浅谈5/2量子霍尔态：偶数分母与拓扑量子计算

已发现的绝大部分分数量子霍尔态以奇数为分母,5/2态是一个例外。在5/2态可能的波函数中,有一些携带非阿贝尔统计,可以用于拓扑量子计算。文章将简单介绍分数量子霍尔效应、5/2态、非阿贝尔统计以及相关最新的科研进展。     

Cu2O/C60梯度薄膜的制备

功能梯度材料应用前景广阔,特别在ICF研究中,梯度靶是一种重要的基础-基准靶。以Cu2O和C60为原料,用真空蒸镀法在石英基底上制备了Cu2O/C60梯度薄膜,并用XPS, AFM, 紫外光谱仪对其成份分布、表面形貌、紫外吸收谱进行了测试。测量结果表明,薄膜的组成沿厚度方向呈连续梯度变化,符合梯度功能材料的变化规律。     

热处理条件对PVA薄膜阻氢性能的影响

采用XRD测定了PVA薄膜在不同热处理条件下的结晶度,并用自行设计的渗氢系数测量系统研究了在不同热处理条件下的PVA薄膜阻氢性能的变化规律。结果表明,PVA薄膜的热处理温度越高,其结晶度越高,越有利于提高PVA薄膜的阻氢性能,但热处理温度宜选择在180℃以下,以防止PVA薄膜热降解,另一方面,在PVA的玻璃化转变温度以下进行热处理同样能够提高PVA薄膜的阻氢性能,而醇解度较低的PVA薄膜在玻璃化转变温度以下经热处理后的阻氢性能提高的幅度较大。     

紫外预电离TEA CO2激光器放电特性的实验研究

横向激励大气压（transversely excited atmospheric,TEA）CO2激光器的放电稳定性是决定该类型激光器应用效果的关键因素。通过对采用电感充放电电路的紫外预电离激光器的实验研究,得到了激光器放电动态过程的规律,并发现残余振荡是主放电后发生弧光放电的主要原因。实验中采用不同配比的气体,并对电感充放电电路与改进后的硅堆充放电电路进行了比较。实验结果表明：增加充电电感值可以降低主放电结束后储能电容上的残余电压;而采用硅堆放电电路在主放电后仅有相对幅值很低的稳定残压,两种方案都大幅度抑制了弧光放电的形成,有效地提高了激光单脉冲能量。     

单层2H-MoTe2光电效应的理论研究

材料的禁带宽度是影响光电探测器探测范围的重要因素.单层2H-MoTe2因具有合适的禁带宽度引起了科研人员广泛的研究兴趣.本文基于非平衡态格林函数-密度泛函理论,采用第一性原理方法,研究了单层2H-MoTe2的光电效应.结果表明:在线性偏振光照射下,MoTe2产生的光电流函数与唯象理论相吻合;在光子能量范围1.6～1.8...     

用红外激光脉冲触发半绝缘GaAs光电导开关的实验研究

报道了用光子能量低于GaAs禁带宽度的红外激光脉冲,触发电极间隙为3mm和8mm的半绝缘GaAs光电导开关的实验结果。使用单脉冲能量为1.9mJ的1 064nm Nd:YAG激光触发开关, 在偏置电压分别为3kV和5kV条件下,光电导开关分别工作于线性和非线性模式。用900nm半导体激光器和1 530nm掺铒光纤激光器分别进行触发实验,得到了重复频率分别为5kHz和20MHz的电脉冲波形。结果表明,半绝缘GaAs光电导开关可以吸收大于本征吸收限波长红外激光脉冲。     

MOPA系统建立中的三个技术问题

介绍了原子能科学研究院准分子激光研究室在建立MOPA系统中遇到的几个技术问题及解决方案。该系统已于1998年12月完成了系统整体的同步,并进行了单束的同步放大工作。     

Synthesis of Moracin C and Its Derivatives with a 2-arylbenzofuran Motif and Evaluation of Their PCSK9 Inhibitory Effects in HepG2 Cells

Proprotein convertase subtilisin/kexin type 9 (PCSK9) is a key factor in several cardiovascular diseases, as it is responsible for the elevation of circulating low-density lipoprotein cholesterol (LDL-C) levels in blood plasma by direct interaction with the LDL receptor. The development of orally available drugs to inhibit this PCSK9-LDLR interaction is a highly desirable objective. Here, we report the synthesis of naturally occurring moracin compounds and their derivatives with a 2-arylbenzofuran motif to inhibit PCSK9 expression. In addition, we discuss a short approach involving the three-step synthesis of moracin C and a divergent method to obtain various analogs from one starting material. Among the tested derivatives, compound 7 (97.1%) was identified as a more potent inhibitor of PCSK9 expression in HepG2 cells than berberine (60.9%). These results provide a better understanding of the structure–activity relationships of moracin derivatives for the inhibition of PCSK9 expression in human hepatocytes.     

Impact of Imine Bond Orientations on the Geometric and Electronic Structures of Imine-based Covalent Organic Frameworks

Many efforts are currently devoted to improving the stability and crystallinity of imine-based two-dimensional (2D) covalent organic frameworks (COFs) given their wide range of potential applications. The variation in the relative orientations of the imine bonds has been found to be a critical factor that impacts the stacking of the 2D COF layers, leads to the formation of isomer structures, and influences the crystallinity of the final product. Most investigations to date have focused only on the structural properties, while the role of the imine orientations on the electronic properties has not been studied systematically. Here, we explore this effect by examining how the electronic band structures, electronic couplings, and effective masses evolve when considering four isomeric structures of an imine-linked tetraphenyl-pyrene naphthalene-diimide COF. Our results provide an understanding of the impact of the imine orientations and how they need to be controlled to realize COF inter-layer stackings that can lead to efficient cross-plane electron transport. They can be used to guide the design and synthesis of imine-based COFs for applications where charge transport needs to be optimized.     

Access to pyridines via cascade nucleophilic addition reaction of 1,2,3-triazines with activated ketones or acetonitriles

We studied the cascade nucleophilic addition reactions of 1,2,3-triazines with activated acetonitriles or ketones,which were used to construct highly substituted pyridines that are not easily accessed by conventional methods.The strategy addressed some structural diversity issues currently facing medicinal chemistry,and the resulting pyridines could be used as convenient precursors for the synthesis of related pharmaceuticals.In particular,our method was applied to the syntheses of the marketed drug etoricoxib and several biologically important molecules in a few steps.