开放式复杂航空网络系统的动力学演化

本文首先实证研究了中国航空网(CAN)与外部经济环境,即国民生产总值(GDP)的相关性,进而揭示CAN的演化方式及其拓扑特征的起源.发现自1998年起网络节点的度与其GDP成线性关系,表明了网络拓扑与经济因素有密切的联系,且CAN的度演化服从类似于多重过程(multiplicative process)的模式,而该模式又强烈依赖于GDP的增长率.这种独特的模式暗示了CAN具有类似适应度模型的微观机理.通过对演化方程的研究发现:1)CAN在增长过程中,节点加入的时刻具有经济上的偏好性,即节点加入的时刻与该节 关键词： 国民生产总值(GDP) 中国航空网(CAN) 双段幂率分布 多重过程     

Constant-factor approximations for Capacitated Arc Routing without triangle inequality

Given an undirected graph with edge costs and edge demands, the Capacitated Arc Routing problem (CARP) asks for minimum-cost routes for equal-capacity vehicles so as to satisfy all demands. Constant-factor polynomial-time approximation algorithms were proposed for CARP with triangle inequality, while CARP was claimed to be NP-hard to approximate within any constant factor in general. Correcting this claim, we show that any factor  α$\alpha$ approximation for CARP with triangle inequality yields a factor  α$\alpha$ approximation for the general CARP.     

微机实时控制中的汉字开发

本文提出了在微机实时测量与控制中开发汉字的方法,给出了有关程序及流程图。要点是借助于 CCDOS 中的 CCLIB 库离线建立专用的小汉字库,使用时,完全不用任何 CCDOS 汉字系统来支持,大大节省内存空间,简而易行。特别适用于把汉字作为菜单提示或帮助的实时应用软件廉价开发。     

基于Bootstrap-DEA的工业能源效率分析

传统DEA方法存在小样本估计有偏、无法进行统计检验等缺点.而Bootstrap-DEA方法能够通过数值模拟技术产生大量的模拟样本,通过对新生成的样本进行估计来修正DEA效率估计偏差,进而计算出效率值的置信区间.作者利用Bootstrap-DEA方法首次对我国36个工业行业1995-2008年的能源利用效率进行分析.研究结果表明,我国工业行业的能源效率呈现出U字型变动趋势,行业间的能源效率差异不断减小.     

Polymerizable C70 derivatives with acrylate functionality for efficient and stable solar cells

Fullerene-based organic solar cells are generally suffering from severe microstructure evolution occurring in their bulk heterojunction active layers and thus are extremely stable. To address it, four polymerizable C₇₀ fullerene derivatives, [6,6]-phenyl-C₇₁-ethyl acrylate (PC₇₁EA), [6,6]-phenyl-C₇₁-propyl acrylate (PC₇₁PrA), [6,6]-phenyl-C₇₁-butyl acrylate (PC₇₁BA), and [6,6]-phenyl-C₇₁-pentyl acrylate (PC₇₁PeA), have been designed, synthesized, and investigated. These fullerene compounds have a molecular structure, shape and size very like the conventional C₇₀ fullerene acceptor, [6,6]-phenyl-C₇₁-butyric acid methyl ester (PC₇₁BM), and have been found no different in their light absorption, redox potentials, and frontier orbital energy levels. Using these fullerene acrylates individually as acceptor and poly(3-hexylthiophene) as donor, organic solar cells have been fabricated and gave optimal efficiencies ranging from 3.32% to 4.16%, comparable to PC₇₁BM-based reference cells (4.06%). Owing to their acrylate functionality, these fullerene derivatives can turn into insoluble upon heating, and thus endow their solar cell devices much better thermostability than PC₇₁BM-based reference cells. The best one, coming from PC₇₁PeA devices, reported an optimal efficiency of 4.16%, and maintained 91.7% efficiency after heat treatment at 150 °C for 35 h. As a sharp contrast, the PC₇₁BM reference cell dropped its optimal efficiency from 4.06% to 0.48% only after 5 h heat treatment. X-ray diffraction, optical and atomic force microscopy, and space-charge-limited current method have been carried out to understand active layer structure, morphology, and charge mobility change during heat treatment.     

