Speciation of functional groups formed on the surface of ammoxidised carbonaceous materials by XPS method

X-ray photoelectron spectroscopy (XPS) has been used to investigate the fate of nitrogen functional groups present in carbonaceous materials obtained from European plum (Prunus domestica) stones and modified by ammonia-air mixture at 250 or 300 °C. Peaks have been found in the XPS patterns, corresponding to different nitrogen functional forms i.e. pyrrolic, pyridinic, pyridone, amine and chemisorbed nitrogen oxides. It has been found that the distribution of nitrogen functional forms changes as a result of the modification processes.     

基于车载通信标准街道场景的电磁散射信道模型

针对室外无线信道视距(line of sight,LOS)/非视距(non-line of sight,NLOS)传输环境下的车到车(vehicular-to-vehicular,V2V)通信系统,本文提出了一种基于标准街道散射的统计信道模型,其移动发射机(mobile transmitter,MT)与移动接收机(mobile receiver,MR)处于运动状态,街道两旁分布的散射体固定.由几何模型出发又引入了一种随机的参考信道模型,其散射体有无穷多个,均以平行于街道两侧的散射条纹形式均匀分布在三维(three dimensional,3D)空间的一个二维(two dimensional,2D)矩形内部.在室外街道通信环境下,模型推导了散射信道中发射角(angle of departure,AOD)以及到达角(angle of arrival,AOA)的概率密度函数(probability density functions,PDFs)解析式;研究了多普勒功率谱密度(power spectral density,PSD)及其时间自相关函数(autocorrelation function,ACF);分析了模型多普勒参数以及街道散射体等因素对V2V通信系统性能的影响.与城市、农村的测量信道对比分析,表明本模型仿真的统计特性符合理论与实际,拓宽了室外V2V无线通信信道建模的研究.为评估室外V2V通信系统的传输特性、仿真无线通信系统提供了有力的研究工具.     

光子晶体Vlasov天线辐射特性研究

 通过在Vlasov天线口径上加装金属面,再在金属面上环绕天线口径排布金属圆柱构成光子晶体,设计出一种新型的光子晶体Vlasov天线。数值仿真及实验结果均表明,光子晶体的带隙特性改善了天线的辐射特性,使得E面上的最大增益在工作频段内平均提高了2.43 dB。     

Structure comparison between Th2Zn17-type and TbCu7-type Sm–Fe intermetallic compounds and their nitrides by means of 57Fe-Mössbauer spectroscopy

Samarium–iron intermetallic compounds were prepared by a melt spinning method with low and high wheel speeds, which resulted in a Th₂Zn₁₇-type and a TbCu₇-type structure, respectively. Structure comparison between these types was investigated for Sm–Fe intermetallic compounds and their nitrides by ⁵⁷Fe-Mössbauer spectroscopy.     

含有周期球腔的黏弹性覆盖层消声性能分析

利用散射矩阵法分析了单个球状空腔在黏弹性橡胶中的Mie散射特性以及振动模式.以此为基础，利用多重散射法分析了不同背衬条件下，含有单层周期球状空腔的橡胶覆盖层(厚度为8mm)的消声性能.结果表明，单个球腔的径向共振对覆盖层的低频消声性能有重要贡献，覆盖薄层在共振区具有良好的消声性能.最后，设计了双层消声覆盖层(厚度为20mm)，有效拓展了消声带宽. 关键词： Mie散射 多重散射法 消声材料 声子晶体     

Defects inspection of the solder bumps using self reference technology in active thermography

With the decrease of solder bumps in dimension and pitch, defects inspection of the solder bumps become more difficult. A nondestructive detection system based on the active thermography has been developed for solder bumps inspection. However, heating non-uniformities and emissivity differences may impede the defects recognition. In this paper, we propose a method using a self reference technology based on a source distribution image (SDI) to eliminate the influence of unevenness in emissivity values and heating power distribution. Three thermograms captured right after the heat pulse are averaged to create the SDI. Then the SDI is subtracted from the original thermograms, and we get the thermal contrast images, in which eight points on the edge of each hot spot are selected as the feature points for the corresponding bump. Thermal difference between the feature points and the central point are adopted to quantify the thermal behaviors of the solder bumps, by which the missing bump is distinguished from the reference bumps. The results show that it is effective using the method to eliminate the impacts of emissivity unevenness and heating non-uniformities on defects identification in the active infrared test.     

裂缝性应力敏感油藏流固耦合的数值模拟

以裂缝各向异性全张量渗透率动态耦合渗流模型为基础,建立三维三相裂缝各向异性特低渗透油藏流固耦合数学模型,并运用模块化显示耦合迭代求解建立流固耦合渗流数值模拟方法,编制耦合求解程序.研究表明:对于裂缝性油藏,随着油藏开采过程中压力的变化,岩石变形和储层介质的各向异性应变特性使开发过程中多组裂缝的变形程度不同,引起裂缝渗透率的非线性变化,进而使油藏裂缝渗透率张量主值发生旋转,改变液流方向、影响油藏开发效果.     

Magnetic and electronic properties of NiAs-type chromium chalcogenides

We have computed spin-dependent energy bands, spin moments and density of states of NiAs-type CrX (X=S, Se and Te) chalcogenides using linear combination of atomic orbitals method within density functional theory as well as full potential augmented plane wave method. In addition, magnetic properties have also been computed using spin polarized relativistic Korringa-Kohn-Rostoker method. We have also obtained the first ever theoretical electron momentum densities of CrX compounds considering linear combination of atomic orbitals and compared the results with the isotropic Compton profiles measured using 20 Ci ¹³⁷Cs Compton spectrometer. The Fermi surface topology and magnetic properties are discussed in terms of majority and minority energy bands and density of states. In addition, to highlight the role of Cr (3d) electrons in such type of chalcogenides, we have also reported the magnetic Compton profile of CrTe using the Korringa-Kohn-Rostoker method.     

Probing mechanical properties of thin film and ceramic materials in micro- and nano-scale using indentation techniques

In this study, we report on the mechanical properties, failure and fracture modes in two cases of engineering materials; that is transparent silicon oxide thin films onto poly(ethylene terephthalate) (PET) membranes and glass-ceramic materials. The first system was studied by the quazi-static indentation technique at the nano-scale and the second by the static indentation technique at the micro-scale. Nanocomposite laminates of silicon oxide thin films onto PET were found to sustain higher scratch induced stresses and were effective as protective coating material for PET membranes. Glass-ceramic materials with separated crystallites of different morphologies sustained a mixed crack propagation pattern in brittle fracture mode.     

热压制备(AgSbTe2)100-x-(GeTe)x合金的热电性能

以Pb粉、Te粉、Ag粉、Ge粉为原材料,在真空气氛下合成(AgSbTe₂)_100-x-(GeTe)_x (x=80---90) (TAGS)合金热电材料, X射线衍射(XRD)分析表明,热压烧结后合金具有低温菱形结构. 通过热压烧结法将TAGS粉末制备成块体材料,运用XRD和扫描电子显微镜对材料的物相成分、 晶体结构和形貌进行了表征.采用直流四探针法测定样品的电导率,当样品两端的温差为1---4℃ 的情况下测量Seebeck系数.通过材料热电性能测试,研究了30---500℃温度范围内不同组分 样品性能参数的变化.结果表明,所制备的TAGS热电材料具有纳米结构, 其性能随着组分的变化而变化, TAGS-80具有较好的热电性能,在530℃时具有最高热电优值(ZT=1.80).