Phosphorylthioacetamides in the synthesis of annulated quinoxalines

Diethoxyphosphorylthioacetamide in the reaction with 2,3-dichloroquinoxaline acted as a thionating reagent, giving diethoxyphosphorylacetonitrile and 2-chloro-3-[(3-chloro-2-quinoxalinyl)thio]quinoxaline. Reactions of phosphorylthioacetamides with N-methylquinoxalinium iodide in alcohol media in the presence of a base proceeded stereoselectively to afford cis-3-phosphoryl-1,3,3a,4,9,9a-hexahydro-2H-pyrrolo[2,3-b]quinoxaline-2-thiones. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1010–1013, May, 2007.     

The six-membered annulation reaction involving sequential palladium-catalyzed allylic alkylation and Michael addition: scope and limitations

The palladium-catalyzed condensation of a variety of active methylene compounds with methyl 6-acetoxymethyl-hepta-2,6-dienoate was investigated. The six-membered adducts resulting from a η³ palladium complex alkylation-Michael addition sequence were obtained with moderate to good yields. In some cases, further evolution of the primary adduct was observed. The process has been expanded to access nitrogen heterocycles by using sodium p-toluenesulfonamide as the nucleophilic partner.     

Multivariate Refinement Equations and Convergence of Cascade Algorithms in Lp（0〈p〈1）Spaces

We consider the solutions of refinement equations written in the form

级联光交叉连接和光分插复用系统串扰研究

分析了光网络节点串扰产生的原因以及级联光交叉连接(OXC)和光分插复用(OADM)系统的串扰,对级联系统进行模拟,计算并分析了光开关隔离度、上路信号的功率差对系统误码率的影响,得出了光开关隔离度是产生串扰的主要原因、在光开关前进行功率均衡有利于提高系统误码性能等结论.     

CO2/R290二元混合制冷剂稳定性能实验研究

对CO2/R290二元混合制冷剂的稳定性能进行了实验测试。结果表明蒸发器、冷凝器和蒸发冷凝器中的温度都比较稳定,机组整体性能稳定。     

复叠系统低温级制冷剂的循环性能对比实验

通过实验测试,比较了不同冷凝温度和蒸发温度下复叠系统低温级常用制冷工质R13、R23、R503和RS08B的COP、压比及制冷量等循环性能,又结合各制冷工质的环境性能、热工性能,分析了现有常用复叠系统低温级制冷工质各自的优缺点,为新工质的开发及进一步的制冷性能对比实验工作提供了有益的帮助.     

Variations on the warped deformed conifold

The warped deformed conifold background of type IIB theory is dual to the cascading SU(M(p+1))×SU(Mp) gauge theory. We show that this background realizes the (super-)Goldstone mechanism where the U(1) baryon number symmetry is broken by expectation values of baryonic operators. The resulting massless pseudo-scalar and scalar glueballs are identified in the supergravity spectrum. A D-string is then dual to a global string in the gauge theory. Upon compactification, the Goldstone mechanism turns into the Higgs mechanism, and the global strings turn into ANO strings. To cite this article: S.S. Gubser et al., C. R. Physique 5 (2004).

Résumé

La configuration de fond pour la théorie de type IIB donnée par le conifold voilé déformé est duale à la cascade de théorie de jauge SU(M(p+1))×SU(Mp). Nous montrons que cette configuration donne une réalisation du mécanisme de (super-)Goldstone où la symètrie baryonique U(1) est brisée par la valeur moyenne dans le vide des opérateurs baryoniques. Les boules de glue pseudo-scalaires et scalaires de masse nulle résultantes sont identifiées dans le spectre de supegravité. Une D-corde est alors duale à une corde globale dans la théorie de jauge. Après compactification, le mécanisme de Goldstone devient un mécanisme de Higgs, et une corde globale devient une corde ANO. Pour citer cet article : S.S. Gubser et al., C. R. Physique 5 (2004).     

Intra-Nuclear Cascade (INC) code for simulation of meson photoproduction in nuclei

η meson photoproduction in the ¹⁴N nucleus was studied using simulations done with INC (Intra-Nuclear Cascade) code. The probability for mesons and nucleons to escape the nucleus on different steps of the reaction was evaluated. These results predict the possibility of studying elastic and inelastic η meson interactions with intra-nuclear nucleons using the recoil proton as a tag for the case of slow η meson and fast recoil proton.     

复叠式低温保存箱系统设计关键问题分析

以R404A/R23为制冷剂,利用二元单级复叠制冷循环,开发出-86℃大容量低温保存箱。文中对蒸发器优化布置、冷凝蒸发器中间温度确定、毛细管设计以及如何保证设备安全运行等关键问题进行了分析。     

Electromagnetically induced transparency in N-level cascade schemes

We examine electromagnetically induced transparency (EIT) in cascade schemes with N levels and N−1 fields. We show that transparency effects are present when N is odd and that destruction of EIT is present on line centre when N is even. We predict multiple dark resonances in such schemes due to multiphoton EIT effects. By examining atomic rubidium we propose methods of achieving such schemes by use of coupling rf fields into hyperfine levels.