Thermo-sensitive colloidal crystals of silica spheres in the presence of large spheres with poly (N-isopropyl acrylamide) shells

Thermo-sensitive colloidal crystals are prepared simply by mixing colloidal silica spheres and large thermo-sensitive gel spheres. The thermo-reversible change in the lattice spacing of colloidal crystals of monodisperse silica spheres (CS82, 103 nm in diameter) depends on the size of the admixed temperature-sensitive gel spheres. For spheres with sizes less and greater than that of the silica spheres, the lattice spacing upon temperature increase above the lower critical solution temperature of poly(N-isopropyl acrylamide) decreases (cf. Okubo et al. Langmuir 18:6783, 2002) and increases, respectively. A mechanism, which is able to explain these experimental findings, is proposed. Moreover, crystal growth rates and the rigidities of the thermo-sensitive colloidal crystals are studied.     

A general method for the quantitative determination of catecholamines in body fluids using off-line sample pretreatment and HPLC-ED analysis

Summary Reversed phase HPLC with electrochemical detection (HPLC-ED) was used for quantitative determination of adrenaline, noradrenaline, and dopamine in several complex biological matrices, including plasma, uremic plasma, and urine. Three different methods of sample preparation for use in this clinical chemistry were tested. These were adsorption of catecholamines on alumina, organic solvent extraction after complex formation with diphenylborate, and adsorption of catecholamines on a cation exchange gel followed by organic solvent extraction of the elute. The selectivity and precision of the three methods were evaluated. The organic solvent extraction proved to be more precise and selective than adsorption on alumina (adrenaline: cv=3.80% vs. 7.58%; noradrenaline: cv=1.70% vs. 4.26%); it also proved suitable for use in the routine quantitative determination of catecholamines in plasma from patients with normal renal function (creatinine <1.2 mg/dl). However when working with uremic plasma or urine, a more selective sample preparation was required. In this case the adsorption of catecholamines on a cation exchange gel followed by organic solvent extraction of the elute was sufficiently selective and precise and thus allowed a reliable quantitative determination of adrenaline and noradrenaline from rather complex biological matrices (adrenaline: cv=6.2%; noradrenaline: cv=2.8%). Use of this specific method showed that basal plasma catecholamine levels in dialysis patients are comparable to those found in patients with normal renal function (adrenaline: 47.7±22.2 pg/ml; noradrenaline: 310.3±121.4 pg/ml).     

能谱涨落统计特征分析在Logistic混沌序列上的应用

混沌现象普遍存在于现实生活中,混沌时间序列的分析是非线性系统研究的主要内容.基于Anderson 模型,提出了一种新的混沌序列的分析方法.通过对Logistic序列的分析,使用能谱涨落分析方法,发现能级斥力的大小能与最大lyapunov指数相对应.结果表明,该方法能较好的预测混沌序列,而且具有较强的抗噪声的能力,不受初值敏感性的影响.     

弱熔体对流对定向凝固中棒状共晶生长的影响

利用渐近方法求出在弱对流熔体中定向凝固棒状共晶生长的浓度场的渐近解,研究了弱熔体对流对定向凝固中棒状共晶生长的影响.结果表明,弱熔体对流对定向凝固中棒状共晶生长有显著的作用;平均界面过冷度不仅与棒状共晶的棒间距、生长速度有关,还与流动强度有关;当生长速度一定时,随着流动强度增大,棒状共晶的平均界面过冷度减小.利用最小过冷原则,获得棒间距与生长速度和流动强度的关系.结果表明,当生长速度比较小时,随着流动强度增大,棒状共晶的棒间距增大;当生长速度比较大时,随着流动强度增大,棒状共晶的棒间距变化减弱;棒状共晶的生长速度越小,流动对棒状共晶生长的影响越大.利用本文的解析结果计算在对流条件下Al-Cu共晶的棒间距,结果显示随着转速增大或径向距离增大,共晶的间距增大,这与Junze等的实验结果相符合.     

SOA nonlinearities in 4 × 25 Gb/s WDM pre-amplified system for 100-Gb/s Ethernet

A simulation analysis of the impact that the nonlinear response of a semiconductor optical amplifier (SOA) has in a four-channel WDM pre-amplified transmission system is presented in the framework of the recently proposed extended-reach (40-km, 4 × 25 Gb/s) 100 Gb Ethernet link. Channel spacing values ranging from 200 to 800 GHz, and fiber losses between 0 and −20 dB are considered. A maximum power penalty of 4.5 dB is predicted for short fiber lengths and for the tightest channel plan. For short fiber lengths, the penalty drops by about 0.8 dB when moving from 400 to 800 GHz; whereas for long fiber lengths, the penalty increases by 0.2 dB, provided that an average dispersive fiber is utilized. The widely spaced channel plan then represents the best choice in terms of the analyzed physical effects to implement the next-generation 100 GbE link. Further, our numerical investigation includes a discrimination analysis that confirms cross-gain modulation as the main overall SOA nonlinear impairment in the analyzed architecture, and establishes ultra-fast carrier heating-induced FWM as responsible for the system performance difference observed as a function of channel spacing. The difference practically vanishes for fiber lengths above 30 km. Finally, the proposal of an equation that fits the simulated power spectrum density of the first-order four-wave mixing-generated product as a function of channel spacing is presented as an aid to validate our numerical results.     

