigiSim program. The electrogenerated reduced form of thionin has been used as an efficient organic catalyst for the reduction of Cr(VI) at a BDD electrode immersed in aqueous media. The cyclic voltammetry measurements indicate that an electrocatalytic process occurs, where electrochemically generated thionin reduced species (Leucothionin) is oxidized by Cr(VI) back to the parent thionin species via a EC' reaction mechanism. The determination of catalytic rate constant (K_cat) was accomplished again by fitting experimental cyclic voltammograms with simulated ones.     

铜电路板缝腐蚀过程缝隙中pH、Cl-浓度分布的测量

根据铜电路板缝腐蚀特征,研制了阵列式Ag/AgCl、IrO2电极,设计缝隙腐蚀模拟装置,在0.5mol.L-1的NaCl溶液中分别同时原位检测电子线路板缝隙腐蚀过程,缝隙内的氯离子浓度分布、pH分布及其随时间的变化.研究表明,在电子线路板发生缝隙腐蚀的过程中,缝隙内部不同深度的Cl-及H+浓度逐渐增大,且随着与缝口距离的增大而增大,从而导致缝隙腐蚀不断向纵深方向发展.     

Electrochemical Immunoassay for Tumor Marker CA19-9 Detection Based on Self-Assembled Monolayer

A CA19-9 electrochemical immunosensor was constructed using a hybrid self-assembled membrane modified with a gold electrode and applied to detect real samples. Hybrid self-assembled membranes were selected for electrode modification and used to detect antigens. First, the pretreated working electrodes were placed in a 3-mercaptopropionic acid (MPA)/β-mercaptoethanol (ME) mixture for 24 h for self-assembly. The electrodes were then placed in an EDC/NHS mixture for 1 h. Layer modification was performed by stepwise dropwise addition of CA19-9 antibody, BSA, and antigen. Differential pulse voltammetry was used to characterize this immunosensor preparation process. The assembled electrochemical immunosensor enables linear detection in the concentration range of 0.05–500 U/mL of CA19-9, and the detection limit was calculated as 0.01 U/mL. The results of the specificity measurement test showed that the signal change of the interfering substance was much lower than the response value of the detected antigen, indicating that the sensor has good specificity and strong anti-interference ability. The repeatability test results showed that the relative standard deviations were less than 5%, showing good accuracy and precision. The CA19-9 electrochemical immunosensor was used for the actual sample detection, and the experimental results of the standard serum addition method showed that the RSD values of the test concentrations were all less than 10%. The recoveries were 102.4–115.0%, indicating that the assay has high precision, good accuracy, and high potential application value.     

L波段高功率线极化径向线阵列天线理论分析与数值模拟

 探索了L波段的高功率线极化径向线阵列天线。基于三角形栅格形式实现了径向线圆形平面阵列天线,分析并给出了径向线并联馈电网络,并以同轴馈电的水平单圆环线极化天线为基础,利用径向线并联馈电网络设计出了间距小于一个波长下L波段高功率线极化径向线阵列天线。研究结果表明：这种结构实现径向线阵列天线的线极化辐射是可行的,该天线在中心频率1.57 GHz下,增益为19.97 dBi,轴比为-52.06 dB,反射系数为0.105 2;在1.37～1.77 GHz的频率范围内增益大于18.64 dBi,轴向轴比值小于-46.45 dB。     

The Orion Water-Hardness Electrode: An Unexpected Response to Magnesium Ion

Abstract

The Orion water-hardness electrode, while being used to measure magnesium ion activity in a series of calcium-free solutions, displayed some unanticipated changes in potential. As the overall potential change observed for one solution was 183 mV (equivalent to more than six orders of magnitude changes in magnesium-ion activity), several precautions are suggested which should be observed when using this electrode for specific purposes. In particular, it is recommended that the exchanger be pre-equilibrated with an appropriate solution if the electrode is to be used in restricted systems of known chemical composition.     

Application of the Salicylate Ion Electrode for the Monitoring of the Electroreduction of Salicylic Acid

Abstract

An ion selective electrode is described for measuring the unreacted salicylate ion concentration during the electroreduction of salicylic acid. Conditions for making measurements are discussed.     

用光谱学方法研究不同放电等离子体粒子约束

本文用光谱学方法研究在ＨＬ－１装置上ＬＨＣＤ及ＥＣＲＨ等离子体，弹丸注入等离子体，偏压电极与偏压孔栏等离子体粒子约束特性。结果表明：在弹丸注入使用正向偏压电极与偏压孔栏期间，等离子体粒子约束行到改善，较低密度下（＾ｎｅ＜２．０×１０＾１＾３ｃｍ＾－＾３），ＬＨＣＤ脉冲期间粒子约束得到改善；而当密度＾－ｎｅ大于２．０×１０＾１＾３ｃｍ＾－＾３时，等离子体约束变坏。ＥＣＲＨ脉冲期间粒子约束得不到改善。     

快速测定氧化还原酶活力的一次性介体电极

以葡萄糖氧化酶（GOD）为模型酶,用一次性丝网印刷电极检测氧化还原酶活力,选用具有较低氧化还原电位的单羟基二茂铁（HMF）作为电子传递介体,以电流法测定氧化酶的活力,所需时间仅为60s,线性响应范围为0～40U/mL.将电极用于检测黑曲酶发酵产生的葡萄糖氧化酶（GOD）的活力,测定结果与传统的方法相对照,具有较好的一致性,相关系数为0.9813.     

电弧炉电极位置控制系统的SIMULINK仿真研究

介绍了基于MATLAB5.2提供的仿真工具SIMULINK,对电弧炉电机位置控制系统进行建模、仿真和分析研究,首先得到了系统数学模型,用超前校正器（PD控制器）对该控制系统进行串联校正,然后用SIMULINK实现对该控制系统的全图形化功能模块结构图仿真计算,仿真结果表明,系统能得到更好的动态性能参数。     

Dynamic calibration of shock overpressure transducers

Piezoelectric transducers for dynamic overpressure measurements are commonly calibrated with static or quasistatic loads and the calibration is extrapolated to frequencies up to 30% of the resonant frequency of the piezoelectric crystal. Sinusoidal pressure generators are also used for dynamic calibration up to 500 Hz in the range of 3 MPa. This paper describes a method for dynamic calibration using transient overpressures, with rise time of 2 μsec and width 40 μsec, generated by exploding wires in air. The calibration is done in the range of 600 kPa.