全文获取类型
收费全文 | 75518篇 |
免费 | 4467篇 |
国内免费 | 8485篇 |
专业分类
化学 | 53423篇 |
晶体学 | 1792篇 |
力学 | 1042篇 |
综合类 | 424篇 |
数学 | 19962篇 |
物理学 | 11827篇 |
出版年
2024年 | 55篇 |
2023年 | 518篇 |
2022年 | 1189篇 |
2021年 | 1462篇 |
2020年 | 1408篇 |
2019年 | 2698篇 |
2018年 | 1743篇 |
2017年 | 2514篇 |
2016年 | 2002篇 |
2015年 | 2004篇 |
2014年 | 2797篇 |
2013年 | 5650篇 |
2012年 | 3950篇 |
2011年 | 4773篇 |
2010年 | 4096篇 |
2009年 | 4815篇 |
2008年 | 5155篇 |
2007年 | 5062篇 |
2006年 | 4551篇 |
2005年 | 3913篇 |
2004年 | 3810篇 |
2003年 | 3162篇 |
2002年 | 2998篇 |
2001年 | 2147篇 |
2000年 | 2050篇 |
1999年 | 1748篇 |
1998年 | 1567篇 |
1997年 | 1318篇 |
1996年 | 1265篇 |
1995年 | 1173篇 |
1994年 | 1050篇 |
1993年 | 887篇 |
1992年 | 826篇 |
1991年 | 580篇 |
1990年 | 416篇 |
1989年 | 447篇 |
1988年 | 335篇 |
1987年 | 260篇 |
1986年 | 236篇 |
1985年 | 286篇 |
1984年 | 256篇 |
1983年 | 128篇 |
1982年 | 188篇 |
1981年 | 208篇 |
1980年 | 158篇 |
1979年 | 140篇 |
1978年 | 108篇 |
1977年 | 96篇 |
1976年 | 69篇 |
1973年 | 53篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
51.
许雪松 《原子与分子物理学报》2006,23(1):137-142
应用密度泛函B3LYP/6—31+G(d,p)方法对C8H80-(H2O)n(n=1~5)团簇这种弱相互作用体系进行垒自由度能量梯度优化,得到该系列团簇的稳定蛄构.计算结果表明。在该系列二元团簇中,一方面水分子数目的多少对苯基丙酮分子的结构影响很小,另一方面由于苯基丙酮分子的存在,破坏了团簇中水分子的对称性结构,在团簇内部极力形成O—H—O这样弯曲的有方向性的氢键.对苯基丙酮-水这样结构复杂的团簇,指认光谱的难度非常大,本文只讨论了与C=O有关的振动峰和水分子的对称伸缩振动的最强峰. 相似文献
52.
53.
Shougo Higashi 《Surface science》2006,600(3):591-597
We have studied the individual adsorption of Mn and Bi, and their coadsorption on Cu(0 0 1) by low-energy electron diffraction (LEED). For Mn, we have determined the c(2 × 2) structure formed at 300 K, whose structure had been determined by several methods. We reconfirmed by a tensor LEED analysis that it is a substitutional structure and that a previously reported large corrugation (0.30 Å) between substitutional Mn and remaining surface Cu atoms coincides perfectly with the present value. In the individual adsorption of Bi, we have found a c(4 × 2) structure, which is formed by cooling below ∼250 K a surface prepared by Bi deposition of ∼0.25 ML coverage at 300 K where streaky half-order LEED spots appear. The c(4 × 2) structure has been determined by the tensor LEED analysis at 130 K and it is a substitutional structure. In the coadsorption, we found a c(6 × 4) structure, which has been determined by the tensor LEED analysis. It is very similar to the previously determined structure of the c(6 × 4) formed by coadsorption of Mg and Bi, and embedded MnBi4 clusters are arranged in the top Cu layer instead of MgBi4. Large lateral displacements of Bi atoms in the c(6 × 4)-(Mn + Bi) suggest that the Mn atoms undergo the size-enhancement caused by their large magnetic moment. 相似文献
54.
The consequences of Ge deposition on Br-terminated Si(1 0 0) were studied with scanning tunneling microscopy at ambient temperature after annealing at 650 K. One monolayer of Br was sufficient to prevent the formation of Ge huts beyond the critical thickness of 3 ML. This is possible because Br acts as a surfactant whose presence lowered the diffusivity of Ge adatoms. Hindered mobility was manifest at low coverage through the formation of short Ge chains. Further deposition resulted in the extension and connection of the Ge chains and gave rise to the buildup of incomplete layers. The deposition of 7 ML of Ge resulted in a rough surface characterized by irregularly shaped clusters. A short 800 K anneal desorbed the Br and allowed Ge atoms to reorganize into the more energetically favorable “hut” structures produced by conventional Ge overlayer growth on Si(1 0 0). 相似文献
55.
J. Carlos Díaz-Ramos Ramón Vázquez-Lorenzo 《Differential Geometry and its Applications》2006,24(4):433-442
Explicit examples of Osserman 4-manifolds with exactly two distinct eigenvalues of the Jacobi operators, α and β=4α≠0, are given. The former has multiplicity two and is a double root of the minimal polynomial of the Jacobi operators. 相似文献
56.
Michael Carr 《Topology and its Applications》2006,153(12):2155-2168
Given a graph Γ, we construct a simple, convex polytope, dubbed graph-associahedra, whose face poset is based on the connected subgraphs of Γ. This provides a natural generalization of the Stasheff associahedron and the Bott-Taubes cyclohedron. Moreover, we show that for any simplicial Coxeter system, the minimal blow-ups of its associated Coxeter complex has a tiling by graph-associahedra. The geometric and combinatorial properties of the complex as well as of the polyhedra are given. These spaces are natural generalizations of the Deligne-Knudsen-Mumford compactification of the real moduli space of curves. 相似文献
57.
Francis Jordan 《Topology and its Applications》2006,153(14):2386-2412
An abstract scheme using particular types of relations on filters leads to general unifying results on stability under supremum and product of local topological properties. We present applications for Fréchetness, strong Fréchetness, countable tightness and countable fan-tightness, some of which recover or refine classical results, some of which are new. The reader may find other applications as well. 相似文献
58.
Debendra K. Mohapatra Dhananjoy Mondal Mukund S. Chorghade Mukund K. Gurjar 《Tetrahedron letters》2006,47(52):9215-9219
The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy. 相似文献
59.
A Volterra type integral equation in a Hilbert space with an additional linear operator L and a spectral parameter depending
on time is considered. If the parameter does not belong to the spectrum of L unconditional solvability of the considered problem
is proved. In the case where the initial value of the parameter coincides with some isolated point of the spectrum of the
operator L sufficient conditions for solvability are established. The obtained results are applied to the partial integral
equations associated with a contact problem of the theory of elasticity. 相似文献
60.
M.F. Al-Kuhaili 《Journal of luminescence》2006,117(2):209-216
Thin films of sodium salicylate were deposited by spin coating from a solution prepared by dissolving sodium salicylate in methanol. The films were characterized by X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, UV-visible spectroscopy and spectrofluorometry. The films were crystalline with a strong blue fluorescence peak at an emission wavelength of 419.3 nm. The influence of solution concentration, spin speed and annealing temperature on the fluorescence intensity was studied. Optimum results were obtained with a solution whose concentration was 2.5 M. It was found that lower spin speed resulted in higher fluorescence intensity. Moreover, the fluorescence intensity decreased as the annealing temperature was increased. The durability of the films over a period of 30 days was also investigated, and films annealed at higher temperatures were found to be less degraded with time. 相似文献