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Summary Electrically driven size exclusion chromatography (ED-SEC) of polystyrenes in packed capillaries using dimethylformamide as
solvent is demonstrated. The efficiency and retention behaviour of polystyrenes under pressure and electro drive were investigated.
Under pressure drive the plate height (H) increases steadily with increasing linear velocity (u) whereas under electro drive
the H-u curves largely coincide and are very flat. At higher velocities the plate heights are about 50% smaller with electro
drive than with pressure drive. Calculations show that with increasing ionic strength, the flow through the particles may
increase causing a clear diminishing of the elution window. 相似文献
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We studied the photon spectrum in coated microspheres with alternating quasiperiodic layers having left-handed (LH) materials included. It is found that the band gap (spectral zone of nearly zero transmittancy) in such a system is strongly enhanced. At an increase of the quasiperiodicity parameter γ, the boundaries of the spectral band gaps acquire the intended shape. When γ exceeds the inverse golden mean value, a structure with extremely narrow separated resonant peaks with nearly complete transmittance arises. At increased γ, such resonances migrate to the center of the band gap. This effect allows creating optical filters with extremely narrow passbands. 相似文献
37.
Yttria-stabilized zirconia (YSZ) buffer layers were deposited on CeO2 buffered biaxially textured Ni-W substrate by reel-to-reel pulsed laser deposition (PLD) for the application of YBa2Cu3O7−δ (YBCO) coated conductor and the influence of substrate temperature and laser energy on their crystallinity and microstructure were studied. YSZ thin films were prepared with substrate temperature ranging from 600 to 800 °C and laser energy ranging from 120 to 350 mJ. X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to investigate how thin film structure and surface morphology depend on these parameters. It was found that the YSZ films grown at substrate temperature below 600 °C or laser energy above 300 mJ showed amorphous phase, the (0 0 1) preferred orientation and the crystallinity of the YSZ films were improved with increasing the temperature, but the surface roughness increased simultaneously, the SEM images of YSZ films on CeO2/NiW tapes showed surface morphologies without micro-cracks. Based on these results, we developed the epitaxial PLD-YSZ buffer layer process at the tape transfer speed of 3-4 m/h by the reel-to-reel system for 100 m class long YBCO tapes. 相似文献
38.
A surface wave of frequency lying within bulk band of transverse waves is found in an elastic medium coated with a thin layer endowed with a surface mass density, surface Young's modulus and surface bending modulus. The wave is a particular case of surface resonance with infinite lifetime. In materials with negative Poisson's ratio (auxetics) the wave exists even for coating material with zero bending modulus, whereas with positive Poisson's ratio it requires the surface bending modulus to be larger than the surface Young's modulus. The manifestation of this wave in the reflection coefficient seems promising for fabrication of devices showing monochromator properties. 相似文献
39.
We studied the frequency spectrum of photons in a multilayered microsphere coated by a quasiperiodic (Fibonacci) dielectric stack numerically. We found that the transmittancy spectrum of such a stack consists of quasiband gaps and narrow resonances caused by re-reflection of optical waves. When the number (Fibonacci order) of layers increases, the band gaps and resonances split, and the structure of the frequency spectrum acquires a fractal form. We found the self-similarity of the frequency spectrum and evaluated the fractal dimension both for lossless and dissipative cases. The influence of a weak random deviation of spherical layers width is also discussed. 相似文献
40.
The average interparticle voidage or porosity (epsilon(inter)) in cylindrical capillaries is studied in dependence on the column diameter (d(c)) to particle diameter (d(p)) ratio for 5 < d(c)/d(p) < 50. Using optimized slurry and packing solvents, high pressure and ultrasonication, 5 mum-sized porous C18-silica particles were slurry-packed into fused-silica capillaries having ids from 30 to 250 mum. Packing densities are assessed by a polystyrene standard which is size-excluded from the intraparticle pore space of the packings. For d(c)/d(p) > 35 densely packed beds are realized (epsilon(inter) = 0.36-0.37), while for decreasing aspect ratios an exponential increase in epsilon(inter )is observed reaching epsilon(inter ) approximately 0.47 at d(c)/d(p) = 5. This behaviour is ascribed to a combination of the geometrical wall effect operating in the direct vicinity of the column wall, caused by the inability of the particles to form a dense packing against the hard surface of the column wall, and particle characteristics like the size distribution, shape and surface roughness. Results are compared with the literature data to address also the importance of absolute particle size in studying structure-transport relations in packed beds in dependence on the aspect ratio d(c)/d(p). 相似文献