New measurements of the emission spectra of Sm2+ in KMgF3 and NaMgF3 crystals

The fluorescence of divalent samarium in KMgF₃ and NaMgF₃ crystals is investigated. The emission is observed to originate from transitions between the ⁵D_J, and ⁷F_J multiplets of the 4?⁶ configuration. More precisely, the lowest ⁵D_J level, ⁵D₀, appears to be the most efficient emitting level in the temperature range 4–300K. Contrary to what has been reported elsewhere, the Sm²⁺ fluorescence in both crystals does not exhibit any broad band emission even at room temperature. The great number of lines in the ⁵D₀→⁷F_J patterns gives evidence of the multiple-center origin of the fluorescence.     

Effects of Orange Leaves Extraction Conditions on Antioxidant and Phenolic Content: Optimization Using Response Surface Methodology

In the last few years, bioactive components or their extraction techniques are gaining special interest in scientific areas. In this framework, orange leaves were used for preparation of extracts with high content of biologically active compounds. To optimize the extraction process, three levels and three variables of Box–Behnken design with response surface methodology were applied. Investigated responses were the total phenolic content (TPC), 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical, cupric ion reducing antioxidant capacity (CUPRAC), and ferric reducing antioxidant power (FRAP). Independent variables were methanol concentration (10–90%), temperature (20–60°C), and extraction time (60–180?min). Experimentally obtained results were fit into a second-order polynomial model with multiple regression. Analysis of variance was used to estimate model fitness and determine optimal conditions for processing. Estimated optimal conditions were 90% methanolic solution, 60°C and 180?min using these parameters; the predicted values of investigated responses were 43.19?mg GAE/g (GAE: gallic acid equivalents), 43.04?mg TE/g (TE: trolox equivalents), 139.34 and 93.76?mg TE/g for TPC, DPPH, CUPRAC, and FRAP, respectively. The obtained optimal conditions could be considered as an alternative strategy for developing novel functional products.     

Preparation of magnetic molecularly imprinted polymer for dispersive solid‐phase extraction of valsartan and its determination by high‐performance liquid chromatography: Box‐Behnken design

In this work, core/shell magnetic molecularly imprinted polymer nanoparticles were synthesized for extraction and pre‐concentration of valsartan from different samples and then it was measured with high‐performance liquid chromatography. For preparation of molecularly imprinted polymer nanoparticles, Fe₃O₄ nanoparticles were coated with tetraethyl orthosilicate and then functionalized with 3‐(trimethoxysilyl) propyl methacrylate. In the next step, molecularly imprinted polymer nanoparticles were synthesized under reflux and distillation conditions via polymerization of methacrylic acid, valsartan (as a template), azobisisobutyronitrile and ethylene glycol dimethacrylate as cross linking. The properties of molecularly imprinted polymer nanoparticle were investigated by FTIR spectroscopy, field emission scanning electron microscopy, and X‐ray diffraction. Box‐Behnken design with the aid of desirability function was used for optimizing the effect of variables such as the amounts of molecularly imprinted polymer nanoparticles, time of sonication, pH, and volume of methanol on the extraction percentage of valsartan. According to the obtained results, the affecting variables extraction condition were set as 10 mg of adsorbent, 16 min for sonication, pH = 5.5 and 0.6 mL methanol. The obtained linear response (r² > 0.995) was in the range of 0.005–10 µg/mL with detection limit 0.0012 µg/mLand extraction recovery was in the range of 92–95% with standard deviation less than 6% (n = 3).     

Development of method for the speciation of inorganic iron in wine samples

In this paper, we proposed a procedure for the determination of iron(II) and total iron in wine samples employing molecular absorption spectrophotometry. The ligand used is 2-(5-bromo-2-pyridylazo)-5-(diethylamino)-phenol (Br-PADAP) and the chromogenic reaction in absence or presence of ascorbic acid (reducing agent) allows the determination of iron(II) or total iron, respectively. The optimization step was performed using a multivariate technique (Box Behnken design) involving the factors pH, acid ascorbic concentration and reaction time.The method allows the determination of iron(II) and iron(III) in wine samples, with limits of detection and quantification 0.22 and 0.72 μg L⁻¹, respectively. The precision expressed as relative standard deviation (R.S.D.) was 1.43 and 0.56% (both, n = 11) for content of iron(II) in wine samples of 1.68 and 4.65 mg L⁻¹, and 1.66 and 0.87% (both, n = 11) for content of total iron in wine samples of 1.72 and 5.48 mg L⁻¹.This method was applied for determination of iron(II) and total iron in six different wine samples. In these, the iron(II) content varied from 0.76 to 4.65 mg L⁻¹ and from 1.01 to 5.48 mg L⁻¹ for total iron. The results obtained in the determination of total iron by Br-PADAP method were compared with those that were performed after complete acid digestion in open system and determination of total iron employing FAAS. The method of regression linear was used for comparison of these results and demonstrated that there is no significant difference between the results obtained with these two procedures.     

