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961.
A. A. Gorman I. Hamblett T. A. King M. D. Rahn 《Journal of photochemistry and photobiology. A, Chemistry》2000,130(2-3):127-132
The triplet state of pyrromethene 567, a molecule with potential as a solid state laser dye, has been characterized in benzene by pulse radiolysis in terms of its absorption spectrum, lifetime, self-quenching, electronic excitation energy, triplet–triplet extinction coefficient and oxygen quenching rate constant. The use of laser flash photolysis has then allowed determination of the triplet quantum yield, efficiency of formation of singlet oxygen (1Δg), and the rate constant for reaction of the latter species with the ground state. The affects of oxygen on the fluorescence and triplet yields demonstrate that oxygen-induced intersystem crossing is important, the sum of these parameters being unity within experimental error. The mechanism of reaction of P-567 with 1Δg in benzene is predominantly physical in character with only a small (6%) contribution from chemical reaction. 相似文献
962.
Radio frequency fingerprint (RFF) has attracted a remarkable surge of attention to wireless transmitter identification due to the inimitable hardware imperfection. However, most RFF-based schemes devised in controlled environments are unable to reach the claimed performance in real-world scenarios. This paper proposes a practical RFF identification method for mobile phones in Global System for Mobile (GSM) system. Specifically, the instantaneous amplitude of near-transient part in normal burst (NB) is regarded as RFF that extracted from up-link communications. In addition, an anomaly filtering and stacking (AFS) method is introduced to obtain stable RFF in Time Division Multiple Access (TDMA) system. Lastly, the impacts of frequency point and sending power variations on RFF are fully dissected in comparison experiments. Experiments on 10 mobile phones show that the proposed RFF scheme yields 99.17% True Acceptance Rate (TAR) in real wireless environments. Experiments also show that the varying transmission power decreases the accuracy of RFF identification. 相似文献
963.
SrCe0.92 Nb 0.03 Tm0.05 O 3-δ powders were synthesized by a modified sol-gel method using citrate as a chelating agent.X-ray diffraction(XRD) analysis verified SrCe 0.92 Nb 0.03 Tm 0.05 O 3-δ powders and membranes consisting of a single perovskite phase.The morphologies of the sintered membranes were investigated by using scanning electron microscopy(SEM) technique.Stability tests demonstrated that the Nb introduction into doped strontium cerate greatly enhanced the chemical stability.Electrical conductivities of SrCe 0.92 Nb 0.03 Tm 0.05 O 3-δ and SrCe 0.95 Tm 0.05 O 3-δ were measured by the four-point DC method under 10% H 2 /He atmosphere and temperatures(700-900℃).With a maximum conductivity of 0.0067 S cm-1 at 900℃,the total electrical conductivity of SrCe 0.92 Nb 0.03 Tm 0.05 O 3-δ increases with increasing temperature.The H 2 permeation flux of SrCe 0.92 Nb 0.03 Tm 0.05 O 3-δ is 0.035 mL cm-2 min-1 when 40% H 2 /He and Ar were used respectively as the feed and sweeping gases at 900℃. 相似文献
964.
965.
以Cu2S中空球为反应性模板, 通过在水溶液中与银离子的阳离子交换和氧化还原反应制备了大小均匀的Ag2S中空球-Ag纳米粒子异质结构, 即Ag2S-Ag异质中空球. 该异质结构中每个Ag2S中空球的直径约为600 nm, 壁厚约20–30 nm, 其表面均附着一个Ag纳米粒子. 采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)和能量色散X射线谱(EDS)对所得Ag2S-Ag异质中空球的结构和组成进行了表征. 若以CuS中空球为反应性模板, 在相似转化条件下则主要得到不含Ag粒子的Ag2S中空球. 该结果表明, Cu2S中的Cu(I)的还原性在Ag2S-Ag异质中空球的形成中发挥了重要作用. 通过对所制备的Ag2S-Ag异质中空球进行二次生长, 还可以得到Ag2S中空球的半球表面均被Ag膜所包覆的Ag2S-Ag异质中空球. 相似文献
966.
