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21.
Yasuhiro Ishida 《Tetrahedron letters》2004,45(51):9455-9459
A planar-chiral imidazolium salt with a tris(oxoethylene) bridge was synthesized, and its potential application as a room temperature ionic liquid with a molecular-recognition ability was demonstrated. 相似文献
22.
23.
In recent years a two-scale expansion was established to study reactions of the type NN→NNπ within chiral perturbation theory. Then the diagrams of some subclasses that are invariant under the choice of the pion field no longer appear at the same chiral order. In this Letter we show that the proposed expansion still leads to well defined results. We also discuss the appropriate choice of the heavy baryon propagator. 相似文献
24.
Amylopectin tris(phenylcarbamate) has been evaluated as a chiral stationary phase for HPLC; the influence on its cptical resolving capabilities of mobile phase composition and nature of the alcohol used as modifier has been studied. Separation and resolution of twelve arylalcohol racemates were examined. In most instances, the stationary phase exhibited high optical resolving capacity. 相似文献
25.
In the present paper, we solve three boundary value problems related to the temperature field in oil strata — the fractional
extensions of the incomplete lumped formulation and lumped formulation in the linear case and the fractional generalization
of the incomplete lumped formulation in the radial case. By using the Caputo differintegral operator and the Laplace transform,
the solutions are obtained in integral forms where the integrand is expressed in terms of the convolution of some auxiliary
functions of Wright function type. A generalization of the Laplace transform convolution theorem, known as Efros’ theorem
is widely used. 相似文献
26.
Fan Fu 《Tetrahedron letters》2006,47(25):4267-4269
A chiral indium(III) complex prepared from indium triflate and a pybox ligand has been developed to give good yields and enantioselectivities (up to 92% ee) in the addition of (1-methoxy-2-methyl-propenyloxy)-trimethylsilane to various aromatic and aliphatic aldehydes via the Mukaiyama aldol reaction. 相似文献
28.
Chiral separations by host-guest complexation with cyclodextrin and crown ether in capillary zone electrophoresis 总被引:2,自引:0,他引:2
Summary Capillary zone electrophoresis using cyclodextrins and a chiral crown ether as buffer constituents was studied for the enantiomeric separation of drugs and amino acids. Based on results obtained from separation of racemic -amino acids both chiral selectors are compared with respect to resolution, efficiency and retention time. For (±)-Quinagolide effects of buffer composition and temperature are examined using -cyclodextrin as chiral agent. Optimum conditions were pH 2.5 at 30 mmol L–1 -cyclodextrin. A linear dependence of retention on -cyclodextrin concentration allowed calculation of formation constants of the host-guest complexes. Buffer concentration and temperature also influence resolution. The application of a chiral crown ether to the separation of optical isomers in capillary zone electrophoresis is described for the first time. Chiral recognition of solutes depends on the formation of protonated alkyl amines and separation is attributed to the formation of diastereomeric host-guest complexes with different interactions for each enantiomer. The effects of crown ether concentration on resolution are presented. 相似文献
29.
Summary Chiral recognition of many enantiomeric solutes by a chiral amide stationary phase is based mainly on hydrogen bonding. A
chiral-recognition-factor CHI is proposed, given by the difference of the enthalpy change in the enantiomer discrimination,
standardized with respect to the specific interaction of the solutes with the diamide core of the stationary phase. The r?le
of the entropy part is also discussed. By extrapolation of the retention behaviour to elevated temperature, peak inversion
of enantiomers is predicted.
Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984 相似文献
30.
Summary A variety of bilipeptides has been synthesized and investigated by UV-VIS and CD spectroscopy to explore the conformational influence of peptide ligands on the covalently bound tetrapyrrol moiety. The results obtained are complemented by those reported previously. From the comprehensive data thus available several features of the peptidic chain regulating interactions with the bilatriene moiety have been elucidated. Accordingly, the presence of three amide linkages at the ligand is prerequiste for induction of pronounced conformational changes consisting either in a complete transition ofM intoP helical bilatriene species by inversion of all torsional angles, or in a stretching of the chromophore. The kind of conformational influence can be controlled by varying the position of the prolyl entity within a given peptide.Dedicated to Prof. Dr. Kurt Schaffner on occasion of his 60th birthday 相似文献