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91.
B. Ritzer M.A. Villegas J.M. Fernández Navarro 《Journal of Sol-Gel Science and Technology》1997,8(1-3):917-921
The darkening of silica sol-gel glasses doped with 0.05 mol% silver was studied. Six sols were prepared from TEOS and silver
nitrate. Different additives were used, to influence the chemical and physical states of silver: oxidizing or reducing agents
(H2O2, As2O5), colloid stabilizer (sodium citrate) and network modifiers (Li2O, CaO). Sols were gelified at 60°C and densified at 600°C. The samples without additives and those prepared with H2O2 at room temperature even if they were protected from light. With increased temperature, the darkening became samples were
heated above, 400°C, reversible bleaching took place. This darkening-bleaching is of thermal nature (“thermochromic effect”)
and seems to be determined by a reversible aggregation-disaggregation of tiny silver particles. The presence of sodium citrate,
as an additive delayed the darkening effect and the presence of CaO delayed it even further. Lithium oxide inhibited it totally. 相似文献
92.
Summary The paper deals with the use of controlled-porosity glasses (CPGs) as adsorbents for HPLC. The physicochemical and chromatographic properties of small-pore CPGs are compared to the analogous properties of silica gels. The results show good correlation between them and suggest the possibility of application of CPGs as adsorbents for liquid chromatography. 相似文献
93.
采用传统的熔融法制备了Er~(3+)掺杂的新型铋酸盐玻璃(Li_2O-SrO-ZnO-Bi_2O_3,LSZB),并对其光谱性质进行了表征,分析了玻璃的拉曼光谱、吸收光谱、荧光光谱,利用Judd-Ofelt理论研究了其荧光特性。LSZB玻璃样品中Er~(3+)的~4I_(13/2)→~4I_(15/2)跃迁发射峰位于1.53 μm处,半高宽约为78 nm。样品中Er~(3+)的~4I_(13/2)能级寿命为2.848 ms,量子效率为99.93%,受激发射截面达到9.76×10~(-21)cm~2。以上结果显示,Er~(3+)掺杂LSZB玻璃有良好的光谱特性。 相似文献
94.
R. Parthasarathy Ravi V. Prasad P. R. Sarode K. J. Rao 《Journal of Chemical Sciences》1982,91(3):201-205
The exafs of Co2+ has been studied in rare earth cobaltites and in sulphate and borate glasses. It has been found that the environment of Co2+ ions is very similar in these cases. It appears feasible to study local structures in glasses using probe ion exafs.
Communication No. 151 from the Solid State and Structural Chemistry Unit. 相似文献
95.
J.M. Conde Garrido J.A. Rocca M. Erazú M.A. Urea M. Fontana B. Arcondo 《Physica B: Condensed Matter》2009,404(18):2816-2818
GeySe(1−y) glasses are semiconductors but when Ag is added above certain threshold concentration, Agx[GeySe(1−y)](100−x) glasses behave as fast ionic conductors [Ureña et al., Solid State Ionics 176 (2005) 505]. This peculiar behavior may be attributed to the intrinsically inhomogeneous nature of these glasses where zones rich in metals coexist with zones of the host material. The conductivity transformation may be ascribed to the percolation of the Ag rich phase [Pradel et al., J. Phys.: Condens. Matter 15 (2003) S1561].Agx[Ge0.25Se0.75](100−x) glasses either massive or as films were obtained by melt quenching and pulsed laser deposition (PLD), respectively, in compositions belonging to the Se rich corner of the ternary phase diagram. Their amorphous nature and intermediate range order was checked employing X-ray diffractometry (XRD), the short range order was characterized by extended X-ray absorption fine structure (EXAFS) (Ge and Se K absorption edge) and their microstructure was characterized by scanning electron microscopy (SEM) and small angle X-ray scattering (SAXS). 相似文献
96.
A previously proposed model describing the trapping site of the interstitial atomic hydrogen in borate glasses is analyzed. In this model the atomic hydrogen is stabilized at the centers of oxygen polygons belonging to B–O ring structures in the glass network by van der Waals forces. The previously reported atomic hydrogen isothermal decay experimental data are discussed in the light of this microscopic model. A coupled differential equation system of the observed decay kinetics was solved numerically using the Runge Kutta method. The experimental untrapping activation energy of 0.7×10−19 J is in good agreement with the calculated results of dispersion interaction between the stabilized atomic hydrogen and the neighboring oxygen atoms at the vertices of hexagonal ring structures. 相似文献
97.
