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11.
The environment of Eu3+ in zinc-thallium-tellurite glass of the molar composition 60TeO2-30TlO0.5-9.9ZnO-0.1Eu2O3 was investigated by laser-induced fluorescence line narrowing (FLN) techniques using Eu3+ as a local site probe. From the site selective luminescence spectra of Eu3+ at 7 K, the energies of the Stark components of the 7F1 and 7F2 states were recorded and then the crystal field parameters Bnm were calculated assuming a C2v site symmetry. The ratios B22/B20 and B44/B40 for each excitation energy within 7F0-5D0 transition were obtained and compared with the values calculated for Eu3+ in other types of glasses. 相似文献
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Ranjan Sengupta 《Journal of voice》1990,4(2)
This article deals with a spectrographic analysis of the singer's formant as occurred during singing of the vowels /a/, /i/, and /o/ in North Indian classical vocal music. The resonance balance, center frequency, and band-width are shown as a function of fundamental frequency for eight singers.Two new parameters have been defined viz. asymmetry parameter (A) and spectral energy balance (W). Their variation with fundamental frequency is shown. 相似文献
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手性是自然界中普遍存在的有趣现象之一,在生命体中手性大分子特有的不对称结构在维持生命过程、新陈代谢和进化等面均起着决定性作用.受此启发,合成具有新型结构的光学活性聚合物,研究其独特的物理化学性质和功能已成为当今高分子领域研究的热点.左旋和右旋的圆偏振光已被广泛应用于氨基酸衍生物的不对称光合成、光分解和去消旋化反应,以及诱导含有偶氮苯或三苯胺等特定功能基团的超分子组装体或无机纳米粒子形成稳定螺旋结构.本文详细地介绍了圆偏振光辐照在手性聚合物合成与螺旋结构调控中的应用,初步揭示了圆偏振光的作用机制以及优势,归纳总结了已取得的研究进展,并对圆偏振光在手性聚合物合成与结构调控中的应用及发展进行了简单的评述和展望. 相似文献
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A novel convenient synthetic route for poly-functional 21-monothiatetraphenylporphyrins of the type A4 und AB3 having base labile substituents in meso position was developed. Using this method a series of symmetric and asymmetric 21-thiaporphyrins containing different functional groups at the meso position is reported. The new products were characterized by NMR, UV-Vis and mass spectroscopy. 相似文献
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《Journal of computational and graphical statistics》2013,22(2):405-419
Multidimensional scaling (MDS) is a set of techniques, used especially in behavioral and social sciences, that enable a researcher to visualize proximity data in a multidimensional space. This article focuses on a particular class of MDS models proposed to deal with proximities which describe asymmetric relationships (i.e., trade indices for a set of countries, brand switching data, occupational mobility tables, and so on). They are based on the decomposition of the relationships into a symmetric and a skew-symmetric part. In this way the objects are represented as points in a multidimensional space and the intensity of their relationships as scalar products (symmetry) or triangle areas (skew-symmetry). These models are seen as special cases of a general model and their rotational indeterminacy is investigated. The aim is to propose a rotation method that makes easier the visual inspection of the graphical representation, highlighting the simple structure of the data. In particular an orthomax-like family of rotation methods and a general algorithm are proposed. Advantages of the proposal are illustrated by analysis of import-export data. 相似文献
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Li Liu Michael I. Mishchenko W. Patrick Arnott 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(15):2656-2663
We employ the numerically exact superposition T-matrix method to perform extensive computations of scattering and absorption properties of soot aggregates with varying state of compactness and size. The fractal dimension, Df, is used to quantify the geometrical mass dispersion of the clusters. The optical properties of soot aggregates for a given fractal dimension are complex functions of the refractive index of the material m, the number of monomers NS, and the monomer radius a. It is shown that for smaller values of a, the absorption cross section tends to be relatively constant when Df<2 but increases rapidly when Df>2. However, a systematic reduction in light absorption with Df is observed for clusters with sufficiently large NS, m, and a. The scattering cross section and single-scattering albedo increase monotonically as fractals evolve from chain-like to more densely packed morphologies, which is a strong manifestation of the increasing importance of scattering interaction among spherules. Overall, the results for soot fractals differ profoundly from those calculated for the respective volume-equivalent soot spheres as well as for the respective external mixtures of soot monomers under the assumption that there are no electromagnetic interactions between the monomers. The climate-research implications of our results are discussed. 相似文献