全文获取类型
收费全文 | 5728篇 |
免费 | 359篇 |
国内免费 | 1537篇 |
专业分类
化学 | 5142篇 |
晶体学 | 49篇 |
力学 | 198篇 |
综合类 | 61篇 |
数学 | 1501篇 |
物理学 | 673篇 |
出版年
2024年 | 13篇 |
2023年 | 82篇 |
2022年 | 141篇 |
2021年 | 160篇 |
2020年 | 230篇 |
2019年 | 225篇 |
2018年 | 172篇 |
2017年 | 251篇 |
2016年 | 244篇 |
2015年 | 193篇 |
2014年 | 316篇 |
2013年 | 515篇 |
2012年 | 437篇 |
2011年 | 355篇 |
2010年 | 293篇 |
2009年 | 371篇 |
2008年 | 387篇 |
2007年 | 368篇 |
2006年 | 321篇 |
2005年 | 293篇 |
2004年 | 313篇 |
2003年 | 255篇 |
2002年 | 210篇 |
2001年 | 158篇 |
2000年 | 167篇 |
1999年 | 165篇 |
1998年 | 120篇 |
1997年 | 133篇 |
1996年 | 125篇 |
1995年 | 107篇 |
1994年 | 86篇 |
1993年 | 78篇 |
1992年 | 73篇 |
1991年 | 54篇 |
1990年 | 40篇 |
1989年 | 23篇 |
1988年 | 24篇 |
1987年 | 18篇 |
1986年 | 19篇 |
1985年 | 11篇 |
1984年 | 13篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 6篇 |
1980年 | 12篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1959年 | 2篇 |
排序方式: 共有7624条查询结果,搜索用时 15 毫秒
31.
We study a class of ‘nonpoissonian’ transformations of the configuration space and the corresponding transformations of the Poisson measure. For some class of Poisson measures we find conditions which are sufficient for the transformed measure (which in general is nonpoissonian) to be absolutely continuous with respect to the initial Poisson measure and get the expression for the corresponding Radon–Nikodym derivative. To solve this problem we use a distributional approach to Poisson multiple stochastic integrals. 相似文献
32.
33.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
34.
L. Jackowska-Strumillo J. Sokolowski A. Żochowski A. Henrot 《Computational Optimization and Applications》2002,23(2):231-255
The new method is proposed for the numerical solution of a class of shape inverse problems. The size and the location of a small opening in the domain of integration of an elliptic equation is identified on the basis of an observation. The observation includes the finite number of shape functionals. The approximation of the shape functionals by using the so-called topological derivatives is used to perform the learning process of an artificial neural network. The results of computations for 2D examples show, that the method allows to determine an approximation of the global solution to the inverse problem, sufficiently closed to the exact solution. The proposed method can be extended to the problems with an opening of general shape and to the identification problems of small inclusions. However, the mathematical theory of the proposed approach still requires futher research. In particular, the proof of global convergence of the method is an open problem. 相似文献
35.
Ana L. Montero Luis A. Montero Ricardo Martínez S. Spange 《Journal of Molecular Structure》2006,770(1-3):99-106
A quantum chemical model (Abinitio HF-MO and DFT-B3LYP) of polyfurfuryl alcohol crosslinking is shown. Two pathways were considered: (a) a Diels–Alder (D–A) reaction between a dihydrofuran moiety and a furan ring; (b) the addition reaction of electrophilic specimens on conjugated double bonds. The ability for the formation of D–A adducts (dienes and dienophiles) was investigated by the frontier molecular orbital (FMO) theory. Energy gaps between the FMO's of diene and dienophile structures suggest that the occurrence of the D–A reaction is possible. The results suggest that the carbons of the exo double bonds attached to dihydrofuran rings are the sites most likely to be attacked by electrophilic species, while the C3 and C4 atoms display the opposite tendency due to their low HOMO electron densities. Results of a thermochemical approach to these reactions at the MP2 level was in agreement with reactivity modelled by MO predictions. 相似文献
36.
甜菜糖蜜酒精废液含有大量的有机物,pH值低,BOD、CDO值高,直接排和会造成环境的严重污染,又损失了一些有机物,在此废液中可直接接入酵母菌,使其大量繁殖,生产出的菌体粗蛋白含量达41.7%,CDO值降低了20%以上,减轻了环境污染。 相似文献
37.
本文对二种新合成的2,3-二羟基萘二钼和四钼多酸有机衍生物[n-Bu)4N]2[Mo2O5(OC10H6O)2](Ⅰ)和[n-Bu)4N]2[Mo4O10(OC10H6O)2(OCH3)2](Ⅱ)进行了红外光谱与核磁共振波谱研究,发现[Mo2O5]^2 中钼氧多桥键的红外振动频率较[Mo4O10(OCH3)2]^2 中钼氧多桥键的红外振动频率红移,而在配合物Ⅱ中2,3-二羟基中芳环的^1H化学位移较配合物Ⅰ中向低场移动。同时还发现含二钼配位中心[Mo2O5]^2 的[Mo2O5(OC10H6O)2]^2-与含四钼配位中心[Mo4O10(OCH3)2]^2 的[Mo4O10(OC10H6O)2(OCH3)2]^2-生成条件的差异仅仅只在反应体系的pH值的微小变化,说明钼多酸有机衍生物阴离子是对体系酸碱度极为敏感的物质。 相似文献
38.
本文将文献[9]中给出的一维广义函数的集值导数的某些结果,推广到n维情形,并给出一些与优化有关的其他结果. 相似文献
39.
We give some sufficient conditions for proper lower semicontinuous functions on metric spaces to have error bounds (with exponents).
For a proper convex function f on a normed space X the existence of a local error bound implies that of a global error bound. If in addition X is a Banach space, then error bounds can be characterized by the subdifferential of f. In a reflexive Banach space X, we further obtain several sufficient and necessary conditions for the existence of error bounds in terms of the lower Dini
derivative of f.
Received: April 27, 2001 / Accepted: November 6, 2001?Published online April 12, 2002 相似文献
40.
甲基红染料掺杂的聚乙烯醇薄膜光存储特性的实验研究 总被引:1,自引:0,他引:1
用2倍频小型YAG激光(532nm)作为写入光和擦除光,用He-Ne激光器623.8nm线作为读出光,用CCD作为探测器,研究了不同写入光功率下,甲基红/聚乙烯醇(MR/PVA)薄膜光栅生长的动力学过程和不同擦除光功率下,光栅擦除的动力学过程.结合光栅生长曲线的波动现象,对光存储机制进行了新的探讨.实验发现,两写入光和读出光的功率配比为1:1:1时,可获得最大衍射效率,提出读出光对写入过程具有双重作用的物理模型,对此实验结果给出了合理的解释. 相似文献