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21.
The structure of the 2-thiazolylazosalicylic acid molecule, TAS, has been determined by means of quantum SCF-CI calculations. The ionization potential and the electron affinity of TAS molecule were calculated to have the values 9.057 and 2.56 eV respectively. The solvation energies in different solvents, and the bond orders of the TAS molecule were calculated for the neutral state, the oxidized form (the cation) and the reduced form (the anion). Mixed solvent studies were carried out with TAS and 2-benzothiazolylazosalicylic acid (BTAS), using polar solvents (EtOH and MeOH) to confirm the formation of a solvent-solute complex. The azo group in the TAS molecule nas a considerable contribution in the SCFLUMO; thus cathodic reduction has been focused on the azo group and was verified experimentally by cathodic reduction. 相似文献
22.
Bruna Cláudia Lourenção Roberta Antigo Medeiros Romeu C. Rocha‐Filho Orlando Fatibello‐Filho 《Electroanalysis》2010,22(15):1717-1723
A cathodically pretreated boron‐doped diamond electrode was used for the simultaneous anodic determination of ascorbic acid (AA) and caffeine (CAF) by differential pulse voltammetry. Linear calibration curves (r=0.999) were obtained from 1.9×10?5 to 2.1×10?4 mol L?1 for AA and from 9.7×10?6 to 1.1×10?4 mol L?1 for CAF, with detection limits of 19 μmol L?1 and 7.0 μmol L?1, respectively. This method was successfully applied for the determination of AA and CAF in pharmaceutical formulations, with results equal to those obtained using a HPLC reference method. 相似文献
23.
阴极微弧电沉积技术是一种在材料表面通过微弧放电沉积陶瓷层的表面处理技术,利用该技术可以在金属及非金属表面生成耐磨、耐蚀性能优异的陶瓷膜层.本文介绍了阴极微弧电沉积技术的研究现状以及应用阴极微弧电沉积技术制备Al2O3陶瓷层的方法和基本原理,并且对阴极微弧电沉积技术的影响因素进行了总结,阐述了阴极微弧电沉积技术的应用前景和存在的问题. 相似文献
24.
《Electroanalysis》2017,29(5):1222-1231
A microbial sensor, namely carbon paste electrode (CPE) modified with Citrobacter freundii (Cf–CPE) has been developed for the detection of hexavalent (Cr(VI)) and trivalent (Cr(III)) chromium present in aqueous samples using voltammetry, an electroanalytical technique. The biosensor developed, demonstrated about a twofold higher performance as compared to the bare CPE for the chosen ions. Using cyclic voltammetry and by employing the fabricated Cf–CPE, the lowest limit of detection (LLOD) of 1x10−4 M and 5x10−4 M for Cr(VI) and Cr(III) ions respectively could be achieved. By adopting the Differential Pulse Cathodic Stripping Voltammetric technique, the LLOD could be further improved to 1x10−9 M and 1x10−7 M for Cr(VI) and Cr(III) ions respectively using the biomodified electrodes. The reactions occurring at the electrode surface‐chromium solution interface and the mechanisms of biosorption of chromium species onto the biosensor are discussed. The stability and utility of the developed biosensor for the analysis of Cr(VI) and Cr(III) ions in chromite mine water samples has been evaluated. 相似文献
25.
采用浸渍-提拉法制备了一系列石墨烯氧化物(GO)薄膜,并通过X射线衍射(XRD),扫描电镜(SEM),傅里叶变换红外光谱,紫外-可见吸收光谱和光电化学测量等技术对样品进行了表征.在GO电极上观察到阴极光电流,且光电流密度受薄膜的厚度影响.GO薄膜电极厚度为27nm时,光电流密度为0.25μA·cm-2.此外,GO电极的光电响应还受紫外光照影响,随着紫外光照时间的延长,阴极光电流逐渐减小.该工作提供了简便的通过控制薄膜厚度或紫外光照时间来控制GO薄膜半导体光电化学性能的方法. 相似文献
26.
