傅里叶红外光谱法研究GAP/AP混合体系的快速热裂解

用T-Jump/FTIR在线联用分析技术,研究了GAP/AP混合体系在模拟燃烧条件下快速加热高温高压的热裂解。结果表明,GAP/AP混合体系的主要热裂解气相产物的组成发生了变化,说明组分之间存在相互作用。压力对GAP/AP混合体系气相产物有明显的影响,表明混合体系组分GAP和AP之间的相互作用是通过AP分解气相产物进行的,混合体系不但存在气相之间的反应,也存在气相/凝聚相反应。而温度并没有影响AP对GAP的作用。用T-Jump/FTIR在线分析技术能够实现模拟燃烧条件下含能材料实时气体产物分析,为从微观反应的角度探索含能材料的快速高压热裂解及其组分之间的相互作用提供一条技术途径。     

舰载光电指向器多轴系耦合精度分析

光电指向器的轴系精度直接影响到光电系统的整体性能指标。分析了光电指向器轴系之间精度影响关系,根据对方位轴系、俯仰轴系和视轴轴系的各项误差源分析计算出各轴系误差值,结合在安装过程中方位轴系误差与俯仰轴系误差建立数学模型,寻找方位角和俯仰角与方位轴系、俯仰轴系、视轴轴系的误差之间的耦合关系,并将三个轴系误差进行耦合后建立数学模型分析。该分析方法和结果为光电指向器的多轴系结构耦合误差设计提供了理论及工程依据。     

共孔径偏振耦合分光系统中反射镜造成的相位延迟差的测量

 激光信标共孔径发射接收偏振分光系统的动态相位补偿需要测量望远镜各反射镜对s光和p光的相位延迟差。利用Stokes矢量和Mueller矩阵建立了物理模型,并推导出用测得的回光功率计算相位延迟差的解析式。提出一种通过实验测量回光功率计算反射镜相位延迟差的方法,解决了在0～2p范围内唯一确定反射镜相位延迟差的问题。实际测量了两块反射镜的相位延迟差,并将测量结果用于动态相位补偿偏振分光实验,验证了该方法的正确性。分析了偏振分光棱镜、法拉第旋光器以及近似计算这3个主要的测量误差源,并估计总测量误差约为1°。     

Optical characterization of thin thermal oxide films on copper by ellipsometry

A complete optical characterization in the visible region of thin copper oxide films has been performed by ellipsometry. Copper oxide films of various thicknesses were grown on thick copper films by low temperature thermal oxidation at 125 °C in air for different time intervals. The thickness and optical constants of the copper oxide films were determined in the visible region by ellipsometric measurements. It was found that a linear time law is valid for the oxide growth in air at 125 °C. The spectral behaviour of the optical constants and the value of the band gap in the oxide films determined by ellipsometry in this study are in agreement with the behaviour of those of Cu₂O, which have been obtained elsewhere through reflectance and transmittance methods. The band gap of copper oxide, determined from the spectral behaviour of the absorption coefficient was about 2 eV, which is the generally accepted value for Cu₂O. It was therefore concluded that the oxide composition of the surface film grown on copper is in the form of Cu₂O (cuprous oxide). It was also shown that the reflectance spectra of the copper oxide–copper structures exhibit behaviour expected from a single layer antireflection coating of Cu₂O on Cu. Received: 19 July 2001 / Accepted: 27 July 2001 / Published online: 17 October 2001     

Finite-Size Effects for the Potts Model with Weak Boundary Conditions

Using the Pirogov–Sinai theory, we study finite-size effects for the ferromagnetic q-state Potts model in a cube with boundary conditions that interpolate between free and constant boundary conditions. If the surface coupling is about half of the bulk coupling and q is sufficiently large, we show that only small perturbations of the ordered and disordered ground states are dominant contributions to the partition function in a finite but large volume. This allows a rigorous control of the finite-size effects for these weak boundary conditions. In particular, we give explicit formulæ for the rounding of the infinite-volume jumps of the internal energy and magnetization, as well as the position of the maximum of the finite-volume specific heat. While the width of the rounding window is of order L ^–d , the same as for periodic boundary conditions, the shift is much larger, of order L ^–1. For strong boundary conditions—the surface coupling is either close to zero or close to the bulk coupling—the finite size effects at the transition point are shown to be dominated by either the disordered or the ordered phase, respectively. In particular, it means that sufficiently small boundary fields lead to the disordered, and not to the ordered Gibbs state. This gives an explicit proof of A. van Enter's result that the phase transition in the Potts model is not robust.     

