双通道电光调Q射频激励波导CO2激光器研究

报道了双通道可调谐电光调Q射频激励波导CO2激光器,其中一通道是光栅选支电调Q的脉冲激光输出,调Q脉冲重复频率1Hz-10kHz可调,,脉冲峰值功率为150W,脉冲宽度为180ns,另一通道是光栅选支连续激光输出,可用压电陶瓷调节激光频率,同时分析了激光外差频率调谐范围,实验上获得最大脉冲激光外差频率调谐范围为150MHz。     

CO2气、液、固三相饱和态下pVT的计算

本文基于分子聚集理论和硬球引力场模型应用分子热力学方法导出CS-vdW状态方程,应用上述方程计算了CO2气-液和气-固平衡相的饱和态下pVT性质.取得了很满意的结果.本方法的优点是使用简便,可供工程计算使用.     

CO_2跨临界制冷循环中应用两相螺杆膨胀机的理论分析

本文在介绍利用环保、安全的ＣＯ２作为制冷剂的跨临界循环的基础上,分析了系统各部件的■损失情况,并通过与常规工质对比,提出了采用汽液两相螺杆膨胀机取代系统中节流阀的方法。该方法可明显提高系统的ＣＯＰ,具有广阔的实际应用前景。文章结合ＣＯ２超临界流体的实际特点,对研制、开发ＣＯ２两相螺杆膨胀机提出了设计思想和建议。     

CO2与缩水甘油醚类单体共聚物的合成及表征

共聚反应;热性能;CO2与缩水甘油醚类单体共聚物的合成及表征     

Coverage performance analysis of multi-camera networks based on observing reliability model

Coverage control is a fundamental problem in sensor networks, which has been explored thoroughly based on a traditional scalar sensing model. However, camera sensors are different from traditional scalar sensors as different cameras from different positions can form distinct views of the target. Hence, Target size and geometric structure of camera nodes can greatly influence the surveillance ability of a camera network. In view of this, a novel observation reliability model of a camera network is proposed, and relationship between surveillance ability and observing reliability for the target is studied. On the basis, a camera network coverage model which considers about obstacles and interesting area of the environment is investigated, and optimized by dynamic planning method. Simulation results show that our method can effectively improve the target capture rate of the network and also we can observe the target from a better view.     

碳纳米管负载Cu-Co复合氧化物的富氢气氛中CO催化消除

采用超声处理辅助浸渍法制备了多壁碳纳米管负载的Cu-Co复合氧化物催化剂. 利用XRD、TEM、H₂-TPR、XPS和Raman光谱等表征了催化剂的结构性质. 在Cu和Co氧化物以及金属氧化物与碳纳米管载体间存在强相互作用. 催化剂在富氢气氛中CO催化消除反应中,与单一Cu或Co催化剂相比,Cu-Co复合氧化物催化剂表现出独特的反应特性,特别是在较高反应温度下可同时结合CO优先氧化和CO甲烷化的反应途径来实现高效CO消除. 当Cu/Co比为1/8时活性最优,可以实现在150～250 o和高反应空速 (120 L/(h·g))富氢气氛中CO的完全消除.     

Enhancing the efficiency of TiO2–perovskite heterojunction solar cell via evaporating Cs2CO3 on TiO2

In a TiO₂–perovskite heterojunction solar cell (TiO₂–PHSC), besides the perovskite CH₃NH₃PbX₃, TiO₂ as one side of the TiO₂/CH₃NH₃PbX₃ heterojunction also plays an important role in the photovoltaic effect. In order to improve the performance of the TiO₂–PHSC with the structure of glass/FTO/compact TiO₂/mesoporous TiO₂/CH₃NH₃PbI_3–xCl_x /poly‐TPD (poly(N,N ′‐bis(4‐butylphenyl)‐N,N ′‐bis(phenyl)benzidine))/Au, a 2 nanometer thick Cs₂CO₃ layer is thermally evaporated on the mesoporous TiO₂ layer. The short‐circuit current density (J_sc) raises from 17.7 mA cm^–2 to 18.9 mA cm^–2, the open‐circuit voltage (V_oc) from 0.81 V to 0.87 V, and the fill factor (FF) from 55.2% to 67.3%; as a result, the power conservation efficiency (PCE) increases from 8.0% to 11.1% under AM 1.5G solar illumination (100 mW cm^–2). Moreover, in a TiO₂–PHSC free of mesoporous TiO₂, where Cs₂CO₃ is evaporated on the compact TiO₂ layer, the J_sc, V_oc, FF and PCE values increase from 16.0 mA cm^–2, 0.83 V, 50.8% and 6.7% to 17.9 mA cm^–2, 0.90 V, 59.3%, and 9.5%, respectively. The reasons of the PCE increase for either the first kind of TiO₂–PHSC or the mesoporous‐TiO₂‐free TiO₂–PHSC with a nanometer‐thick Cs₂CO₃ layer on mesoporous TiO₂ or compact TiO₂ are discussed. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

Controlling arrangement of multi‐layer microcellular materials by using supercritical fluids

A series of semicrystalline microcellular materials were prepared by the foaming technology using supercritical fluids. The distribution of multi‐size microcellulars and multi‐layer arrangement was observed by scanning electronic microscopy. By controlling the foaming condition accurately, the alternated arrangement of variable in cellular size may be tuned. One key point was discussed here to understand the phenomenon: the prior sequencing of the crystal nucleation and cellular nucleation. As the supporting experiments, the gravimetric desorption data of CO₂ were kinetically and thermodynamically evaluated by three diffusion equations. The concepts of local crystal nucleation and local cellular nucleation were introduced first, and the mechanism of multi‐layer arrangement was proved. Copyright © 2012 John Wiley & Sons, Ltd.     

Ceria nanospindles: Template-free solvothermal synthesis and shape-dependent catalytic activity

The ceria nanospindles have been successfully synthesized via a simple template-free solvothermal treatment by employing a mixture of glycerin and water as the reaction solvent. The properties of the ceria nanospindles were characterized. A series of control experiments confirms that the reaction solvents, reaction temperature and time are the crucial factors determining the formation of ceria nanospindles, and by adjusting the experimental parameters the other ceria micro/nanostructures such as columns, spheres, and rods were obtained. The platinum coated ceria nanospindles show the excellent low-temperature catalytic activity in the oxidation of carbon monoxide as compared with other micro/nanostructures, which is mainly due to their special shape and uniformly-distributed active sites.     

Templated Synthesis of Nitrogen‐Enriched Nanoporous Carbon Materials from Porogenic Organic Precursors Prepared by ATRP

A facile templated synthesis of functional nanocarbon materials with well‐defined spherical mesopores is developed using all‐organic porogenic precursors comprised of hairy nanoparticles with nitrogen‐rich polyacrylonitrile shells grafted from sacrificial cross‐linked poly(methyl methacrylate) cores (xPMMA‐g‐PAN). Such shape‐persistent all‐organic nanostructured precursors, prepared using atom transfer radical polymerization (ATRP), assure robust formation of template nanostructures with continuous PAN precursor matrix over wide range of compositions, and allow for removal of the sacrificial template through simple thermal decomposition. Carbon materials prepared using this method combine nitrogen enrichment with hierarchical nanostructure comprised of microporous carbon matrix interspersed with mesopores originating from sacrificial xPMMA cores, and thus perform well as CO₂ adsorbents and as supercapacitor electrodes.