Characteristics of nanosized ruthenium metal by chemical reduction method

Nano-sized Ru metals have been prepared by the chemical reduction of ruthenium chloride and ruthenium hydroxide. Sodium borohydride was used as a reducing agent. The samples have been characterized by elemental analysis, X-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The preparation method greatly affects the composition and surface area of the material. All the samples show nanosized particles. However, samples prepared by reduction of ruthenium hydroxide had a lower surface area and larger particle size than those prepared by reduction of ruthenium chloride. Residual amount of boron was present in the samples. The samples demonstrate amorphous structure.     

Bidendriform bialgebras, trees, and free quasi-symmetric functions

We introduce bidendriform bialgebras, which are bialgebras such that both product and coproduct can be split into two parts satisfying good compatibilities. For example, the Malvenuto-Reutenauer Hopf algebra and the non-commutative Connes-Kreimer Hopf algebras of planar decorated rooted trees are bidendriform bialgebras. We prove that all connected bidendriform bialgebras are generated by their primitive elements as a dendriform algebra (bidendriform Milnor-Moore theorem) and then is isomorphic to a Connes-Kreimer Hopf algebra. As a corollary, the Hopf algebra of Malvenuto-Reutenauer is isomorphic to the Connes-Kreimer Hopf algebra of planar rooted trees decorated by a certain set. We deduce that the Lie algebra of its primitive elements is free in characteristic zero (G. Duchamp, F. Hivert and J.-Y. Thibon conjecture).     

Ordered OLPS and CF Nth numerators

Definitions, theorems and examples are established for a general model of Laurent polynomial spaces and ordered orthogonal Laurent polynomial sequences, ordered with respect to ordered bases and orthogonal with respect to inner products ·=L°⊙ decomposed into transition functional ⊙ and strong moment functional, or, more generally, sample functional L couplings. Under this formulation that is shown to subsume those in the existing literature, new fundamental results are produced, including necessary and sufficient conditions for ordered OLPS to be sequences of nth numerators of continued fractions, in contrast to the classical result concerning nth denominators which is shown to hold only in special cases.     

A Fubini theorem

Let I₀ be the σ-ideal of subsets of a Polish group generated by Borel sets which have perfectly many pairwise disjoint translates. We prove that a Fubini-type theorem holds between I₀ and the σ-ideals of Haar measure zero sets and of meager sets. We use this result to give a simple proof of a generalization of a theorem of Balcerzak-Ros?anowski-Shelah stating that I₀ on N² strongly violates the countable chain condition.     

Invariant measures and regularity properties of perturbed Ornstein-Uhlenbeck semigroups

This paper deals with perturbations of the Ornstein-Uhlenbeck operator on L²-spaces with respect to a Gaussian measure μ. We perturb the generator of the Ornstein-Uhlenbeck semigroup by a certain unbounded, non-linear drift, and show various properties of the perturbed semigroup such as compactness and positivity. Strong Feller property, existence and uniqueness of an invariant measure are discussed as well.     

On Genuine Bernstein–Durrmeyer Operators

We continue the studies on the so–called genuine Bernstein–Durrmeyer operators U _n by establishing a recurrence formula for the moments and by investigating the semigroup T(t) approximated by U _n . Moreover, for sufficiently smooth functions the degree of this convergence is estimated. We also determine the eigenstructure of U _n , compute the moments of T(t) and establish asymptotic formulas. Received: January 26, 2007.     

The essential Lagrangian-Grassmannian and the homotopy type of the Fredholm Lagrangian-Grassmannian

Let H be a separable infinite dimensional Hilbert space endowed with a symplectic structure and let L₀⊂H be a Lagrangian subspace. Using the results of [A. Abbondandolo, P. Majer, Infinite dimensional Grassmannians, math.AT/0307192], we show that the Fredholm Lagrangian-Grassmannian FL₀(Λ) has the homotopy type of Gc(L₀), the Grassmannian of all Lagrangian subspaces of H that are compact perturbations of L₀. It is well known that the latter has the homotopy type of the quotient U(∞)/O(∞). As a corollary, we recover a result by B. Booss-Bavnbek and K. Furutani (see [B. Booss-Bavnbek, K. Furutani, Symplectic functional analysis and spectral invariants, Contemp. Math. 242 (1999) 53-83; K. Furutani, Fredholm-Lagrangian-Grassmannian and the Maslov index, J. Geom. Phys. 51 (2004) 269-331]) that the L₀-Maslov index is an isomorphism between the fundamental group of FL₀(Λ) and the integers.     

Some geometrical aspects of semidefinite linear complementarity problems

This article studies some geometrical aspects of the semidefinite linear complementarity problem (SDLCP), which can be viewed as a generalization of the well-known linear complementarity problem (LCP). SDLCP is a special case of a complementarity problem over a closed convex cone, where the cone considered is the closed convex cone of positive semidefinite matrices. It arises naturally in the unified formulation of a pair of primal-dual semidefinite programming problems. In this article, we introduce the notion of complementary cones in the semidefinite setting using the faces of the cone of positive semidefinite matrices and show that unlike complementary cones induced by an LCP, semidefinite complementary cones need not be closed. However, under R₀-property of the linear transformation, closedness of all the semidefinite complementary cones induced by L is ensured. We also introduce the notion of a principal subtransformation with respect to a face of the cone of positive semidefinite matrices and show that for a self-adjoint linear transformation, strict copositivity is equivalent to strict semimonotonicity of each principal subtransformation. Besides the above, various other solution properties of SDLCP will be interpreted and studied geometrically.     

The way of Diophantus: Some clarifications on Diophantus' method of solution

In the introduction of the Arithmetica Diophantus says that in order to solve arithmetical problems one has to “follow the way he (Diophantus) will show.” The present paper has a threefold objective. Firstly, the meaning of this sentence is discussed, the conclusion being that Diophantus had elaborated a program for handling various arithmetical problems. Secondly, it is claimed that what is analyzed in the introduction is definitions of several terms, the exhibition of their symbolism, the way one may operate with them, but, most significantly, the main stages of the program itself. And thirdly, it is argued that Diophantus' intention in the Arithmetica is to show the way the stages of his program should be practically applied in various arithmetical problems.     

The Sheffer group and the Riordan group

We define the Sheffer group of all Sheffer-type polynomials and prove the isomorphism between the Sheffer group and the Riordan group. An equivalence of the Riordan array pair and generalized Stirling number pair is also presented. Finally, we discuss a higher dimensional extension of Riordan array pairs.