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11.
G. Price 《Accreditation and quality assurance》1996,1(2):57-66
National measurement systems are infrastructures to ensure, for each nation, a consistent and internationally recognised
basis for measurement. Such complex systems have historical, technical, legal, organisational and institutional aspects to
connect scientific metrology with practical measurements. Underlying any valid measurement is a chain of comparisons linking
the measurement to an accepted standard. The ways the links are forged and the etalons (measurement standards) to which they
connect are defining characteristics of all measurement systems. This is often referred to as traceability which aims at basing
measurements in common measurement units – a key issue for the integration of quantitative chemical analysis with the evolving
physical and engineering measurement systems. Adequate traceability and metrological control make possible new technical capabilities
and new levels of quality assurance and confidence by users in the accuracy and integrity of quantitative analytical results.
Traceability for chemical measurements is difficult to achieve and harder to demonstrate. The supply of appropriate etalons
is critical to the development of metrology systems for chemical analysis. An approach is suggested that involves the development
of networks of specialised reference laboratories able to make matrix-independent reference measurements on submitted samples,
which may then be used as reference materials by an originating laboratory using its practical measurement procedures.
Received: 31 July 1995 Accepted: 19 August 1995 相似文献
12.
Mathematical models with stage structures are proposed to describe the process of awareness, evaluation and decision-making. First, a system of ordinary differential equations is presented that incorporates the awareness stage and the decision-making stage. If the adoption rate is bilinear and imitations are dominant, we find a threshold above which innovation diffusion is successful. Further, if the adoption rate has a higher nonlinearity, it is shown that there exist bistable equilibria and a region such that an innovation diffusion is successful inside and is unsuccessful outside. Secondly, a model with a time delay is proposed that includes an evaluation stage of a product. It is proved that the system exhibits stability switches. The bifurcation direction of equilibria is also discussed. 相似文献
13.
Q. Gong R. N tzel P.J. van Veldhoven T.J. Eijkemans J.H. Wolter 《Journal of Crystal Growth》2005,280(3-4):413-418
We report on the shape transition from InAs quantum dashes to quantum dots (QDs) on lattice-matched GaInAsP on InP(3 1 1)A substrates. InAs quantum dashes develop during chemical-beam epitaxy of 3.2 monolayers InAs, which transform into round InAs QDs by introducing a growth interruption without arsenic flux after InAs deposition. The shape transition is solely attributed to surface properties, i.e., increase of the surface energy and symmetry under arsenic deficient conditions. The round QD shape is maintained during subsequent GaInAsP overgrowth because the reversed shape transition from dot to dash is kinetically hindered by the decreased ad-atom diffusion under arsenic flux. 相似文献
14.
Microstructure effect on chemical etching behavior of the annealed Ti-6Al-4V and Ti-3Al-2.5V titanium (Ti) alloys was compared with that of unalloyed commercially pure titanium. The microstructural evolution of structure phases after annealing the titanium and its alloys at temperature near and above β transus and followed by furnace cooling to room temperature was studied using optical microscope, scanning electron microscope and X-ray diffraction techniques. The microstructure study illustrates that the heat treatment enhanced partitioning effect allows extensive formation of hemispherical and near spherical pits roughened surface to be readily acquired by chemically etching the annealed α + β titanium alloys. The kinetics of the chemical etching reaction process show a linear dependence on time. The annealed α + β titanium alloys that exhibit relatively lower weight loss and thickness reduction rate illustrate less chemical activity than the annealed unalloyed titanium. 相似文献
15.
N.M. Shash F.E. Salman M.G. El-Sharawy M.K. El-Mansy 《Journal of Physics and Chemistry of Solids》2004,65(5):881-889
Vitrification suppression in the (V2O5)1−x (P2O5)x glasses where x=0.10, 0.15, 0.20, and 0.25 was controlled by changing the rate of quenching glasses. The structure variations occurring in the glasses were detected by differential thermal analysis and optical microscope. The results implied the separation and growth of V2O5 orthorhombic microcrystal in the samples with x=0.10 and 0.15 whereas other samples did not illustrate remarkable changes in their microstructure. However, in temperature range between 300 and 473 K a semiconducting behavior for all samples appears during the study of electrical conductivity-temperature dependence. A decrease in conductivity values accompanied with some variations in activation energies by reducing quenching rate was observed. The conductivity results suggested that the conduction occurs by the phonon assisted hopping of a small polaron between V4+ and V5+ states at relatively higher temperature range above θD/2. Whereas at relatively low temperatures the conduction may occur by electron jumping between filled and empty states at Fermi level in the disordered matrix besides polaronic conduction. Reasonable values for the density of localized states, carrier concentration and carrier mobility were estimated and discussed. Also, dielectric constant and dielectric loss were studied as a function of frequency at different temperatures confirming the structure variations in the glass system. 相似文献
16.
Electron paramagnetic resonance (EPR) investigations has been carried out on the new family of molybdenum doped vanadium sesquioxides (V1−xMox)2−δO3. The oxidation effects were monitored from the rate of paramagnetic V4+ created when the sample is exposed to the air. The effects of the oxidation time, sample temperature, and annealing at 1000 °C under a diluted hydrogen atmosphere on the EPR signal features are analyzed. The V4+ concentration in the oxidized samples is determined and the relaxation effects driven by the conduction electrons are pointed out from the thermal behaviour of the EPR line features. EPR spectra of all the oxidized samples also reveal a small ferromagnetic contribution strongly correlated with the V4+ content. 相似文献
17.
18.
本文报道了一种测角单晶NMR探头。该探头采用单线圃双调谐电路,工作频率在90MHz-110 MHz连续可调,可进行交叉极化大功率去耦实验。文中提出了一种简单而有效的测角装置,可使单晶绕三个互相垂直轴转动实现单晶的NMR测量。作为典型的应用例子,本文利用该探头实现了单晶DGO(2NH2CH2COOH·H2C2O4)屏蔽张量的测量。 相似文献
19.
Eric Gifford Mark Johnson Chun-che Tsai 《Journal of computer-aided molecular design》1991,5(4):303-322
Summary The metabolic pathways of medazepam, oxazepam, and diazepam were modeled using graph-theoretic transforms which are incorporable into computer-assisted metabolic analysis programs. The information, represented in the form of a graph-theoretic transform kit, which was obtained from these pathways was then used to predict the metabolites of other benzodiazepine compounds. The transform kits gave statistically significant predictions with respect to a statistical method for evaluating the performance of the transform kits. 相似文献
20.