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501.
New methylene blue (NMB) dye incorporated into AlMCM‐41 surfactant‐free and hybrid surfactant‐AlMCM‐41 mesophase. UV‐vis evidence shows that new methylene blue dye protonated in both cases of zeolites. New methylene blue is electroactive in zeolites and their electrochemical activity has been studied by cyclic voltammetry and compared to that of NMB in aqueous solutions. New methylene blue molecules are not released to the solution during CV measurements and are accessible to H3O+ ions. The presence of surfactant affects the kinetics of the redox process through proton ions diffusion. The midpoint potentials (Em) values show that new methylene blue dye incorporated into AlMCM‐41 can be reduced easily with respect to solution new methylene blue. New methylene blue interacting with surfactant polar heads and residual Br? ions as a results, it shows a couple of peaks in high potential with respect to new methylene blue solution. The electrode made with methylene blue‐AlMCM‐41 without surfactant was used for the mediated oxidation of ascorbic acid. The anodic peak current observed in cyclic voltammetry was linearly dependent on the ascorbic acid concentration. The calibration plot was linear over the ascorbic acid concentration range 1.0×10?5 to 5.0×10?4 M. The detection limit of the method is 1.0×10?5 M, low enough for trace ascorbic acid determination in various real samples. 相似文献
502.
《Electroanalysis》2004,16(20):1734-1738
A novel biosensor by electrochemical codeposited Pt‐Fe(III) nanocomposites and DNA film was constructed and applied to the detection of uric acid (UA) in the presence of high concentration of ascorbic acid (AA). Based on its strong catalytic activity toward the oxidation of UA and AA, the modified electrode resolved the overlapping voltammetric response of UA and AA into two well‐defined peaks with a large anodic peak difference (ΔEpa) of about 380mV. The catalytic peak current obtained from differential pulse voltammetry (DPV) was linearly dependent on the UA concentration from 3.8×10?6 to 1.6×10?4 M (r=0.9967) with coexistence of 5.0×10?4 M AA. The detection limit was 1.8×10?6 M (S/N=3) and the presence of 20 times higher concentration of AA did not interfere with the determination. The modified electrode shows good sensitivity, selectivity and stability. 相似文献
503.
《Electroanalysis》2004,16(8):684-687
In 0.05 mol/L phosphate buffer solution (pH 7.0), carbon nanotubes modified electrode exhibits rapid response, strong catalytic activity with high stability toward the electrochemical oxidation of catechol. The electrochemical behavior of catechol on both the multi‐walled and single‐walled carbon nanotubes modified electrode was investigated. The experimental conditions, such as pH of the solution and scan rate were optimized. The currents (measured by constant potential amperometry) increase linearly with the concentrations of catechol in the range of 2.0×10?5–1.2×10?3 mol/L. Moreover, at the multi‐walled carbon nanotubes modified electrode the electrochemical responses of catechol and ascorbic acid can be separated clearly. 相似文献
504.
Baozhen Wang 《Talanta》2007,72(2):415-418
Multilayer thin films composed of poly(allylamine hydrochloride) (PAH) and carboxymethyl cellulose (CMC) have been prepared on the surface of a gold (Au) disk electrode by a layer-by-layer deposition of PAH and CMC and ferricyanide ions ([Fe(CN)6]3−) were confined in the film. [Fe(CN)6]3− ions can be successfully confined in the films from weakly acidic or neutral [Fe(CN)6]3− solutions, while, in basic solution, [Fe(CN)6]3− ion was not confined. The [Fe(CN)6]3− ion-confined Au electrode showed clear redox peaks in the cyclic voltammogram around 0.35 V versus Ag/AgCl. The amounts of [Fe(CN)6]3− ions confined in the films depended on the thickness of the films or the number of layers in the LbL films. The [Fe(CN)6]3− ion-confined Au electrode was used for electrocatalytic determination of ascorbic acid in the concentration range of 1-50 mM. 相似文献
505.
A glassy carbon electrode (GCE) was modified with electropolymerized films of isonicotinic acid in pH 5.6 phosphate buffer solution (PBS) by cyclic voltammetry (CV). The modified electrode showed an excellent electrocatalytical effect on the oxidation of norepinephrine (NE). In PBS of pH 7.4, the oxidation current increased linearly with two concentration intervals of NE, one is 4.0×10−7 to 1.0×10−5 M, the other is 1.0×10−5 to 2.0×10−4 M. The detection limit (S/N=3) obtained by DPV was 6.0×10−9 M. Then the modified electrode was used to determine NE in an excess of ascorbic acid (AA) by difference pulse voltammetry. The peak potentials recorded in a PBS of pH 7.4 were −68 and +111 mV versus SCE for AA and NE, respectively. The high selectivity and sensitivity for NE was found to be due to the very distinct attracting interaction between NE cations and the negtively charged poly(isonicotinic acid) film in pH 7.4 PBS. The proposed method exhibited good recovery and reproducibility. 相似文献
506.
