Local automorphisms and derivations on certain -algebras

It is shown that continuous -local derivations on -algebras are derivations and surjective -local *-automorphisms on prime -algebras or on -algebras such that the identity element is properly infinite are *-automorphisms.

     

Analytical methods for the determination of mixtures of bisphenols and derivatives in human and environmental exposure sources and biological fluids. A review

Bisphenol A (BPA) is ubiquitous in humans and the environment. Its potential adverse effects through genomic and non-genomic pathways have fostered BPA replacement by bisphenol analogs that, unfortunately, exert similar adverse effects. Many of these analogs, as well as their derivatives, have already found in humans and the environment and major concerns have arisen over their low dose- and mixture-related effects. This review aims to discuss the characteristics of the main analytical methods reported so far for the determination of mixtures of bisphenol analogs and/or derivatives in human and environmental exposure sources and biological fluids. Approaches followed for removal of background contamination, sample preparation and separation and detection of mixtures of bisphenols and derivatives are critically discussed. Sample treatment is matrix-dependent and common steps include analyte isolation, removal of interferences, evaporation of the extracts and solvent reconstitution. Separation and quantification has been almost exclusively carried out by liquid chromatography tandem mass spectrometry (LC-MS/MS) or gas chromatography mass spectrometry (GC–MS), in the last case prior derivatization, but LC-fluorescence detection has also found some applications. Main characteristics, advantages and drawbacks of these methods will be comparatively discussed. Although at an early stage, some approaches for the assessment of the risk to mixtures of bisphenols, mainly based on the combination of chemical target analysis and toxicity evaluation, have been already applied and they will be here presented. Current knowledge gaps hindering a reliable assessment of human and environmental risk to mixtures of bisphenols and derivatives will be outlined.     

Voltammetric Determination of Bisphenol A Using an Acetylene Black‐Dihexadecyl Hydrogen Phosphate Composite Film‐Modified Electrode

Abstract

Herein, acetylene black (AB) was easily dispersed into water in the presence of dihexadecyl hydrogen phosphate (DHP), resulting in a stable and homogeneous AB‐DHP suspension. Then, an AB‐DHP composite film coated glassy carbon electrode (GCE) was constructed after evaporation of water. The electrochemical behavior of bisphenol A was investigated using cyclic voltammetry (CV), linear sweep voltammetry (LSV), and differential pulse voltammetry (DPV). Compared with the unmodified GCE, the AB‐DHP film‐modified GCE not only significantly enhances the oxidation peak current of bisphenol A but also lowers the oxidation overpotential, suggesting that AB‐DHP film‐modified GCE has great potential in sensitive determination of bisphenol A. Based on this, a sensitive and simple electrochemical method was developed after optimization of the experimental parameters such as supporting electrolyte, the amount of AB‐DHP, scan rate, and accumulation time. The linearity is over the range form 2.0×10^?8 to 5.0×10^?6 mol l^?1, and the detection limit is 6.0×10^?9 mol l^?1. Finally, this method was successfully employed to determine bisphenol A in waste water samples.     

The Electrochemical Behavior of Gold Nanoparticle‐Tantalum(V) Phthalocyanine Composites: Applications Towards the Electroanalysis of Bisphenol A

The formation of gold nanoparticle (AuNP) composites with tantalum phthalocyanines (TaPc) complexes { 1a and 1b (Figure 1 )} is reported. The TaPc‐AuNPs conjugates were characterised by atomic force microscopy (AFM) and transmission electron microscopy. The AFM analyses show that conjugates of TaPc with AuNPs are more aggregated when compared to AuNPs alone. The conjugates and TaPc complexes were immobilized on a gold electrode by drop and dry method and these were characterized by electrochemical impedance spectroscopy. The charge transfer behaviour of AuNPs was enhanced in the presence of TaPc complexes. All the modified electrodes showed electrocatalytic oxidation of bisphenol A. The limits of detection for complexes 1a and 1 b were 4.78×10^?10 and 2.76×10^?10 mol L^?1, respectively.     

The development of a novel smart mid-infrared sensing methodology for residual solvents

The potential of a novel polymer modified mid-infrared technique as a ‘smart’ sensing methodology is demonstrated. Diffusion of a penetrant (analyte molecule) was monitored into a Teflon® AF2400 membrane through observation of one of its infrared absorption bands. During the diffusion of select analytes, mid-IR polymer bands were observed to experience a red shift (reduction in absorption frequency). The rate of appearance of these bands matched that of analyte diffusion. As these bands are specific to certain analytes, and their intensity is analyte-dependent, monitoring of these shifted bands forms the basis of a ‘smart’ sensing regime. The suitability of this smart sensing methodology for the enhanced detection of several residual solvents is presented. A fivefold increase in sensitivity through the monitoring of these bands was realized for the detection of ethylbenzene. One of the aims of this work was to determine whether the cause of the polymer band shifting is chemical or optical in nature. Result data presented support the hypothesis that polymer/diffusant interactions cause this band shifting. This is demonstrated by the fact that a penetrant (tetrahydrofuran), which affected a band shift in the polymer, displayed a blue shift (increase in absorption frequency) in its own spectrum. Ethanol did not cause a polymer band shift and displayed no band shifts in its absorbance spectrum. The relative absorbance of the shifted polymer bands is compared between analytes and does not demonstrate a correlation to analyte refractive indices supporting a polymer/diffusant interaction hypothesis.     

