首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1045篇
  免费   68篇
  国内免费   27篇
化学   402篇
晶体学   5篇
力学   135篇
综合类   19篇
数学   186篇
物理学   393篇
  2024年   2篇
  2023年   12篇
  2022年   30篇
  2021年   32篇
  2020年   33篇
  2019年   21篇
  2018年   33篇
  2017年   30篇
  2016年   45篇
  2015年   46篇
  2014年   36篇
  2013年   81篇
  2012年   29篇
  2011年   56篇
  2010年   31篇
  2009年   58篇
  2008年   71篇
  2007年   54篇
  2006年   37篇
  2005年   47篇
  2004年   45篇
  2003年   37篇
  2002年   29篇
  2001年   45篇
  2000年   31篇
  1999年   25篇
  1998年   14篇
  1997年   21篇
  1996年   12篇
  1995年   16篇
  1994年   11篇
  1993年   12篇
  1992年   7篇
  1991年   5篇
  1990年   8篇
  1989年   6篇
  1988年   6篇
  1987年   3篇
  1986年   6篇
  1985年   5篇
  1982年   4篇
  1981年   2篇
  1979年   3篇
  1975年   3篇
排序方式: 共有1140条查询结果,搜索用时 15 毫秒
1.
2.
In this paper, we re-examine a series of gedanken welcher Weg (WW) experiments introduced by Scully, Englert and Walther that contain the essential ideas underlying the quantum eraser. For this purpose we use the Bohm model which gives a sharp picture of the behaviour of the atoms involved in these experiments. This model supports the thesis that interference disappears in such WW experiments, even though the centre of mass wave function remains coherent throughout the experiment. It also shows exactly what it means to say ‘that the interference can be restored by manipulating the WW detectors long after the atoms have passed’. It does not support Wheeler’s notion that ‘the past is undefined and undefinable without the observation (in the present)’.  相似文献   
3.
Free‐radical copolymerizations of N‐vinylcaprolactam (VCL) and glycidyl methacrylate (GMA) were investigated to synthesize temperature‐responsive reactive copolymers with minimized compositional heterogeneity. The average copolymer composition was determined by Fourier transform infrared and nuclear magnetic resonance techniques. The reactivity ratios for VCL and GMA were found to be 0.0365 ± 0.0009 and 6.44 ± 0.36 by the Fineman–Ross method and 0.039 ± 0.006 and 6.75 ± 0.29 by the Kelen–Tudos method, respectively. When prepared by batch polymerization, VCL–GMA copolymers had a highly heterogeneous composition and fractions of different solubilities in water. The use of a gradual feeding technique, which included the sequential addition of more reactive GMA monomer into the reaction, yielded copolymers with much more homogeneous composition. The produced copolymers with 0.9 and 0.11 fractional GMA contents preserved their temperature‐responsive properties and precipitated from aqueous solutions when the temperature exceeded 31 °C. The GMA units in the VCL–GMA copolymers were capable of reacting with amino end‐functionalized poly(ethylene oxide) at room temperature to produce poly(N‐vinylcaprolactam)–poly(ethylene oxide) graft copolymers. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 183–191, 2006  相似文献   
4.
Bohr's well-known claim that only a registered phenomenon is a true phenomenon is further elaborated into occurrence in the past: If ideal occurrence of an eventP ((1–P)) is a state at a timet i makes another eventQ ((1–Q))certain at a later timet f, and, finallyU is the evolution operator fromt i tot f, then, it is proved that the final collapsed stateQ(U U +)Q/TrQU U +, which comes about in ideal occurrence ofQ att f,equals the initial collapsed stateU(P P/TrP)U +, which evolves from the state resulting from the ideal occurrence ofP in att i. Utilizing the latter state is called theretroactive apparent ideal occurrence (RAIO) ofP in. A number of consequences, including the general notion of twin events (the case whent f=t i, andU=1) is derived. It is pointed out that RAIO is relevant in second-kind quantum measurement, in Wheeler's delayed-choice experiments in second-kind (or conditional) quantum preparators.  相似文献   
5.
