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51.
依据柱相比的热力学定义和反相液相色谱中溶质的计量置换保留理论(the stoichiometric dispheement heory of solute for retention,SDT-R),对反相液相色谱中固定相和流动相性质、温度对柱相比的影响进行了研究。结果表明:固定相的种类和配基的疏水性对柱相比影响较大,而流动相中有机溶剂的种类,特别是脂肪酸作为置换剂时,对柱相比的影响更大,而柱相比受温度的影响较小。此外,通过用27种小分子溶质对柱相比的测定,其logI和Z良好的线性关系,进一步证明柱相比是一个与溶质性质无关的常数。 相似文献
52.
A. Ono 《Chromatographia》1980,13(12):752-754
Summary Xylenol isomers can be resolved on most polyols (sugars or sugar alcohols) and polyethers (polyethylene glycol or polypropylene glycol) with hydrogen-bonding interaction. They are separated on vinical polyols which have more hydroxy hydrogen than tetrol, and even on vicinal triol when its hydroxy hydrogen is acidic (stronger proton donor). The stronger is the hydrogen bonding interaction between xylenols and the liquid phase, the better is the separation of 2,4- and 2,5-xylenol, and the poorer the separation of 2,4-and 2,3-xylenol. 相似文献
53.
Hidetoshi Taima 《Tetrahedron letters》2005,46(24):4161-4164
Two esters of chlorin e6 have been synthesized by esterification with aminoalcohols via the formation of acid chloride using oxalyl chloride and converted to the corresponding cationic water-soluble esters of chlorin e6. The visible absorption and circular dichroism spectra have revealed that these two cationic chlorin e6 esters synthesized are readily soluble in water as a monomer. 相似文献
54.
Summary Forming a polymer layer on the surface of siliceous materials is one of the methods for protecting the silica skeleton from dissolution in alkaline mobile phases as well as eliminating the negative influence of silanol groups on separated molecules e.g. proteins. Polysaccharides, especially their derivatives bearing amine groups, can play the role of the surface layer. This paper discusses the possibilities of preparing such a layer by cross-linking a dextran-polyimine mixture (rather than the traditionally used DEAE-dextran) deposited on the surface of the solid material. The results presented prove the utility of synthesized materials as supports for affinity ligands in high performance affinity chromatography or as supports for complexed metal ions in ligand-exchange chromatography. The properties of the sorbents with a polymer layer can be changed both by the composition of the cross-linked mixture and by chemical modification. 相似文献
55.
56.
Carbonate Isostructural Anions [SnX3]5? in the Compounds Rb6[SnX3]O0.5 and Cs6[SnX3]O0.5 with X = As, Sb, and Bi The metallic shining compounds Rb6[SnX3]O0.5 and Cs6[SnX3]O0.5 with X = As, Sb, and Bi were prepared from the melt starting from adequate mixtures of the elements and SnO2. They crystallize in the hexagonal system (space group P63/mmc, No. 194, Z = 2) with the lattice constants mentioned in ?Inhaltsübersicht”?. In the structures of the isotypic compounds tin and the main group(V) elements build up trigonal planar anions [SnX3]5? with X = As, Sb, and Bi isostructural to the carbonate anion, oxygen forms isolated O2? ions. The bond lengths Sn? X are significantly shortened with respect to the sums of Pauling covalent radii. The atoms of the units [SnX3]5? are coordinated by alkali metal cations forming trigonal prisms and the O2? anions occupy octahedral holes. 相似文献
57.
Q. Zhong L. He T. E. Beesley W. S. Trahanovsky P. Sun C. Wang D. W. Armstrong 《Chromatographia》2006,64(3-4):147-155
The comparisons of five different chiral stationary phases (CSPs) based on 2,6-dinitro-4-trifluoromethylphenyl (DNP-TFM) ether substituted β-cyclodextrin are presented. The five CSPs differ from each other in the linkage/spacer chemistry, or on the position of the substituents on β-cyclodextrin, or in the sequence of the synthetic procedure. The results show that there are two optimum combinations: (1) DNP-TFM randomly substituted on the β-cyclodextrin as the chiral selector along with a carbamate linkage chain bonding it to the silica support; and (2) β-cyclodextrin derivatized by DNP-TFM substituents only on the C-2 and C-3 positions of the cyclodextrin with an ether linkage chain anchoring it to the silica gel. These two combinations show complementary separations for some enantiomers. The spacer chain effect is much more pronounced for the CSP based on the β-cyclodextrin derivatives with DNP-TFM substituents only on C-2 and C-3 positions than its randomly substituted counterpart. The sequence of derivatizing the cyclodextrin and attaching it to silica gel also affects its selectivity and efficiency. The β-cyclodextrin should be derivatized before it is linked to the silica gel. 相似文献
58.
Chaowei Yuan Wen Cui Yanjuan Sun Jiadong Wang Ruimin Chen Jin Zhang Yuxin Zhang Fan Dong 《中国化学快报》2020,31(3):751-754
It is of a great challenge to develop semiconductor photocatalysts with potential possibilities to simultaneously enhance photocatalytic efficiency and inhibit generation of toxic intermediates.In this study,we developed a facile method to induce the La doping and cationic vacancie(V(Zn))on ZnO for the highly efficient complete NO oxidation.The photocatalytic NO removal efficiency increases from 36.2%to 53,6%.Most importantly,a significant suppressed NO2 production also has been realized.According to the DFT calculations,ESR spectra and in situ FTIR spectra,the introduction of La^3+induce the redistribution of charge carriers in La-ZnO,which promote the production of·O2^- and lead to the formation of V(Zn)for the formation of·OH,contributing to the complete oxidation of NO to nitrate.Besides,the conversion pathway of photocatalytic NO oxidation has been elaborated,This work paves a new way to simultaneously realize the photocatalytic pollutants removal and the inhibition of toxic intermediates generation for efficient and safe air purification. 相似文献
59.
Lämmerhofer M 《Journal of chromatography. A》2005,1068(1):31-57
A review on the advantages, peculiarities, and the potential of enantioselective capillary electrochromatography (CEC) in nonaqueous media is presented. Some fundamentals on CEC with particular focus on enantioselective CEC are discussed. The strategies, concepts, preferentially utilized chiral selectors and column technologies that have been utilized to succeed in highly efficient enantiomer separations by nonaqueous CEC are described thoroughly. 相似文献
60.
The crystal structures of the intermediate solid solution HT (high temperature) Ni1+δSn with δ=0.28, 0.52 and 0.61 (refined Ni contents) have been analyzed in detail by X-ray diffraction on single crystals. The previously reported basic atomic arrangement, i.e., a NiAs/Ni2In structure type (P63/mmc, Ni(1) on 2a, 0 0 0, Ni(2) with an occupancy δ on 2d, and Sn on 2c, ), is confirmed. However, strong anisotropic atomic displacements occur for Sn within the a-b plane of the hexagonal unit cell, which require a Gram-Charlier expansion of the probability density function of Sn in order to obtain a good fit to the diffraction data. Direction, magnitude and the concentration dependence of the displacements can be interpreted in terms of the geometrical requirements of the different local atomic configurations in the planes z=±1/4, so that the displacements can be identified as static ones. 相似文献