Effect of epitaxial crystallization on packet-like space charge characteristics in low-density polyethylene under multi-field coupling conditions

In order to study the effect of epitaxial crystallization on charge transport in low-density polyethylene (LDPE) under multi-field coupling conditions, three typical epitaxial crystallizations, namely disorder (glass substrate), crossover (isotactic polypropylene substrate), and parallel (polytetrafluoroethylene substrate), were prepared and denoted as LD-G, LD-iPP, and LD-PT, respectively. Packet-like space charge through samples was analyzed by the pulsed electro-acoustic (PEA) method. It is shown that different microscopic surface morphologies appeared in the LDPE samples with different epitaxial crystallizations, which, however, do not change the crystalline structure of the bulk. Packet-like space charge phenomena were observed and the distortion field increased with the temperature which could be attributed to the larger amount of charge injection in a shorter period. The differences of the amount and injection rate of the space charge were explained and verified considering the typical chain alignment of epitaxial crystallization, which, in our opinions, contributes to the pass over of positive charge in LD-iPP samples.     

基于FCS的海水痕量元素的通用测定平台

为了对海水痕量营养盐与重金属进行测定,基于FCS的设计思想,采用流动注射分光光度法研制了具有自适应外界设备、快速组建多种仪器及全数字化通信等特点的软硬件一体化的通用测定平台。平台以ARM(S3C2416)处理器为核心,Linux为操作系统,LCD作为人机交互显示,触摸屏或者USB鼠标完成输入控制,构成完整的嵌入式工控机系统;采用CAN总线并制定CAN应用层协议管理设备,提高了系统的可靠性及抗干扰能力。实际测试和应用证明,该平台自动化程度高,通用性、重用性及可扩展性均较强,可组建成亚硝氮、硝氮、氨氮、活性磷、铁等多种痕量元素的实验室、船载和原位分析系统,检测限为nmol/L级别。平台对样品的测试准确度与商品专用仪器无显著性差异。     

基于豆甾醇衍生物的超分子凝胶的合成与性能

设计合成出两种含有不同结构单元的新型豆甾醇衍生物凝胶因子（化合物1和2）。通过扫描电子显微镜（SEM）、傅里叶变换红外光谱（FT-IR）和紫外-可见光谱（UV-Vis）等技术手段对形成凝胶的结构和性能进行研究。结果表明,两种凝胶因子可分别在二甲基亚砜及甲醇溶剂中形成稳定的凝胶。其中化合物1还可在二甲基亚砜/水混合溶液体积比分别为9∶1、8∶2和7∶3中形成稳定的凝胶。当化合物1和2在DMSO溶剂中以质量浓度均为12 mg/mL形成凝胶时,二者的凝胶-溶胶相转变温度（T_gel）分别为51和46 ℃,表明随着凝胶因子中甾体结构单元的增加,其形成凝胶的热稳定性显著下降。在此基础上,以化合物1制备的凝胶为载体,通过紫外-可见光谱对罗丹明B、亚甲基蓝和阿霉素的包封与释放应用进行了研究。结果表明,制备的凝胶可以作为药物载体,并在240 min时在水中达到的最大释放值为84％。本文为豆甾醇衍生物凝胶的制备,及将其作为药物载体在药物输送领域的应用提供了有益的思路。     

Design of fluorescence system based on rutin functionalized gold nanoparticles: Sensitive detection of etimicin via a smartphone in the food and human samples

The abuse and contamination of antibiotics have long been a hot issue of global concern. On the basis of inner filter effect (IFE), this article established the fluorescence detection system of a mixture of Rutin-AuNPs and 7-hydroxycoumarin, realizing the rapid and sensitive detection of etimicin. The system was also successfully applied to actual samples through a smartphone sensing platform. Due to the antioxidant property of rutin, Rutin-AuNPs were green synthesized with uniform particle size, good monodispersity, and favorable stability. As a good fluorescent quencher, Rutin-AuNPs could effectively quench the fluorescence of 7-hydroxycoumarin based on IFE with a quenching percent of 89.81 %. However, etimicin could bind tightly to the surface of Rutin-AuNPs through charge attraction, Au-N bond, and affinity between sugars, leading to the replacement of 7-hydroxycoumarin. In addition, one or more of the above effects caused aggregation of Rutin-AuNPs, leading to fluorescence recovery rapidly. A linear response between the fluorescence system and etimicin was reasonably established with detection limits as low as 0.12 μM. This system was successfully applied to real sample detection. Moreover, the great potential smartphone sensing platform was also built for practical application owing to its advantages of digitalization and portability.     