转移基板材质对Si衬底GaN基LED芯片性能的影响   总被引:7,自引:4,他引:3  
在Si衬底上生长了GaN基LED外延材料,分别转移到新的硅基板和铜基板上,制备了垂直结构蓝光LED芯片。研究了这两种基板GaN基LED芯片的光电性能。在切割成单个芯片之前,对大量尺寸为(300μm×300μm)的这两种芯片分别通高达1 A的大电流在测试台上加速老化1 h。结果显示,铜基板Si衬底GaN基LED芯片有更大的饱和电流,光输出效率更高,工作电压随驱动电流的变化不大,光输出在老化过程中衰减更小。铜基板芯片比硅基板芯片可靠性更高,在大功率半导体照明器件中前景诱人。  相似文献   
6.
Molecules containing the guanidinic nuclei possess several pharmacological applications, and knowing the preferred isomers of a potential drug is important to understand the way it operates pharmacologically. Benzoylguanidines were synthesized in satisfactory to good yields and characterized by NMR, Electrospray Ionization Mass Spectrometry (ESI‐MS) and Fourrier Transform InfraRed Spectroscopy techniques (FTIR). E/Z isomerism of the guanidines was studied and confirmed by NMR analysis in solution (1H‐13C Heteronuclear Single Quantum Coherence (HSQC) and Heteronuclear Multiple‐Bond Correlation (HMBC), 1H‐15N HMBC, 1H‐1H Correlation Spectroscopy (COSY) and Nuclear Overhauser Effect Spectroscopy (NOESY) experiments) at low temperatures. Compounds with p‐Cl and p‐Br aniline moiety exist mainly as Z isomer with a small proportion of E isomer, whereas compounds with p‐NO2 moiety showed a decrease in proportion of isomer Z. The results are important for the application of these molecules as enzymatic inhibitors. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
7.
Vector‐borne diseases, such as leishmaniasis, dengue, malaria, and yellow fever, transmitted by microparasites show periodic fluctuations in their prevalence. The novelty of this research is to assess the relationship between the vector feeding preference for an infectious host and the annual seasonal transmission through a vector‐host mathematical model. For the first time, numerical simulations illustrate that by increasing the vector feeding preference value in the transmission dynamics, periodic fluctuations accentuate and the endemic equilibrium average increases in vector and host populations. Moreover, increasing the vector feeding preference value, the amplitude strengthens for the infectious host and vector populations. This periodic behavior shows a similar pattern with the Peruvian incidence data from 2000 to 2016 for Andean cutaneous leishmaniasis provided by the Ministry of Health of Peru (MINSA). In addition, using the Floquet theory, the time average method and the linear operator method provides for the first time that the basic reproduction number for a nonautonomous system depends explicitly on the vector feeding preference for the infectious host. The nonautonomous model system shows that is a threshold parameter for the local stability of the disease‐free periodic solution. Therefore, the vector feeding preference is an important factor that should be considered and attended to for future research. Public and veterinary health in Peru and other countries should consider the vector feeding preference for specific host to vector control.  相似文献   
8.
以高等数学课堂教学为例,通过科学试验的方法分析数学建模思想渗入大学数学课堂教学对学生学习的影响力。通过精心设计教学试验,采集大量试验数据进行建模分析,结果表明,数学建模思想渗入高等数学课堂教学会对学生的学习产生积极影响,值得推广并长期坚持。  相似文献   
9.
Following a recent investigation on the N(2D) + H2O reaction [Homayoon et al., J. Phys. Chem. Lett. 5, 3508 (2014)], we report on an experimental and theoretical study of the isotopologue N(2D) + D2O reaction. Crossed molecular beam (CMB) experiments were conducted at a collision energy of 10.3 kcal mol–1. Quasiclassical trajectory calculations were performed on a recent potential energy surface to derive the centre-of-mass functions necessary to simulate the CMB laboratory distributions. Excellent agreement was found. The importance of the channel leading to HON/DON was confirmed. The inclusion of this channel, in addition to that leading to the isomer HNO/DNO, can affect the models considering the coupling between nitrogen and oxygen chemistry in the upper atmosphere of Titan.  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号