Separation and determination of flavonoids in three traditional chinese medicines by capillary electrophoresis with amperometric detection

Flavonoids are important active ingredients in many traditional Chinese medicines. In this paper, capillary electrophoresis with amperometric detection was employed to separate and detect eight flavonoids, rutin, quercetrin, quercetin, kaempferol, kaempferide, catechin, apigenin, and luteolin, in a home‐made capillary electrophoresis device. Under the separation voltage of 2000 V, the eight flavonoids could be completely separated within 33 min in 18 mM borax running buffer at pH 10.2. Good linear relationships were obtained for all analytes and the detection limits for flavonoids ranged from 0.46 to 0.85 μM. Then, the method was applied to separate and determine the flavonoids in three traditional Chinese medicines, hippophae rhamnoides, hypericum perforatum, and cacumen platycladi. Finally, rutin, kaempferol, quercetin, and quercetrin were discovered in these medicines and the concentrations ranged from 0.28 to 9.94 mg/g. The recoveries of flavonoids ranged from 84.7 to 113%, which showed the high reliability of this method.     

Identification and analysis of chemical constituents and rat serum metabolites in Suan‐Zao‐Ren granule using ultra high performance liquid chromatography quadrupole time‐of‐flight mass spectrometry combined with multiple data processing approaches

Suan‐Zao‐Ren granule is widely used to treat insomnia in China. However, because of the complexity and diversity of the chemical compositions in traditional Chinese medicine formula, the comprehensive analysis of constituents in vitro and in vivo is rather difficult. In our study, an ultra high performance liquid chromatography with quadrupole time‐of‐flight mass spectrometry and the PeakView® software, which uses multiple data processing approaches including product ion filter, neutral loss filter, and mass defect filter, method was developed to characterize the ingredients and rat serum metabolites in Suan‐Zao‐Ren granule. A total of 101 constituents were detected in vitro. Under the same analysis conditions, 68 constituents were characterized in rat serum, including 35 prototype components and 33 metabolites. The metabolic pathways of main components were also illustrated. Among them, the metabolic pathways of timosaponin AI were firstly revealed. The bioactive compounds mainly underwent the phase I metabolic pathways including hydroxylation, oxidation, hydrolysis, and phase II metabolic pathways including sulfate conjugation, glucuronide conjugation, cysteine conjugation, acetycysteine conjugation, and glutathione conjugation. In conclusion, our results showed that this analysis approach was extremely useful for the in‐depth pharmacological research of Suan‐Zao‐Ren granule and provided a chemical basis for its rational.     

治疗溃疡性结肠炎中药制剂金属元素含量分析

采用火焰原子吸收法检测了两种溃疡性结肠炎中药制剂中Ｍｎ、Ｃｒ、Ｋ、Ｎａ、Ｃａ、Ｍｇ等金属元素的含量。结果显示,肠炎宁灌肠散中Ｍｎ、Ｃｒ、Ｎａ、Ｍｇ元素含量均明显高于肠炎宁口服胶囊中含量,而Ｋ元素则明显低于口服胶囊中含量。结果提示,中药肠炎宁疗效与金属元素含量有一定关系。     

Rapid detection of pesticide residues in Chinese herbal medicines by molecularly imprinted membrane electrospray ionization mass spectrometry

Chinese herbal medicines(CHMs) play an increasingly important role in the field of medicine and affects public health in the world.Although more and more strict has been employed to ensure the quality and safety of CHMs,pesticide residues in CHMs remain a serious issue and are the bottleneck for the global development of CHMs.In this work,we applied molecularly imprinted membrane electrospray mass spectrometry(MIM-ESI MS) for rapid detecting 4 classes of pesticide residues in CHMs,including organophosphorus(OPP),carbamates,pyrethroids and neonicotinoids in CHMs.Compared with our previous ambient ionization method MESI,MIM-ESI is capable of achieving a ～50-fold increase in the detection limit of conventional analytical methods owing to the specificity recognition and unique enrichment of MIM.The optimal experimental conditions were determined,and the method was further validated for its sensitivity and specificity.Our data showed that MIM-ESI MS is applicable for the direct quantitation of pesticide residues in CHMs.This detection technology may help to ensure the quality of CHMs in the future.