金属衬底上石墨烯的控制生长和微观形貌的STM表征 总被引:2,自引:0,他引:2
目前化学气相沉积(CVD)方法在不同的金属基底上大规模生长获得石墨烯得到了广泛的应用; 同时扫描隧道显微镜(STM)做为一种强大的精细直观的研究手段可以用于表征金属衬底上石墨烯的微观形貌, 指导石墨烯的控制生长. 本文侧重于Cu箔、Pt 箔和Ni 衬底上石墨烯的控制生长、表面微观形貌、表面缺陷态、堆垛形式的阐述, 得到结论: (1) 两种溶碳量较低的金属(Cu, Pt)上, 石墨烯的生长都符合表面催化的生长机制, 同时层间的范德华相互作用也可以诱导双层石墨烯的生长; (2) 衬底粗糙度的增加可以使石墨烯的电子态去简并化, 从而破坏石墨烯面内π键共轭结构, 导致部分碳原子转变为sp3杂化; (3) 原生的褶皱是由于界面热膨胀系数失配所导致; (4) Pt 箔表面石墨烯的平整度要远优于Cu箔表面的石墨烯, 且不同晶面共存的基底对于石墨烯的连续性并没有产生显著的影响. 相似文献
967.
K.C. IaroszA.M. Batista R.L. Viana S.R. LopesI.L. Caldas T.J.P. Penna 《Physica A》2012,391(3):819-827
We study the firing rate properties of a cellular automaton model for a neuronal network with chemical synapses. We propose a simple mechanism in which the nonlocal connections are included, through electrical and chemical synapses. In the latter case, we introduce a time delay which produces self-sustained activity. Nonlocal connections, or shortcuts, are randomly introduced according to a specified connection probability. There is a range of connection probabilities for which neuron firing occurs, as well as a critical probability for which the firing ceases in the absence of time delay. The critical probability for nonlocal shortcuts depends on the network size according to a power-law. We also compute the firing rate amplification factor by varying both the connection probability and the time delay for different network sizes. 相似文献
968.
The purpose of this study was to investigate the effect of parameter changes that can potentially lead to unreliable measurements in fat quantification. Chemical shift imaging was performed using spoiled gradient echo sequences with systematic variations in the following: two-dimensional/three-dimensional sequence, number of echoes, delta echo time, fractional echo factor, slice thickness, repetition time, flip angle, bandwidth, matrix size, flow compensation and field strength. Results indicated no significant (or significant but small) changes in fat fraction with parameter. The significant changes can be attributed to the known effects of T1 bias and two forms of noise bias. 相似文献
969.
R. Baghdad B. Kharroubi A. Abdiche M. Bousmaha M.A. Bezzerrouk A. Zeinert M. El Marssi K. Zellama 《Superlattices and Microstructures》2012
Mn-doped ZnO thin films with different percentage of Mn content (0, 1, 3 and 5 at.%) and substrate temperature of 350 °C, were deposited by a simple ultrasonic spray pyrolysis method under atmospheric pressure. We have studied the structural and optical properties by using X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR) and ultra-violet visible near infrared (UV–Vis-NIR) spectroscopy. The lattice parameters calculated for the Mn-doped ZnO from XRD pattern were found to be slightly larger than those of the undoped ZnO, which indicate substitution of Mn in ZnO lattice. Compared with the Raman spectra for ZnO pure films, the Mn-doping effect on the spectra is revealed by the presence of additional peak around 524 cm−1 due to Mn incorporation. With increasing Mn doping the optical band gap increases indicating the Burstein–Moss effect. 相似文献
970.
Wei Zhang Wenxue Yu Lina Zhang Haibin Yang Wuyou Fu Minghui Li Yixing Li 《Superlattices and Microstructures》2012
Highly ordered arrays of Cu2ZnSnSe4 nanotubes have been successfully synthesized on fluorine-doped tin oxide glass substrate using ZnO nanorod arrays as sacrificial templates. The structure, morphology and optical properties of the Cu2ZnSnSe4 arrays were characterized by X-ray diffraction, Raman spectrometry, field-emission scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray, and UV–Vis absorption spectroscopy. The diameter and length of the Cu2ZnSnSe4 nanotubes can be adjusted by tuning the diameter and length of the ZnO nanorods. In addition, the effect of the length on the performance of the photoelectrochemical cells was also investigated. 相似文献