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51.
《中国化学快报》2020,31(7):1895-1898
By using ambient air as the oxidant and malic acid as the promoter, a practical method for the preparation of 2-aminobenzothiazoles through visible-light-initiated cascade reaction of aromatic amines and KSCN in eco-friendly bis(methoxypropy)ether under metal-, hazardous additive-, photocatalyst-free conditions was established. 相似文献
52.
53.
Rhodium Enalcarbenoids: Direct Synthesis of Indoles by Rhodium(II)‐Catalyzed [4+2] Benzannulation of Pyrroles 下载免费PDF全文
Sudam Ganpat Dawande Vinaykumar Kanchupalli Jagadeesh Kalepu Haribabu Chennamsetti Bapurao Sudam Lad Dr. Sreenivas Katukojvala 《Angewandte Chemie (International ed. in English)》2014,53(16):4076-4080
Disclosed herein is the design of an unprecedented electrophilic rhodium enalcarbenoid which results from rhodium(II)‐catalyzed decomposition of a new class of enaldiazo compounds. The synthetic utility of these enalcarbenoids has been successfully demonstrated in the first transition‐metal‐catalyzed [4+2] benzannulation of pyrroles, thus leading to substituted indoles. The new benzannulation has been applied to the efficient synthesis of the natural product leiocarpone as well as a potent adipocyte fatty‐acid binding protein inhibitor. 相似文献
54.
The enantioselective cyclization of the prochiral cyclic substrates1 to7 and26, can be carried out in theneat using S-proline as catalyst. The substrates18 to22 and27 could not be cyclized with S-proline but could be cyclized with a mixture of S-phenylalanine and d-camphorsulphonic acid.
The enantioselective cyclization of prochiral acyclic triones45 and47 and also the racemic tricarbonyl compounds54 to57 could also be carried out in theneat using S-proline as catalyst. The optically active enediones obtained in the above cyclizations could also be obtained directly
from 1,3-diones or 2-hydroxymethylene cycloalkanones in a one-pot reaction with methyl vinyl ketone (MVK) and S-proline in
the absence of solvents.13C NMR studies of the one-pot synthesis ofS-11 andS-14 reveal that the annulations involve initial formation of an acid-base complex followed by a Michael reaction and then an
enantioselective cyclization. Such enantioselective cyclizations probably occur on the surface of S-proline crystals. 相似文献
55.
56.
The warped deformed conifold background of type IIB theory is dual to the cascading SU(M(p+1))×SU(Mp) gauge theory. We show that this background realizes the (super-)Goldstone mechanism where the U(1) baryon number symmetry is broken by expectation values of baryonic operators. The resulting massless pseudo-scalar and scalar glueballs are identified in the supergravity spectrum. A D-string is then dual to a global string in the gauge theory. Upon compactification, the Goldstone mechanism turns into the Higgs mechanism, and the global strings turn into ANO strings. To cite this article: S.S. Gubser et al., C. R. Physique 5 (2004).
Résumé
La configuration de fond pour la théorie de type IIB donnée par le conifold voilé déformé est duale à la cascade de théorie de jauge SU(M(p+1))×SU(Mp). Nous montrons que cette configuration donne une réalisation du mécanisme de (super-)Goldstone où la symètrie baryonique U(1) est brisée par la valeur moyenne dans le vide des opérateurs baryoniques. Les boules de glue pseudo-scalaires et scalaires de masse nulle résultantes sont identifiées dans le spectre de supegravité. Une D-corde est alors duale à une corde globale dans la théorie de jauge. Après compactification, le mécanisme de Goldstone devient un mécanisme de Higgs, et une corde globale devient une corde ANO. Pour citer cet article : S.S. Gubser et al., C. R. Physique 5 (2004). 相似文献57.
Multivariate Refinement Equations and Convergence of Cascade Algorithms in Lp(0〈p〈1)Spaces 总被引:1,自引:0,他引:1
SongLI 《数学学报(英文版)》2003,19(1):97-106
We consider the solutions of refinement equations written in the form
where the vector of functions ϕ = (ϕ
1, ..., ϕ
r
)
T
is unknown, g is a given vector of compactly supported functions on ℝ
s
, a is a finitely supported sequence of r × r matrices called the refinement mask, and M is an s × s dilation matrix with m = |detM|. Inhomogeneous refinement equations appear in the construction of multiwavelets and the constructions of wavelets on a finite
interval. The cascade algorithm with mask a, g, and dilation M generates a sequence ϕ
n
, n = 1, 2, ..., by the iterative process
from a starting vector of function ϕ
0. We characterize the L
p
-convergence (0 < p < 1) of the cascade algorithm in terms of the p-norm joint spectral radius of a collection of linear operators associated with the refinement mask. We also obtain a smoothness
property of the solutions of the refinement equations associated with the homogeneous refinement equation.
This project is supported by the NSF of China under Grant No. 10071071 相似文献
58.
This review focuses mainly on recent endeavors in the field of cyclizations triggered by the catalytic hydroamination (formal or direct) of alkynes. The new strategies developed offer an efficient and convenient entry to several heterocycles of biological importance. 相似文献
59.
60.
A mild, eco‐friendly and efficient route for the synthesis of quinolines and polycyclic quinolines via Friedländer annulation using cyanuric chloride as a catalyst under aqueous conditions is described. 相似文献