Aditya M. Vora 《Central European Journal of Physics》2008,6(2):253-262
The theoretical investigations of the superconducting state parameters (SSP) viz. electron-phonon coupling strength λ, Coulomb pseudopotential μ*, transition temperature T
C
, isotope effect exponent α and effective interaction strength N
O
V of six binary La100-C
Ga
C
(C = 16, 20, 22, 24, 26 and 28 at. %) metallic glasses have been reported using Ashcroft’s empty core (EMC) model potential
for the first time. Five local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid
et al. (F) and Sarkar et al. (S) are used in the present investigation to study the screening influence on the aforesaid properties. It is observed that
the electron-phonon coupling strength λ and the transition temperature T
C
are quite sensitive to the selection of the local field correction functions, whereas the Coulomb pseudopotential μ*, isotope effect exponent α and effective interaction strength N
O
V show weak dependences on the local field correction functions. The T
C
obtained from H-local field correction function are found in qualitative agreement with available experimental data and show
almost linear nature with the concentration (C) of ‘Ga’ element. A linear T
C
equation is proposed by fitting the present outcomes for H-local field correction function, which is in conformity with other
results for the experimental data. Also, the present results are found to be in qualitative agreement with other such earlier
reported data, which confirms the superconducting phase in the metallic glasses.
相似文献
98.
Tae Jin Park Sung Jin Park Dae Hyun Kim In Soo Kim Soo Kyung Kim Se Young Choi 《Current Applied Physics》2008,8(6):716-719
Optical switching and structural transformation of GeTe–Sb2Te3 pseudobinary alloys, Ge2Sb2Te5, Ge1Sb2Te4, and Ge1Sb4Te7, were studied for data storage application. As-deposited Ge2Sb2Te5, Ge1Sb2Te4, and Ge1Sb4Te7 thin films were amorphous and they crystallized to FCC and HCP upon heat treatment. Crystallization was accelerated by increasing the proportion of Sb2Te3 rather than GeTe in Ge–Sb–Te compounds; this was observed by reflectivity changes under nanosecond laser irradiation in static tester. The different crystallization kinetics according to composition might be affected by the structural incompatibility of GeTe under the ‘Umbrella Flip’ theory. 相似文献
99.
M. Sasaki V. Dupuis J.-P. Bouchaud E. Vincent 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,29(3):469-479
We study the deviations from perfect memory in negative temperature cycle spin glass experiments. It is known that the a.c.
susceptibility after the temperature is raised back to its initial value is superimposed to the reference isothermal curve
for large enough temperature jumps ΔT (perfect memory). For smaller ΔT, the deviation from this perfect memory has a striking non monotonous behavior: the `memory anomaly' is negative for small ΔT's, becomes positive for intermediate ΔT's, before vanishing for still larger ΔT's. We show that this interesting behavior can be reproduced by simple Random Energy trap models. We discuss an alternative
interpretation in terms of droplets and temperature chaos.
Received 23 May 2002 Published online 14 October 2002
RID="a"
ID="a"e-mail: sasaki@ipno.in2p3.fr 相似文献
100.
This paper reports a comparative study of shear banding in BMGs resulting from thermal softening and free volume creation.
Firstly, the effects of thermal softening and free volume creation on shear instability are discussed. It is known that thermal
softening governs thermal shear banding, hence it is essentially energy related. However, compound free volume creation is
the key factor to the other instability, though void-induced softening seems to be the counterpart of thermal softening. So,
the driving force for shear instability owing to free volume creation is very different from the thermally assisted one. In
particular, long wave perturbations are always unstable owing to compound free volume creation. Therefore, the shear instability
resulting from coupled compound free volume creation and thermal softening may start more like that due to free volume creation.
Also, the compound free volume creation implies a specific and intrinsic characteristic growth time of shear instability.
Finally, the mature shear band width is governed by the corresponding diffusions (thermal or void diffusion) within the band.
As a rough guide, the dimensionless numbers: Thermal softening related number B, Deborah number (denoting the relation of instability growth rate owing to compound free volume and loading time) and Lewis
number (denoting the competition of different diffusions) show us their relative importance of thermal softening and free
volume creation in shear banding. All these results are of particular significance in understanding the mechanism of shear
banding in bulk metallic glasses (BMGs).
Supported by the Chinese Academy of Sciences under the project “Multi-Scale Complex System” (Grant No. KJCX-SW-L08), the National
Natural Science Foundation of China (Grant Nos. 10725211 and 10721202), and the Doctorial Start-up Fund of Hunan University
of Science and Technology (Grant No. E50840) 相似文献