Modified Fourier-transform method for phase-shift calibration

A fast convergent algorithm to accurately measure phase-shift for phase shifter is proposed. In the presence of a spatial carrier frequency, an error function in the Fourier-domain is introduced and then the unknown phase-shift between two phase-shifted fringe patterns is determined by minimization of the error function with the help of a golden section search approach. Compared with the conventional Fourier-transform method, the modified method proposed in the paper is more immune to random noise and hence can give a more accurate result. The translation curve of a liquid-crystal spatial light modulator is also experimentally calibrated.     

生物活动对海床沉积物工程地质特征改造研究

底栖穴居动物是河口潮滩生态系统的重要组成部分,它对沉积物的二次改造作用非常重要。本文以黄河三角洲钓 口区潮滩为研究对象,研究了不同生物密度对沉积物工程地质特征的改造,包括滩面形态、沉积物强度、以及沉积物颗粒大小 的改变。在此基础上探讨了生物活动与滩面凹坑,沉积物强度非均匀性以及研究区浮泥之间的关系。     

Notes on the Rescaled Sasaki Type Metric on the Cotangent Bundle

Let (M,g) be an n-dimensional Riemannian manifold and T^*M be its cotangent bundle equipped with the rescaled Sasaki type metric. In this paper, we firstly study the paraholomorphy property of the rescaled Sasaki type metric by using some compatible paracomplex structures on T^*M. Second, we construct locally decomposable Golden Riemannian structures on T^*M. Finally we investigate curvature properties of T^*M.     

颜色不稳定黄色蓝宝石的谱学特征与颜色成因

颜色不稳定黄色蓝宝石广泛存在市场中,如何有效鉴别颜色不稳定黄色蓝宝石的特征是当前宝石学研究的热点。利用改色实验、紫外-可见光谱（UV-Vis）、三维荧光光谱对颜色不稳定黄色蓝宝石进行深入的谱学特征研究。改色实验表明斯里兰卡黄色蓝宝石中部分存在光致变色的现象,短波紫外光会导致样品着色,而太阳光会导致样品褪色。紫外光照后黄色蓝宝石的颜色由稳定部分和不稳定部分共同组成。颜色不稳定蓝宝石的“着色态”和“褪色态”紫外-可见光谱可见明显的蓝紫区吸收,这可能与蓝宝石中O2--Fe3+的电荷转移有关,导致了蓝宝石稳定的黄色调。蓝宝石的紫外-可见光谱在“着色态”相比“褪色态”可见明显的蓝紫区吸收增强,可能由于紫外光照射增强了O2--Fe3+之间的电荷转移。紫外-可见光谱测试表明样品中具有弱的与Fe有关的吸收峰,这与样品含有较低的Fe含量一致,不足以产生稳定黄色调。三维荧光光谱分析结果表明颜色不稳定黄色蓝宝石的“着色态”和“褪色态”具有一致的激发光波长Ex=325～335 nm、发射光波长Em=560～570 nm的特征荧光中心,在“着色态”时的荧光强度明显高于“褪色态”。含铁黄色蓝宝石具有荧光效应且特征的荧光中心可作为识别这种颜色不稳定黄色蓝宝石的潜在鉴定手段。综合报道了颜色不稳定黄色蓝宝石的谱学特征与可能的颜色成因,为识别颜色不稳定的蓝宝石提供了鉴定依据,同时为后续改色处理的工艺提供了理论基础。     

基于QA Score的GDPS各个版本在黄海海域GOCI数据处理中的适应性分析

水体的遥感反射比光谱（R_rs(λ)）是海洋水色遥感反演海洋生物地球光学参数的关键,其定义是离水辐亮度与恰好水面之上的向下辐照度之比。海洋水色卫星传感器接收到的总信号中90%是大气的贡献,海洋水体贡献的离水辐亮度不足10%,因此对接收的信号进行大气校正获得高精度的水体遥感反射比信号是海洋光学遥感的关键技术之一。基于大量高质量的现场高光谱遥感反射比数据的基础上建立的R_rs(λ)光谱数据的质量评价体系QA(quality assurance),可以通过计算R_rs的得分情况（QA score）很好地识别出有问题或可能错误的R_rs(λ)光谱。GOCI(geostationary ocean color imager)是搭载在全球第一颗对地静止卫星COMS(communication ocean and meteorological satellite)上的主要传感器,由韩国海洋卫星中心（KOSC）发射,其高观测频次(8景观测数据/天)使生物地球化学参数的日变化监测成为可能。KOSC研发了GDPS (GOCI data processing system)软件专门用于GOCI数据处理,包括大气校正。到目前为止已为全球用户免费提供GDPS1.1, GDPS1.2, GDPS1.3, GDPS1.4, GDPS1.4.1, GDPS2.0六个版本。应用QA Score评价体系对于GDPS1.2, GDPS1.3, GDPS1.4.1, GDPS2.0四个版本在黄海海域处理得到的GOCI遥感反射比光谱数据的质量进行了评比。结果发现GDPS1.2的R_rs数据被视为无效的数据量明显大于GDPS1.3, GDPS1.4.1和GDPS2.0的处理结果;GDPS2.0的R_rs数据QA得分情况要差于GDPS1.2,GDPS1.3和GDPS1.4.1;GDPS1.3和GDPS1.4.1的数据处理结果基本相同,这与GDPS1.4在GDPS1.3的基础上只进行了软件模块化优化处理且修复了一些小问题的结果相吻合。基于该研究,黄海海域使用GOCI R_rs数据时,如果R_rs波段比是首要考虑因素（如反演叶绿素a浓度）且对有效数据数量要求不高,可以使用GDPS1.2版本进行大气校正;如果更关心的是某个波段R_rs值,则使用GDPS2.0进行大气校正更合适。     