Degradation of the Giant Magnetoresistance in Fe/Cr Multilayers Due to Ar-Ion Beam Mixing

The influence of 200 keV Ar-ion irradiation on the interlayer coupling in the Fe/Cr multilayer system exhibiting the giant magnetoresistance effect (GMR) is studied by conversion electron Mössbauer spectroscopy (CEMS), VSM hysteresis loops, magnetoresistivity and electric resistivity measurements and supplemented by the small-angle X-ray diffraction (SAXRD). The increase of Ar ion dose causes an increase of interface roughness, as evidenced by the increase of the Fe step-sites detected by CEMS as a result of which the GMR gradually decreases and vanishes at doses exceeding 1×10¹⁴ Ar/cm². A degradation of GMR with increasing Ar-ion dose is related to the formation of pinholes between Fe layers and the decrease of the antiferromagnetically coupled fraction.

     

Fe–Mn–Al–C Alloys: a Study of Their Corrosion Behaviour in SO2 Environments

The corrosion reaction of four Fe–Mn–Al alloys exposed to a cycling, dry–humid, SO₂ (0.001% by volume) polluted atmosphere was studied. ICEMS, XPS, AES-SAM and transmission Mössbauer spectroscopy at different temperatures were employed to characterize the corrosion products. The analytical results indicate that (i) ferrihydrite is the main component of the rust; (ii) there is an abundant presence of Mn²⁺ and SO₃ ^2–/SO₄ ^2– on the top of the corrosion layer, the concentration of SO₄ ^2– increasing with the number of cycles; and (iii) the magnetic hyperfine pattern exhibited by the series of low-temperature spectra of the rust is quite different from that observed in the rust formed under similar corrosive environments on iron and weathering steel. This latter finding is correlated with a slow rate of transformation of the Fe³⁺ species formed at the early stages of corrosion into -FeOOH, the usual final product of this type of corrosion processes. The sulphate anions, abundant inside the electrolyte during the wet periods, could be incorporated to the ferrihydrite structure being responsible for the Mössbauer spectral pattern recorded from the corrosion products at low temperatures.     

Adhesion measurement of thin films by a modified laser spallation technique: theoretical analysis and experimental investigation

Laser driven shocks can lead to a dynamic failure, called film spallation. Here, we use a modified laser spallation set-up to measure the dynamic adhesion of thin films and we propose a novel diagnostic technology. Based on correlation theory, new spallation criteria for characterizing the progressive damage at the interface between the film and the substrate are established, such as interface delamination, film spallation and film expulsion. With the help of the theory, the degree of damage and the dimension of damage (i.e. fracture), such as the minimum width of delamination radius, the thickness of the film etc., are estimated. Experiments are carried out on epoxy/stainless steel and epoxy/Al, and the experimental results show that their dynamic bonding strengths are about 25 MPa and 20 MPa, respectively. The detailed results, analyses and discussions are presented in this paper. Received: 6 February 2001 / Accepted: 3 December 2001 / Published online: 11 February 2002     

钛扩散铌酸锂矩形波导中的双折射耦合对传播常数的影响

 从亥姆霍兹方程出发，得到了各向异性光波导在弱导近似下的耦合模理论。耦合系数包括偏振耦合项和双折射耦合项。并用马卡提里近似下的模式作为零级近似。用一级微扰法计算了折射率渐变分布的钛扩散铌酸锂矩形波导的传播常数。在给定参数的情况下，得到双折射项引起的传播常数的改变约为主微扰项的3%，因此双折射耦合对钛扩散铌酸锂矩形波导的性能影响不可忽略，这对设计和分析与它相关的光波导器件具有指导意义。     

条件愈苦,意志愈坚 --记王淦昌早年的科研活动

文章介绍了中国物理学家王淦昌早期的科研工作，特别是在抗日战争时期的科研成绩．王淦昌早期的科研贡献并不是在先进的实验仪器上，在条件优裕的实验室内完成的，而是在实验设备缺乏，科学文献不足等极端困难的环境中完成的．从王淦昌身上，可以看到那个时代中国优秀科学家脚踏实地、执志若金的奋斗精神．