本刊英文版Vol.30(2014),No.11论文摘要(英文)北大核心CSCD

On Equivalence of Simple Closed Curves in Flat Surfaces Zong Liang SUN Abstract By explicit constructions,we give direct proofs of the following results:for any distinct homotopy classes of simple closed curvesαandβin a closed surface of genus g>1,there exist a hyperbolic structure X and a holomorphic quadratic differential q on X such     

本刊英文版Vol.30(2014),No.7论文摘要(英文)

<正>Perturbations of Frames Dong Yang CHEN;;Lei LI;;Ben Tuo ZHENG Abstract In this paper,we give some sufficient conditions under which perturbations preserve Hilbert frames and near-Riesz bases.Similar results are also extended to frame sequences,Riesz sequences and Schauder frames.It is worth mentioning that some of our perturbation conditions are quite different from those used in the previous literatures on this topic.Perturbations of Moore-Penrose Metric Generalized Inverses of Linear Operators in Banach Spaces Hai Feng MA;;Shuang SUN;;Yu Wen WANG;;Wen Jing ZHENG     

Operator norm localization for linear groups and its application to K-theory

We prove the operator norm localization property for linear groups. As an application we prove the coarse Novikov conjecture for box spaces of a linear group.     

Quality by design-based development and validation of an HPLC method for simultaneous estimation of pregabalin and piperine in dual drug-loaded liposomes

The current research work describes the development of a rapid HPLC method for the concurrent detection of pregabalin and piperine in dual drug-loaded nanoformulations. The primary goal was to recognize the chromatographic conditions wherein propitious segregation of the integrants with quality peaks can be attained. An attempt to expound the target analytical profile was made to accomplish this goal, and critical method attributes (CMAs), viz. percentage acetonitrile content, injection volume and pH, which affect critical quality attributes (CQAs), were identified using systemic risk analysis. Box–Behnken design was employed to develop a relationship between CMAs and CQAs, which engenders an analytical design space. Efficient chromatographic separation for pregabalin and piperine was attained using an analytical C₁₈ column and mobile phase comprising acetonitrile–water (pH 6.9; 70:30%, v/v) in an isocratic elution mode with a 1 ml/min flow rate. The elution was descried at an isosbestic wavelength of 221 nm using a photodiode array detector. The International Conference on Harmonization guidelines were adopted for the developed HPLC method. The validated HPLC method can be further utilized for the simultaneous quantification and detection of pregabalin and piperine in other lipid-based nanopharmaceuticals such as polymeric nanoparticles, nanocrystals, solid-lipid nanoparticles, metallic nanoparticles, etc., in in vitro and in vivo studies.     

Modeling and computational framework of radiative hybrid nanofluid configured by a stretching surface subject to entropy generation: Using Keller box scheme

This study examines the characteristics of the velocity, thermal field and entropy profiles for hybrid nanofluid flow passing through a starching sheet with thermal radiation. The carbon nanotube (SWCNT and MWCNT) are used as a nanoparticles with Cattaneo-Christov (CC) heat flux. Ethylene glycol is utilized as a base fluid in this case. To achieve an improved solution, the fluid flow over the geometric properties is designed using highly non-linear PDEs, and the governing equations must be converted into dimensionless non-similar equation systems using the highly efficient well-known Keller-box scheme in computational software MATLAB. The practical feasibility of these solutions is determined by the range of the controlling parameters. The velocity distribution reduces as the magnetic parameter estimate increases, however, the temperature field and entropy production increase as the magnetic parameter fluctuation esclates. As the slip parameter is increased, the velocity field diminish. The thermal field is enhanced for rising the radiation parameter, and the entropy profile is boosted for increasing Brinkman parameter values. The findings of this research might have a significant impact on industries where local cooling and heating via impingement jets are needed in electronic devices, heat sinks, drying technologies, and so on. To the best of the authors' knowledge, this is the first effort to employ a hybrid nanofluid to analyze entropy formation due to magnetohydrodynamics flow over a starching sheet.