Uranium recovery from Uro area phosphate ore,Nuba Mountains,Sudan

This study was carried out in a laboratory scale to recover uranium from Uro area phosphate ore in the eastern part of Nuba Mountains in Sudan. Phosphate ore samples were collected, and analyzed for uranium abundance. The results showed that the samples contain a significant concentration of uranium with an average of 310.3 μg/g, which is 2.6 times higher than the world average of phosphate. The green phosphoric acid obtained from the samples was found to contain uranium in the range of 186–2049 μg/g, with an average of 603.3 μg/g, and about 98% of uranium content of the phosphate ore was rendered soluble in the phosphoric acid. An extraction process using 25% tributylphosphate, followed by stripping process using 0.5 M sodium carbonate reported that more than 98% of uranium in the green phosphoric acid exists as uranyl tricarbonate complex, moreover, sodic decomposition using 50% sodium hydroxide showed that about 98% of the uranium was precipitated as sodium diuranate concentrate that is known as the yellow cake (Na₂U₂O₇). Further purification and calcinations of the yellow cake led to the formation of the orange powder of uranium trioxide (UO₃). The chemical analysis of the obtained uranium concentrates; yellow cake and uranium trioxide proved their nuclear purity and that they meet the standard commercial specification. The obtained results proved that uranium from Uro phosphate ore was successfully recovered as uranium trioxide with an overall recovery percentage of 93%.     

用改进的重叠分辨率优化法于薄层色谱分离二茂铪化合物

在薄层色谱中分离一系列二茂铪化合物，首先利用黄金分割优选法优化二元展开剂体系，然后按优化结果把二元展开剂混合成四元溶剂体系，共用重叠分辨率法确定四元展开剂体系的最佳组成，分离结果令人满意，同时，本文还对等溶剂强度条件和不等溶剂强度条件下的优化结果做了比较和讨论。     

LD泵浦Nd:YVO4/LBO腔内和频连续黄光激光器

用国产半导体激光二极管泵浦Nd:YVO4晶体,通过优化膜系,调节1064 nm谱线的线性损耗以达到与弱谱线1342 nm 增益匹配,在室温下实现1064 nm和1342 nm双波长连续运转,并通过Ⅰ类临界相位匹配LBO晶体腔内和频在国内首次实现593.5 nm黄色激光连续输出,当泵浦注入功率为1.8 W时和频黄激光最大输出达85 mW,光光转换效率为4.7%,功率稳定性24 h内优于±2.8%.     

QuEChERS-高效液相色谱-串联质谱法测定酵母抽提物中9种黄色合成色素

本文建立了酵母抽提物中9种黄色合成色素的高效液相色谱-串联质谱(HPLC-MS/MS)分析方法。样品用乙腈-甲醇(5∶5,V/V)提取,经聚苯乙烯/二乙烯苯(PEP)和C18粉净化,以Zorbax Eclipse Plus C18柱(100×3.0mm,1.8μm)分离,流动相为乙腈-10mmol/L NH4Ac,梯度洗脱。采用电喷雾负离子源(ESI-)、多重反应监测(MRM)模式检测,基质匹配外标法定量。结果表明,9种黄色合成色素在各自线性范围内相关系数(r2)均大于0.994;检出限(S/N3)为0.01~0.30mg/kg,定量限(S/N10)为0.02~3.0mg/kg,3个加标水平(1、2、10倍定量限)下,回收率为75.5%~115.1%,相对标准偏差(RSD)为4.7%~17.6%。该方法适用于酵母抽提物中9种黄色合成色素的同时测定。     

Determination of hydroxysafflor yellow A in rat plasma and tissues by high-performance liquid chromatography after oral administration of safflower extract or safflor yellow

A simple and reproducible HPLC method for quantification of hydroxysafflor yellow A (HSYA) in rat plasma and tissues after oral administration of safflower extract or safflor yellow (SY) was developed. Sample preparation was achieved by protein precipitation of plasma and tissue homogenates with three volumes of methanol. p-Hydroxybenzaldehyde was used as the internal standard (IS). HSYA and IS were separated on a Hypersil BDS-C(18) column with a gradient elution system composed of acetonitrile and aqueous acetic acid. UV detection was used at 320 nm. The calibration curves were linear in all matrices (r(2) > 0.999) in the concentration ranges 0.51-101.36 microg/mL for plasma, 12.27-2454.46 microg/g for intestines and 0.96-192.20 microg/g for lung. The intra-day and inter-day precision were all less than 12.5%, and the extract recovery was in the range 64.1-103.7% with RSD less than 15.6% for HSYA in all matrices. The method was used successfully to quantify HSYA in rat plasma and tissue samples to support a pharmacokinectic study.