以硼氢化钠为还原剂化学镀镍的电化学研究 总被引:1,自引:0,他引:1
采用线性电位扫描伏安法研究了以硼氢化钠为还原剂的化学镀镍体系, 考查了镀液组成及工艺条件对化学镀镍硼阴、阳极过程的影响, 结果表明: 乙酸镍和硼氢化钠含量的提高分别促进了Ni2+的还原反应和BH4-的氧化反应; 乙二胺、氢氧化钠以及添加剂硫脲、糖精钠对阴、阳极反应均有不同程度的抑制作用, 同时添加剂中的硫元素加速了镍的氧化; 升高温度有利于阴、阳极反应的进行. 相似文献
27.
Cathodic stripping mechanism of an insoluble salt coupled with a homogenous chemical reaction is considered both theoretically and experimentally under conditions of square‐wave voltammetry. For the mercury electrode in aqueous solution, the electrode reaction is described as L(aq)+Hg(l)=HgL(s)+2e?, where L(aq) is the reactive ligand that forms a sparingly soluble compound HgL(s). The electrode reaction is coupled with a homogenous, first‐order chemical reaction, A(aq)=L(aq). Theoretical predictions are confirmed by experiments with 6‐mercaptopurine‐9‐D‐riboside in the presence of nickel(II) ions. 相似文献
28.
29.
Dierk Knittel V. Suryanarayana Rao 《Monatshefte für Chemie / Chemical Monthly》1986,117(10):1185-1193
Cathodic reduction of -azidochalcones under slightly protic conditions proves to be an excellent method for a selective conversion of the azido function to an amino group without affecting other reducible parts of the molecules. The amino-propenones retain theZ-configuration about the C=C-bond of the starting material, whereas N-acetyl derivatives, obtained under mildly acetylating conditions, are partially isomerised. The low reduction potential of N,N-diacetyl-enamines of this type prevents their direct one step synthesis by electrolysis of azidochalcones under strongly acetylating conditions. The voltammetric behaviour of the azides and their reduction pathway is discussed.
Elektrolytische Untersuchungen an Vinylaziden, 6. Mitt.Elektrolytische Reduktion von Azidochalkonen
Zusammenfassung Die kathodische Reduktion von -Azidopropenon erweist sich als ausgezeichneter Weg, um selektiv zu Enaminen zu gelangen, ohne (wie chemische Reduktionsmittel) auch andere Gruppierungen anzugreifen. Durch die Kontrolle von Protonierungs- bzw. Acetylierungsschritten lassen sich die stabileren N-Acetylamine erhalten. Das niedrig liegende Reduktionspotential der N,N-Diacetylamino-propenone verhindert, daß sie in einer Einstufensynthese bei der Reduktion der Azidochalkone unter stark acylierenden Bedingungen erhältlich sind. Das voltammetrische Verhalten der Azide und ihr Reaktionsweg bei der kathodischen Reduktion werden diskutiert.相似文献
30.
The cathodic preparation of enamino ketones from enazidoketones has been generalised to include heteroaromatic and aliphatic derivatives. Mechanistically the role of different sites of protonation, either on N1 of the N3-group or on carbonyl depending on electrolysis potential and acid strength, apparent by product distribution, is clarified. Aldehydic groups are preferentially reduced compared to the vinylazide part. Purely aliphatic azidoketones yield conjugated dienes under reductive acetylation, which might be useful for cycloaddition reactions.Die kathodische Synthese von Enaminoketonen aus ungesättigten Azidoketonen wurde auf heteroaromatisch substituierte und auf rein aliphatische Derivate übertragen. Zum Reduktionsmechanismus wurde der Einfluß verschiedener Stellen der Protonierung (am N1 der N3-Gruppe bzw. an der Carbonylgruppe), abhängig von Potential und Säurestärke, untersucht. Aldehydische Gruppen als weitere funktionelle Gruppen im Enazid werden leichter als die Vinylazide reduziert. Die rein aliphatischen Enazidoketone ergeben bei reduktiver Acylierung konjugierte Diene.
Elektrolytische Untersuchungen an Vinylaziden, 7. Mitt.: Kathodische Synthese von 2-Amino-2-propen-1-onen相似文献