Excess molar heat capacity of isobutyric acid–water binary liquid mixtures near and far away from the critical temperature

The heat capacity of the liquid–liquid mixture isobutyric acid–water has been measured for the first time near and far away from its critical point using an adiabatic calorimeter. The measurements were performed at atmospheric pressure, in the one phase region as a function of three temperatures: (1) T − T_C = 0.055 °C, (2) T − T_C = 3.055 °C, (3) T − T_C = 8.055 °C and of the composition X in acid (IA). The heat capacity C_p decreases rapidly when X increases at the used temperatures. Near the critical composition, C_p is not affected by the correlation of the concentration fluctuations.

The molar excess heat capacity of the system under investigation was analysed along the phase diagram and considered as a structural transformation effect.     

The dual bases for the Bézier-Said-Wang type generalized Ball polynomial bases and their applications

A unifying representation for the existing generalized Ball bases and the Bernstein bases are given. Then the dual bases for the Bézier-Said-Wang type generalized bases (BSWGB for short) are presented. The Marsden identity and the mutual transformation formulas between Bézier curve and Bézier-Said-Wang type generalized curve (BSWGB curve) are also given. These results are very useful for the applications of BSWGB curves and their popularization in CAGD. Numerical examples are also given to show the effectiveness of our methods.     

Relation of structure to performance characteristics of monolithic and perfusive stationary phases

Commercially available polymer-based monolithic and perfusive stationary phases were evaluated for their applicability in chromatography of biologics. Information on bed geometry, including that from electron microscopy (EM), was used to interpret and predict accessible volumes, binding capacities, and pressure drops. For preparative purification of biologics up to at least 7 nm in diameter, monoliths and perfusive resins are inferior to conventional stationary phases due to their low binding capacities (20–30 g/L for BSA). For larger biologics, up to several hundred nanometers in diameter, calculations from EM images predict a potential increase in binding capacity to nearly 100 g/L. The accessible volume for adenovirus calculated from the EM images matched the experimental value. While the pores of perfusive resins are essentially inaccessible to adenovirus under binding conditions, under non-adsorbing conditions the accessible intrabead porosity is almost as large as the interbead porosity. Modeling of breakthrough curves showed that the experimentally observed slow approach to full saturation can be explained by the distribution of pore sizes.     

Visco-penalization of the sum of two monotone operators

A new type of approximating curve for finding a particular zero of the sum of two maximal monotone operators in a Hilbert space is investigated. This curve consists of the zeros of perturbed problems in which one operator is replaced with its Yosida approximation and a viscosity term is added. As the perturbation vanishes, the curve is shown to converge to the zero of the sum that solves a particular strictly monotone variational inequality. As an off-spring of this result, we obtain an approximating curve for finding a particular zero of the sum of several maximal monotone operators. Applications to convex optimization are discussed.     

On S-Shaped Bifurcation Curves for a Class of Perturbed Semilinear Equations

By making use of bifurcation analysis and continuation method, the authors discuss the exact number of positive solutions for a class of perturbed equations. The nonlinearities concerned are the so-called convex-concave functions and their behaviors may be asymptotic sublinear or asymptotic linear. Moreover, precise global bifurcation diagrams are obtained.     

Supersimplicity and quadratic extensions

An elliptic curve over a supersimple field with exactly one extension of degree 2 has an s-generic point. A. Martin-Pizarro would like to express his gratitude to the organisation of the Florida Logic year, in which he took part. Martin-Pizarro research was supported by a DFG-Forschungsstipendium MA3310/1-1. F. O. Wagner is a Membre junior de l’Institut Universitaire de France. Work done during the semester on Model Theory and Applications in Algebra and Analysis at the Isaac Newton Institute for the Mathematical Sciences, whose hospitality is gratefully acknowledged.     

Some inverse problems in rheology leading to integral equations

Two inverse problems of the integral type, which are of the general importance to rheology, are discussed. The first of them is the possibility of calculating the molecular weight distribution (MWD) from the flow curve and the second one is the interrelation between creep and relaxation functions. It was shown that the first problem is incorrect and any solution is unstable in respect to minor experimental errors. It means that the general solution of this problem is impossible in principle and only estimations of the width of unimodal MWD can be received from the curvature of the flow curve. The possibility of the correct calculation of the creep function exists in case the relaxation curve being approximated by the sum of exponential members. But the approximation of the relaxation curve within the experimental accuracy is the necessary, but not sufficient condition for the correct solution of this integral inverse problem, because not every mode of approximation leads to the satisfactory prediction of creep function.Delivered as the Courtaulds Lecture at the Golden Jubilee Conference of the British Society of Rheology and Third European Rheology Conference, Edinburgh, 3–7 September, 1990.     

Modeling structural recovery in glasses: An analysis of the peak‐shift method

Amorphous polymers below their glass‐transition temperature are inherently not at equilibrium. As a result, their structures continuously relax in an attempt to reach the equilibrium state. The current models of structural recovery can quantitatively describe the process. One of the parameters needed for the models is the nonlinearity parameter x. It has been proposed that x can be obtained from experimental data with the so‐called peak‐shift method. In this work, we use the Tool–Narayanaswamy–Moynihan model to identify the factors that determine the accuracy of the peak‐shift method and to quantify the errors in the value of x obtained from the peak‐shift method. In addition, we determine the influence of the error in x on the evaluation of the nonexponential model parameter β. Finally, the peak‐shift method is compared with the traditional curve‐fitting method for model parameter determination. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2027–2036, 2002     

单功能基叔胺型弱碱树脂的合成及其滴定曲线研究

合成了以苯乙烯－二乙烯苯为骨架的若干叔胺型弱碱性树脂，研究了胺化反应条件，胺化试剂及交联度等对叔胺产碱树脂功能单一性的影响，测定了强碱交换量低的叔胺树脂的滴定曲线特征，找到了适合作为热再生树脂弱碱组分的单功能基叔胺树脂的合成条件。     

A finite strain contact model for mixed lubricated surfaces in forming processes

For an accurate simulation of forming processes, it is of paramount importance to model the different lubrication regimes that can develop at the contact interface. These might vary from zone to zone of the forming piece, and from one regime to another, resulting in forces of different nature and magnitude. In these cases, the use of the classical Coulomb friction law will be clearly not sufficient to capture, in a suitable manner, the variety of forces applied on the forming piece.