HYDROGEN-BONDING INDUCED CHANGE OF CRYSTALLIZATION BEHAVIOR OF POLY（BUTYLENE SUCCINATE） IN ITS MIXTURES WITH BISPHENOL A

In the present work, the blend of poly（butylene succinate） （PBS） and bisphenol A （BPA） was prepared by solution mixing, and the intermolecular interactions between the two components were characterized by a combination of nuclear magnetic resonance （NMR） and Fourier transform infrared spectroscopy （FTIR）. The results showed that intermolecular hydrogen-bonding forms between the carbonyl group of PBS and phenol hydroxyl of BPA. With the increase of BPA content, more hydrogen bonds were formed. The effect of hydrogen bonding on the crystallization behavior of PBS was investigated by differential scanning calorimetry （DSC） and polarized optical microscopy （POM）. The results showed that the overall isothermal crystallization kinetics and the spherulite growth rate of PBS decrease with the increase of BPA content, while the PBS spherulite size increases with BPA content.     

Liquid chromatography with diode array detection and multivariate curve resolution for the selective and sensitive quantification of estrogens in natural waters

Following the green analytical chemistry principles, an efficient strategy involving second-order data provided by liquid chromatography (LC) with diode array detection (DAD) was applied for the simultaneous determination of estriol, 17β-estradiol, 17α-ethinylestradiol and estrone in natural water samples. After a simple pre-concentration step, LC–DAD matrix data were rapidly obtained (in less than 5 min) with a chromatographic system operating isocratically. Applying a second-order calibration algorithm based on multivariate curve resolution with alternating least-squares (MCR-ALS), successful resolution was achieved in the presence of sample constituents that strongly coelute with the analytes. The flexibility of this multivariate model allowed the quantification of the four estrogens in tap, mineral, underground and river water samples. Limits of detection in the range between 3 and 13 ng L⁻¹, and relative prediction errors from 2 to 11% were achieved.     

Single-step extraction and cleanup of bisphenol A in soft drinks by hemimicellar magnetic solid phase extraction prior to liquid chromatography/tandem mass spectrometry

Hemimicelles of tetradecanoate chemisorbed onto magnetic nanoparticles (MNPs) are here proposed as a sorbent for the single-step extraction and cleanup of bisphenol A (BPA) in soft drinks. The purpose of this work was to develop a simple, rapid and low-cost sample treatment suitable to assess the human exposure to BPA from this type of high consumption food. The nanoparticles were easily coated by mixing commercially available magnetite of 20–30 nm mean particle diameter with tetradecanoate at 85 °C for 30 min. The extraction/cleanup procedure involved stirring the samples (3 mL) with 200 mg of tetradecanoate-coated MNPs for 20 min, isolating the sorbent with a Nd–Fe–B magnet and eluting BPA with methanol. The extraction efficiency was not influenced by salt concentrations up to 1 M and pH values over the range 4–9. No cleanup of the extracts was needed, and the method proved matrix-independent. The extracts were analyzed by liquid chromatography, electrospray ionization tandem mass spectrometry. Quantitation was performed by internal standard calibration using BPA-¹³C₁₂. The limit of quantitation obtained for the method, 0.03 ng mL⁻¹, was below the usual range of concentrations reported for BPA in soft drinks (0.1–3.4 ng mL⁻¹). The proposed method was successfully applied to the determination of BPA in different samples acquired from various supermarkets in southern Spain; the concentrations found ranged from 0.066 to 1.08 ng mL⁻¹. Recoveries from samples spiked with 0.33 ng mL⁻¹ of BPA ranged from 91% to 105% with relative standard deviations from 3% to 8%.     

Parylene-AF4: a polymer with exceptional dielectric and thermal properties

[2.2]Paracyclophanes are useful chemical vapor deposition (CVD) precursors of thin film polymers, known as Parylenes. Parylenes are ideally suited for use as conformal coatings in a wide variety of applications, such as in the automotive, medical, electronics, and semiconductor industries. Parylene coatings are inert and transparent and have excellent barrier properties. The bridge-fluorinated 1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane (AF4) is the CVD precursor of Parylene-AF4 polymer, which combines a low dielectric constant with high thermal stability, low moisture absorption, and other advantageous properties. With such properties, and because its in vacuo deposition process ensures conformality to microcircuit features and superior submicron gap-filling capability, Parylene-AF4 has considerable promise as an interlayer dielectric for on-chip high-speed semiconductor device interconnection. This paper reviews the synthesis and properties of Parylene-AF4 and its paracyclophane precursor, including a discussion of the importance of the fluorinated bridges, the advantages of the dimeric precursor, and why Parylene-AF4 has the potential to meet the needs of the semiconductor industry with respect to the key properties of a potential interlayer dielectric.     

AF C*-代数中的Lie理想

本文描述了AF C*-代数中闭Lie理想,证明了如果AF C*-代数A中的线性流形L 是A的闭Lie理想,则存在A的闭结合理想I和A的典型masa D中的闭子代数EI使得[A,I](?)L(?)I EI,并且A中每一个这种形式的闭子空间都是A的闭Lie理想.