准周期链状聚合物电子谱及特征

研究了链状聚合物的长短键结构呈准周期排列的电子谱。利用紧束缚近似和转移矩阵方法通过理论证明和计算表明：这种准周期排列聚合物的电子谱,当长短键长度相差很小时,具有类似于金属晶体的能带结构;相差很大时,具有无序系统一维能级结构;而对于一般情形,其电子谱与上两者均异,形成所谓的类Cantor集。这3类不同的谱结构反映在链状聚合物的宏观物理性质上也将有所不同,它无疑会影响聚合物的稳定性及相关(超)导电性能,深入研究这方面问题将有助于对有机超导的认识。     

Effects of confinement on static and dynamical properties of water

Molecular-dynamics results on water confined in a silica pore are reviewed and discussed in connection with experiments performed on water in Vycor and with studies of water in contact with proteins. The properties of confined water are studied as a function of both temperature and hydration level. The interaction of water in the film close to the substrate with the silica atoms induces a strong distortion of the hydrogen bond network. At high hydration levels a double dynamical regime is observed. At low hydration an anomalous diffusion is found upon supercooling with a transition from a Brownian to a non-Brownian regime on approaching the substrate in agreement with results found in studies of water in contact with globular proteins.Received: 1 January 2003, Published online: 14 October 2003PACS: 61.20.-p Structure of liquids - 61.20.Ja Computer simulation of liquid structure     

Intersection Local Times of Independent Brownian Motions as Generalized White Noise Functionals

A 'chaos expansion' of the intersection local time functional of two independent Brownian motions in R ^d is given. The expansion is in terms of normal products of white noise (corresponding to multiple Wiener integrals). As a consequence of the local structure of the normal products, the kernel functions in the expansion are explicitly given and exhibit clearly the dimension dependent singularities of the local time functional. Their L ^p -properties are discussed. An important tool for deriving the chaos expansion is a computation of the 'S-transform' of the corresponding regularized intersection local times and a control about their singular limit.     

掺杂偶氮化合物的PMMA光折变聚合物的拉曼光谱分析

光折变聚合物具有良好的光折变效应,采用以惰性聚合物PMMA为基体,掺杂偶氮化合物染料的光折变聚合物具有较好的光学非线性和稳定性。文章主要介绍使用激光拉曼光谱仪对合成聚合物的各单体和聚合物薄膜进行拉曼光谱扫描,对比分析各个单体成分的特征谱峰与聚合物薄膜特征谱峰,肯定了实验中得到的光折变聚合物薄膜与理论上要求得到的一致性。     

Photoluminescence and optical absorption properties of polymer modified carbon nanotubes

Polymethyl methacrylate modified carbon nanotubes were prepared using γ radiation, and the modified carbon nanotubes exhibited strong luminescence (∼ ∼568 nm) at room temperature and an absorption peak at ∼ ∼247 nm can be observed in the polymer modified samples.     

Laser synthesis of nanostructured ceramics from liquid precursors

The free-form net shape laser synthesis of nanostructured ceramics from liquid precursors enables a residual stress-free production of high temperature resistant ceramic units and components for the use in microsystem engineering. Due to the use of molecular compounded liquid, ceramic precursors the resulting ceramic components show outstanding properties, for example high purity and a nanostructured material design.The use of pulsed lasers enables a defined input of energy required to pyrolyse the precursor material into a crystalline ceramic, so the active volume can be reduced significantly compared to other processes, for example pyrolysis by furnace.In this paper several methods for a further minimization of the active volume are presented. The investigations determined different factors affecting the process. Realizing selective experiments allows a determination of their influencing level and the definition of a working area to produce three-dimensional components with high aspect ratio.By several studies, e.g., scanning electron microscopy, transmission electron microscopy as well as X-ray diffraction analysis, the atomic structure and composition of the created components were analyzed and valued, so the different reaction processes can be described extensively.     

IR laser ablation of doped poly(methyl methacrylate)

We investigate the TEA CO₂ laser ablation of films of poly(methyl methacrylate), PMMA, with average M_W 2.5, 120 and 996 kDa doped with photosensitive compounds iodo-naphthalene (NapI) and iodo-phenanthrene (PhenI) by examining the induced morphological and physicochemical modifications. The films casted on CaF₂ substrates were irradiated with a pulsed CO₂ laser (10P(20) line at 10.59 μm) in resonance with vibrational modes of PMMA and of the dopants at fluences up to 6 J/cm². Laser induced fluorescence probing of photoproducts in a pump and probe configuration is carried out at 266 nm. Formation of naphthalene (NapH) and phenanthrene (PhenH) is observed in NapI and PhenI doped PMMA, respectively, with relatively higher yields in high M_W polymer, in similarity with results obtained previously upon irradiation in the UV at 248 nm. Above threshold, formation of photoproducts is nearly complete after 200 ms. As established via optical microscopy, bubbles are formed in the irradiated areas with sizes that depend on polymer M_W and filaments are observed to be ejected out of the irradiated volume in the samples made with high M_W polymer. The implications of these results for the mechanisms of polymer IR laser ablation are discussed and compared with UV range studies.     

Matrix assisted pulsed laser evaporation of poly(d,l-lactide) thin films for controlled-release drug systems

We report the successful deposition of the porous polymer poly(d,l-lactide) by matrix assisted pulsed laser evaporation (MAPLE) using a KrF* excimer laser (248 nm, τ = 7 ns) operated at 2 Hz repetition rate. The chemical structure of the starting materials was preserved in the resulting thin films. Fluence played a key role in optimizing our depositions of the polymer. We demonstrated MAPLE was able to improve current approaches to grow high quality thin films of poly(d,l-lactide), including a porosity control highly required in targeted drug delivery.