Effects of vertical grid discretization in infrared transmission modeling

The vertical spacing of a discretization used to model transmission in the mid-infrared spectral range was investigated. The forward model employed in this study is a part of an algorithm used to retrieve trace gas profiles from high-resolution ground-based solar absorption Fourier transform infrared (FTIR) spectra, however, the results have general applicability. A finely spaced retrieval grid was constructed and made progressively more sparse in the troposphere and in the stratosphere. The effect was quantified in terms of transmission differences with respect to the most fine discretization for a suite of molecules (H₂O, O₃, CO, CO₂, CH₄, N₂O, NO, NO₂, HCl, HF, HNO₃, ClONO₂, and N₂) in microwindows commonly used in FTIR spectroscopy. Systematic differences in modeled transmissions are apparent when coarser grid schemes are used for all species and microwindows, though some are below random noise levels typical of spectra recorded at Toronto. The most significant are H₂O and O₃ at 0.30-0.73% and 0.10-0.34%, respectively. CO (0.13%), ClONO₂ (0.84%), and HF (1.03%) are also influenced by the interference of H₂O, which is sensitive to temperature interpolation errors via the lower state energy of the particular H₂O transition. O₃ is a significant interference in CO (0.42%) and ClONO₂ (0.31%) microwindows, but its influence is felt primarily via interpolation errors in the O₃ number concentration profile introduced by the coarser grids. HCl and HF themselves show the next most significant response in transmission to coarser stratospheric grids (∼0.18%). Finally, considering transmission differences >0.1% as significant in typical measurements, we identify maximum tropospheric and stratospheric layer widths that still lead to negligible transmission errors as, respectively, 0.6 and 2.0 km. These numbers can vary depending on the band or transition of interest, the signal-to-noise ratio of the measurement and the use of significantly different a priori volume mixing ratio profiles.     

惯导速度辅助下GNSS高精度定位

传统的卫星导航接收机无法同时适应高动态和高精度要求。对于10g以上的加速度,高精度接收机很难达到高精度的指标,甚至基带环路失锁无法正常导航定位。针对GNSS动态条件下高精度定位需求,引入惯性/卫星深组合导航技术,在应用惯性信息辅助接收机减小基带跟踪环路带宽基础上,采用码片窄相关方法降低伪距抖动误差,提高动态条件下GNSS伪距定位精度。仿真结果表明:通过惯性信息辅助跟踪环路可实现较小跟踪环路带宽下的稳定跟踪;在此基础上,通过码片窄相关方法并提高射频前端带宽可实现定位精度的提高。对比传统的伪距定位方法,定位精度(1?)从6 m提高到3 m左右。     

热屏间距对泡生法蓝宝石单晶生长影响研究

太空、军事和科研等高科技领域的持续发展极大促进了对蓝宝石晶体的需求,泡生法是蓝宝石晶体的主要制造方法之一;热场结构对所得蓝宝石晶体的质量具有重要影响.本文对采用泡生法工艺制造蓝宝石单晶过程中,具有内置7层氧化锆外置8层钼金属的新型热屏结构间距进行研究.通过数值模拟考察热屏间距对单晶炉功率、固-液界面形状和晶体热应力的影响确定了合理的热场结构;并与试验生产结果进行对比验证.结果表明:热屏间距增大使得单晶炉功率明显提升,并引起固-液界面凸度增大;而蓝宝石晶体热应力出现减小.综合考察三个影响因素的影响,最后确定热屏间距为5 mm时单晶炉能耗较低,可用于制造高质量的蓝宝石晶体.     

能谱涨落统计特征稳定性分析

通过引入权重,并用一能级数等于简并谱的无趋向性序列为标准去衡量 简并邻间距谱的趋向性,由此建立分析简并谱涨落统计特征稳定性的MKS无参量试验法;根 据该方法,具体分析、比较了H2O分子低激发态与高激发态振动能谱涨落统计特征,找出 了从低激发态向高激发态过度时涨落统计特征明显改变点。     

EFFECT OF Z-PINS＇ DIAMETER, SPACING AND OVERLAP LENGTH ON CONNECTING PERFORMANCE OF CMC SINGLE LAP JOINT

The effect of through-thickness reinforcement by composite pins （Z-pins） on the static tensile strength and failure mechanisms of the joints made from ceramic matrix composite （CMC） is investigated. Overlap length of the single lap joint is 15 mm, 20 mm, 23 mm, 37 mm, and 60 mm, respectively. The experimental results indicate that the final failure modes of the joints can be divided into two groups, （a） the bond-line stops debonding until crack encounters Z-pins; and then the adherends break at the location of Z-pins, when overlap length is more than 20 mm; （b） the bond-line detaches entirely and Z-pins are drawn from adherends, when overlap length is equal to 15 mm. A simple efficient computational approach is presented for analyzing the benefit of through-thickness pins for restricting failure in the single lap joints. Here, the mechanics problem is simplified by representing the effect of the pins by tractions acting on the fracture surfaces of the cracked bond-line. The tractions are prescribed as functions of the crack displacement, which are available in simple forms that summarize the complex deformations to a reasonable accuracy. The resulting model can be used to track the evolution of complete failure mechanisms, for example, bond-line initial delamination and ultimate failure associated with Z-pin pullout, ultimate failure of the adherends. The paper simulates connecting performance of the single lap joints with different Z-pins＇ diameter, spacing and overlap length; the numerical results agree with the experimental results; the numerical results indicate enlarging diameter and decreasing spacing of Z-pins are in favor of improving the connecting performance of the joints. By numerical analysis method, the critical overlap length that lies between two final failure modes is between 18 mm and 19 mm, when Z-pins＇ diameter and spacing are 0.4 mm, 5 mm, respectively.