Fabrication of a solution-processed thin-film transistor using zinc oxide nanoparticles and zinc acetate

We have fabricated a solution-processed ZnO thin-film transistor without vacuum deposition. ZnO nanoparticles were prepared by the polyol method from zinc acetate, polyvinyl pyrrolidone, and diethyleneglycol. The solution-processable semiconductor ink was prepared by dispersing the synthesized ZnO in a solvent. Inverted stagger type thin-film transistors were fabricated by spin casting the ZnO ink on the heavily doped Si wafer with 200 nm thick SiO₂, followed by evaporation of Cr/Au source and drain electrodes. After the drying and heat treatment at 600 C, a relatively dense ZnO film was obtained. The film characteristics were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). In order to obtain the electrical properties of the solution-derived transistor, the on–off ratio, threshold voltage, and mobility were measured.     

石化厂区有毒气体泄漏在线监测平台的构建

针对石化厂区在生产过程中可能发生有毒气体泄露带来的生产安全问题,构建了石化厂区有毒气体在线监测平台。该平台是由PC监控中心、网络监控中心、ARM便携式终端、安卓手机客户端组成。实现对石化厂区中有毒气体及环境参数的实时、在线监测和预警,使生产管理人员掌握石化厂区的有毒气体实时动态信息,对可能引发危险事故的因素及时排除,把危险控制在始发阶段,以实现化工生产的安全、持续、高效进行。测试结果表明该平台能实现所设计的各项功能,并具有良好的稳定性、安全性和实用性。     

基于Web的实时漆包线材生产设备监控平台设计

为了实现漆包机生产的远程监控,设计了一款基于Web的实时漆包机远程监控平台。该平台使用模块化,可扩展的设计方案,采用了Spring MVC的后台Web应用程序框架,基于Modbus协议的数据交互,Ajax方式的网络数据异步提交以及无刷新的图表显示技术。传统的监控平台只能通过以太网在企业内部访问,而该平台可接入互联网,可实现随时随地通过电脑及或者移动终端对生产设备各部分的温度点、电机风机转速、耗电量统计的实时监视,对温度的上下限及电机转速进行远程控制,接收设备状态异常的实时报警,数据存储分析。实验测试表明,该平台的实时性和稳定性均能达到车间生产的要求。     

QoS enhancement in OFDM based systems under transceiver impairments

Broadband wireless systems generally use orthogonal frequency division multiplexing (OFDM) with link adaptation (LA) to achieve high throughput while meeting bit error rate (BER) constraint. OFDM systems are known to be affected by non-linearity of high power amplifier (HPA) at transmitter, carrier frequency offset (CFO), symbol timing offset (STO) and channel estimation error at the receiver. The delay in feedback of channel state information (CSI) further affects the performance of LA procedures. The focus of this work is on performance analysis in presence of simultaneous affect of all these impairments on LA based OFDM systems. The results are found to be useful for threshold readjustment which is essential for successful implementation of LA scheme to counter the effects of change in operating conditions from ideal to as listed above.     

微信平台辅助的农科有机化学实验课混合式教学实践

利用微信公众平台和移动网络辅助教学的优点,改革农科院校中非化学专业公共基础有机化学实验课传统教学模式,构建了“课前翻转教学,课中解惑内化,课后巩固提高”的三段混合式新型教学模式,并对此类教学模式的构建原则,特色微信公众平台建设、应用情况及注意事项进行实践研究。     

Wearable Multiparameter Platform Based on AlGaN/GaN High‐electron‐mobility Transistors for Real‐time Monitoring of pH and Potassium Ions in Sweat

Biosensors based on field‐effect transistor (FET) structures have attracted considerable attention because they offer rapid, inexpensive parallel sensing and ultrasensitive label‐free detection. However, long‐term repeatable detection cannot be performed, and Ag/AgCl reference electrode design is complicated, which has hindered FET biosensors from becoming truly wearable health‐monitoring platforms. In this paper, we propose a novel wearable detection platform based on AlGaN/GaN high‐electron‐mobility transistors (HEMTs). In this platform, a sweatband was used to continuously collect sweat, and a pH detecting unit and a potassium ion detecting unit were formed by modifying different sensitive films to realize the long‐term stable and repeatable detection of pH and potassium ions. Experimental data show that the wearable detection platform based on AlGaN/GaN HEMTs has good sensitivity (pH 3–7 sensitivity is 45.72 μA/pH; pH 7.4–9 sensitivity is 51.073 μA/pH; and K⁺ sensitivity is 4.94 μA/lgα_K⁺), stability (28 days) and repeatability (the relative standard deviation (RSD) of pH 3–7 sensitivity is 2.6 %, the RSD of pH 7.4–9 sensitivity is 2.1 %, and the RSD of K⁺ sensitivity is 7.3 %). Our newly proposed wearable platform has excellent potential for predictive analytics and personalized medical treatment.