全文获取类型
收费全文 | 158篇 |
免费 | 11篇 |
国内免费 | 10篇 |
专业分类
化学 | 169篇 |
晶体学 | 1篇 |
物理学 | 9篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 7篇 |
2012年 | 14篇 |
2011年 | 11篇 |
2010年 | 10篇 |
2009年 | 25篇 |
2008年 | 11篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 1篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1991年 | 1篇 |
1990年 | 7篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有179条查询结果,搜索用时 15 毫秒
151.
Nian‐Yun Yang Xiao‐Hua Xu Dong‐Chun Ren Jin‐Ao Duan Ning Xie Li‐Juan Tian Shi‐Hui Qian 《Helvetica chimica acta》2010,93(1):65-71
Four new secoiridiod glucosides, p‐hydroxyphenethyl 7‐β‐D ‐glucosideelenolic acid ester ( 1 ), 6′‐elenolylnicotiflorine ( 2 ), 6′′′‐acetylnicotiflorine ( 3 ), and oleoside 7‐ethyl 11‐methyl ester ( 4 ), as well as six known glucosides, nuezhenide ( 5 ), Gl‐3 ( 6 ), nicotiflorine ( 7 ), isonuezhenide ( 8 ), neonuezhenide ( 9 ), and oleoside 11‐methyl ester ( 10 ) were isolated from the fruits of Ligustrum lucidum. Their structures were elucidated by spectroscopic methods. Compound 4 was an artifact produced during extraction. 相似文献
152.
Antonio Fiorentino Brigida D'Abrosca Andreina Ricci Severina Pacifico Simona Piccolella Pietro Monaco 《Magnetic resonance in chemistry : MRC》2009,47(11):1007-1012
Three new nor‐neo‐clerodane diterpenes, named chamaedryoside A (1), B (2) and C (3), have been isolated from the organic extracts of Teucrium chamaedrys (L.) and their structural characterization has been accomplished by 1H and 13C‐NMR spectra, and DEPT, by COSY, TOCSY, HSQC, HSQC‐TOSCY and HMBC experiments, as well as by ESI‐MS/MS techniques. The stereostructures have been elucidated by NOESY and computational calculations. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
153.
Kiyoshi Hosono Akihiko Kanazawa Hideharu Mori Takeshi Endo 《Cellulose (London, England)》2007,14(5):529-537
Cellulose acetate (degree of substitution 2.45) films containing diphenyliodonium salt and benzophenone were prepared and their degradative behavior was examined under simulated solar exposure. Acetic acid generation from the films under irradiation was greater in the co-presence of diphenyliodonium salt and benzophenone than in the sole presence of diphenyliodonium salt. Photosensitization and free-radical oxidization, which are followed by Brønsted acid generation, were postulated as the mechanism for the observed increase of deacetylation. The patterns of decreased molecular weight were different between the films with the diphenyliodonium salt and those with benzophenone; while the films with the diphenyliodonium salt kept a relatively constant molecular-weight distribution, the polydispersity increased in the films with benzophenone during the degradation. Since the synthesized characteristics of those two different patterns of change in molecular-weight distribution were observed in the co-presence of the diphenyliodonium salt and benzophenone, each additive appeared to act independently to lead to main-chain cleavage of cellulose acetate. Therefore, decrease in the molecular weight of cellulose acetate by diphenyliodonium salt did not seem to be enhanced in the co-presence with benzophenone. 相似文献
154.
155.
Qin Qin Zhu Wolfram Schnabel 《Journal of photochemistry and photobiology. A, Chemistry》2000,130(2-3):119-125
Hindered amines such as 2,2,6,6-tetramethyl piperidines and N-methyl-2,2,6,6-tetramethyl piperidines and hindered amino ethers such as N-methoxy-2,2,6,6-tetramethyl piperidines were examined with respect to their reactivity towards triplet-excited benzophenone (3BP*) in Ar-saturated acetonitrile solution at room temperature. Upon measuring phosphorescence decay rates in the absence and presence of quencher it was found that the amines are two to three orders of magnitude more reactive than the amino ethers. For all amine/BP systems examined the generation of free ions was inferred from an increase in the electrical conductivity. This indicates that a charge transfer (CT) mechanism is operative in these cases. Notably, tertiary amines were found to be more reactive towards 3BP* and give higher free ion yields than secondary amines. In the case of amino ether/BP systems evidence for a CT mechanism was not obtained in spite of an increase in the electrical conductivity indicating the generation of free ions. The latter are formed much faster than the phosphorescence decays and very likely originate from triplet–triplet annihilation (3BP*+3BP*→BP√++BP√−). 相似文献
156.
Hai Jiang Xu-Dong Xing Mei-Ling Yan Xin-Yue Guo 《Journal of carbohydrate chemistry》2013,32(6):383-391
AbstractTwo new cucurbitane-type triterpenoid glucosides, 3β,11α-dihydroxycucurbita-5,24(E)-diene-3,26-glucosides (1) and 3β,11α-dihydroxycucurbita-5,24(Z)-diene-3,27-glucosides were isolated from the tubers of Hemsleya amabilis. Their structures were elucidated by various spectroscopic techniques including IR, HRESIMS, 1D and 2D NMR. The two compounds were evaluated for their anti-tumor activity against HeLa and HepG-2 cell lines, and both displayed moderate anti-tumor activity towards HeLa cell lines with IC50 values of 9.8 and 15.7?μM, respectively. 相似文献
157.
158.
Jacques H. Poupaert Patrick Depreux Christopher R. McCurdy 《Monatshefte für Chemie / Chemical Monthly》2003,134(6):823-830
Summary. AlCl3-mediated chlorocarbonylation of a first arene by oxalyl chloride followed by in situ Friedel-Crafts acylation of a second electron-rich arene expeditiously provides, in a one-pot procedure, either symmetrical or unsymmetrical
benzophenones with yields ranging from 17–52%. Best results are obtained when the more activated substrate is used as the
second arene. Another advantage is that the resultant benzophenone precipitates from the reaction mixture allowing facile
workup.
Corresponding author. E-mail: Poupaert@cmfa.ucl.ac.be
Received October 4, 2002; accepted October 15, 2002
Published online March 6, 2003 相似文献
159.
Antonio Fiorentino Marina DellaGreca Annunziata Golino Angelina Izzo 《Tetrahedron》2006,62(38):8952-8958
Implementing the phytochemical study of the weed Amaranthus retroflexus, four new sesquiterpene glucosides were isolated from the methanolic extract of the plant. The structures of these metabolites are determined on the basis of the mass spectrometry, and 1D and 2D NMR spectroscopies (DQ-COSY, TOCSY, HSQC, HSQC-TOCSY, HMBC, and NOESY). Two compounds are characterized by a new aglycone and differed from the site of glucosylation. The other two compounds are dimeric diastereoisomers.All the glucoside sesquiterpenes were tested on the wild species Taraxacum officinale to evaluate the role of this weed in the habitat and on the seed of A. retroflexus to verify the potential autotoxic effect of the plant. 相似文献
160.