Exploiting micellar environment for simultaneous electrochemical determination of ascorbic acid and dopamine 总被引:1,自引:0,他引:1
A simple and reliable method for simultaneous electrochemical determination of ascorbic acid (AA) and dopamine (DA) is presented in this work. It was based on the use of the cationic surfactant cetylpyridinium chloride (CPC) that enables the separation of the oxidation peaks potential of AA and DA. Cyclic voltammetry (CV) as well as pulse differential voltammetry (PDV) were used in order to verify the voltammetric behaviour in micellar media. In the cationic surfactant CPC, a remarkable electrostatic interaction is established with negatively charged AA, as a consequence, the oxidation peak potential shifted toward less positive potential and the peak current increased. On the other hand, the positively charged DA is repelled from the electrode surface and the oxidation peak potential shifts toward more positive potential in comparison to the bare electrode. Therefore, the common overlapped oxidation peaks of AA and DA can be circumventing by using CPC. Parameter that affects the Epa and Ipa such as CPC concentration and pH were studied. Under optimised conditions, the method presented a linear response to AA and DA in the concentration range from 5 to 75 μmol L−1 and 10 to 100 μmol L−1, respectively. The proposed method was successfully applied to the simultaneous determination of AA and DA in dopamine hydrochloride injection (DHI) samples spiked with AA. 相似文献
507.
聚苯胺薄膜修饰电极对抗坏血酸的电催化氧化 总被引:12,自引:0,他引:12
本文表明聚苯胺(PAn)薄膜修饰电极对水溶液中的抗坏血酸(AH_2)在较宽的pH范围和较宽的浓度范围内均有良好的电催化氧化作用, 为EC平行催化过程。利用旋转圆盘电极(RDE)进行了催化过程动力学分析, 求出了催化反应动力学参数。在抗坏血酸浓度10~(-2)~10~(-6) mol·L~(-1)范围内, 催化峰电流与AH_2浓度均成良好的线性关系, 且PAn薄膜修饰电极具有很好的稳定性, 有应用分析抗坏血酸的意义。 相似文献
508.
Lei Qian Xiurong Yang 《Colloids and surfaces. A, Physicochemical and engineering aspects》2005,260(1-3):79-85
Ag(Au) bimetallic core–shell nanoparticles were prepared by a new seed growth method. Ascorbic acid was used to reduce the complex of HAuCl4 and hexadecyltrimethylammoniumbromide (CTAB). This resulted in the forming of colorless Au(I) (AuCl2−). It was used as the growth solution to prepare these bimetallic core–shell nanoparticles. These nanoparticles were characterized by UV–vis spectroscopy, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results showed these nanoparticles exhibited core–shell shape and there was large amount of Ag in the shell. These nanoparticles could be produced in a few minutes without violent stirring and the method was easy and convenient compared with others. The effect of amount of AuCl2− on the shape of nanoparticles was also studied. Many small gold nanoparticles were formed on the surface of bimetallic core–shell nanoparticles in the presence of excess AuCl2−. The mechanisms were also proposed to explain the process of colloidal preparation. 相似文献
509.
510.
抗坏血酸的催化动力学光度法测定 总被引:7,自引:0,他引:7
建立了一种测定抗坏血酸的方便、快速、高灵敏度的催化动力学光度法。对氨基苯磺酸与亚硝酸根进行重氮化反应生成重氮盐,抗坏血酸对重氮盐的分解有催化作用。利用加入8-羟基喹啉与该重氮盐反应生成偶氮染料来终止反应。在波长495nm处,用1cm比色皿以水作参比测定其吸光度,最佳测定酸度为pH9.0。吸光度与空白体系的差值△A与抗坏血酸的质量浓度呈线性关系。该法测定抗坏血酸的线性范围为0.16-6.3mg/L,检出限为0.005mg/L。利用该法测定了维生素C片剂及荔枝晶中的抗坏血酸含量,并与碘量法进行对照,结果基本吻合。 相似文献