The Synthesis,Characterization and Conductance Studies of New Cu(II), Ni(Ii) And Zn(II) Complexes with the Schiff Base Derived from 1,2-Bis-(o-Aminophenoxy)Ethane and Salicylaldehyde

Cu(II), Ni(II) and Zn(II) complexes with the Schiff base derived from 1,2-bis-(o-aminophenoxy)ethane with salicylaldehyde have been prepared. The complexes have been characterized by elemental analysis, magnetic measurements, ¹H NMR, ¹³C NMR, UV, visible and IR spectra as well as conductance measurements. The ligand is coordinated to the central metal as a tetradentate ONNO ligand. The four bonding sites are the central azomethine nitrogen and aldehydic OH groups. The ligand was used for complexation studies. Stability constants were measured by a conductometric method. Furthermore, the stability constants for complexation between ZnCl₂ and Cu(NO₃)₂ salts and N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H₂L) in 80% dioxane/water and pure methanol were determined from conductance measurements. The magnitudes of these ion association constants are related to the nature of the solvation of the cation and the complexed cation. The mobilities of the complexes are also dependent, in part, upon solvation effects.     

H(2) activation and hydride transfer to olefins by al(c(6) f(5) )(3) -based frustrated lewis pairs

Frustrated delivery: Frustrated Lewis pairs derived from tBu(3) P and Al(C(6) F(5) )(3) activate H(2) to give [tBu(3) PH][(μ-H)(Al(C(6) F(5) )(3) )(2) ], which reacts with unactivated olefins to give RAl(C(6) F(5) )(2) (R=Et or Cy) and [tBu(3) PH][Al(C(6) F(5) )(4) ]. The proposed mechanism involves olefin activation by aluminum, which is supported by the isolation of the cyclohexene complex [Al(C(6) F(5) )(3) ?(C(6) H(10) )].     

闭路光伏光折变聚合物中非相干耦合亮-暗空间孤子对

为了得到闭路光折变有机聚合物中存在非相干耦合亮-暗光伏空间孤子对,采用数值模拟的方法,对稳态情况下两束互不相干的光束,在闭路光伏光折变有机聚合物中的传播进行了研究。结果表明,具有相同偏振和相同波长的两束互不相干的光束,可在光伏光折变有机聚合物中形成非相干耦合亮-暗光伏孤子对。在给定适当参量或扰动不太大的情况下,孤子对中的亮孤子和暗孤子都能在光伏光折变有机聚合物中稳定传播。研究结果可为光折变有机聚合物空间孤子理论的发展提供理论依据。     

双光子光折变晶体串联回路中独立全息屏蔽空间孤子对

为了得到双光子独立全息屏蔽空间孤子对的结果,基于光折变晶体中的两波耦合和双光子光折变效应,证明在由两块双光子光折变晶体和一个电压源通过导线连接组成的串联回路中存在全息亮(暗)屏蔽孤子。每块晶体中能支持一个全息屏蔽孤子,这两个孤子称为双光子独立全息屏蔽孤子对,有明-明、暗-暗和明-暗三种类型。数值计算结果表明,在光束的空间展宽远小于晶体宽度的极限条件下,孤子对中的两孤子通过光电流和相互耦合能影响到这些孤子的空间包络和动态演化特性。     

多分量AKNS方程的新可积分解

从一个任意阶矩阵谱问题出发,多分量AKNS方程的新可积分解被导出.通过利用迹恒等式建立了其双哈密顿结构.同时,证明了空间与时间的约束流在刘维尔意义下是两个完全可积的哈密顿系统.     

Recollements arising from cotorsion pairs on extriangulated categories

This paper is devoted to constructing some recollements of additive categories associated to concentric twin cotorsion pairs on an extriangulated category. As an application, this result generalizes the work by W. J. Chen, Z. K. Liu, and X. Y. Yang in a triangulated case [J. Algebra Appl., 2018, 17(5): 1–15]. Moreover, it highlights new phenomena when it applied to an exact category. Finally, we give some applications of our main results. In particular, we obtain Krause's recollement whose proofs are both elementary and very general.     

Ion-pairing and reversed phase liquid chromatography for the determination of three different quinolones: Enrofloxacin,lomefloxacin and ofloxacin

Two simple and sensitive high performance liquid chromatographic (HPLC) methods have been developed for the simultaneous determination of three different quinolones: enrofloxacin, lomefloxacin and ofloxacin in their pure and dosage forms, one with reversed phase HPLC and the other with ion-pair HPLC. In reversed phase HPLC, method (A), the mobile phase consists of 2.18% aqueous solution of KH₂PO₄ with pH adjusted to 2.4 ± 0.2 with acetonitrile (80:20; v/v), the mobile phase pumped at flow rate of 1.2 ml min^?1. A Neucleosil C₁₈ column (10 μm, 100 Å), 250 mm length × 4.6 mm diameter was utilized as stationary phase. Detection was affected spectrophotometrically at 294 nm. While in ion-pair HPLC, method (B), the mobile phase was aqueous solution of 0.65% sodium perchlorate and 0.31% ammonium acetate adjusted to pH 2.2 ± 0.2 with orthophosphoric acid: acetonitrile (81:19; v/v), the mobile phase pumped at flow rate of 1.5 ml min^?1. A μ bondapack C₁₈ column (10 μm, 100 Å), 250 mm length × 4.6 mm diameter was utilized as stationary phase. Detection was affected spectrophotometrically at 294 nm. Linearity ranges for enrofloxacin, lomefloxacin and ofloxacin were 4.0–108, 7.0–112 and 8.0–113 μg ml^?1, respectively using method A and 8.0–112, 7.0–112 and 5.0–105 μg ml^?1, respectively applying method B. Minimum detection limits obtained were 0.013, 0.023 and 0.035 μg ml^?1 for enrofloxacin, lomefloxacin and ofloxacin, respectively using method A, and 0.028, 0.023 and 0.011 μg ml^?1 using method B. The proposed methods were further applied to the analysis of enrofloxacin in injection and tablets containing the ofloxacin and lomefloxacin drugs, and the results were satisfied.     

Base-induced transient isotachophoretic stacking of acidic drugs in capillary zone electrophoresis

Online sample concentration of acidic drugs by transient isotachophoresis (t-ITP) with the injection of a base is described in capillary zone electrophoresis (CZE). A positively coated capillary was conditioned with background electrolyte (ammonium acetate at pH 6). A long plug of sample solution (S) prepared in ammonium acetate was then hydrodynamically injected followed by the base (tetrapropylammonium hydroxide). A negative voltage was applied and caused the hydroxide ions from the base to penetrate the S zone and created a pH junction that swept through the S zone. The analytes stack at the junction where the mechanism of focusing was transient ITP with the acetate and hydroxide ions as leading and terminating ions, respectively. The concentrated analytes separated in co-EOF CZE once the hydroxide was exhausted. The base stacking strategy was tested using hypolipidemic, nonsteroidal anti-inflammatory, and diuretic drugs, and afforded 19-37 improvements in peak height.