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71.
72.
C. Aguzzoli E. K. Tentardini C. A. Figueroa C. Kwietniewski L. Miotti I. J. R. Baumvol 《Applied Physics A: Materials Science & Processing》2009,94(2):263-269
Transport of N, O, and Ti during dc magnetron sputtering deposition of nanoscopic TiN/Ti and TiN structures on plasma nitrided
M2 tool steel, as well as transport of metallic species composing the plasma nitrided steel substrates were investigated.
N and O depth distributions were determined with subnanometric resolution using narrow resonant nuclear reaction profiling,
whereas Ti was profiled, also with subnanometric depth resolution, by medium energy ion scattering. The surface elementary
compositions of the TiN/Ti/nitrided steel and TiN/nitrided steel structures were determined by low energy ion scattering.
The chemical compounds formed during deposition were accessed by X-ray photoelectron spectroscopy, indicating the presence
of TiN, TiO2, Ti oxynitrides, as well as other metallic nitrides and oxynitrides, but no metallic Ti was observed. Owing to the observed
intensive atom mobility, the compositions of the deposited films on plasma nitrided steel structures varied continuously on
a nanoscopic scale, from the core of the steel substrate to the bulk of the stoichiometric TiN films. The Ti interlayer assists
interdiffusion of all species, in contrast to the TiN film layer, which is known to be a diffusion barrier. The improved adhesion
of TiN hard coatings to plasma nitrided steel under working conditions is discussed in terms of the gradual compositional
change around the interfaces and the atomic mobility during their formation. 相似文献
73.
First-principles study of structrural and corrected band properties of wurtzite Zn1-xCdxO and Zn1-xMgxO systems 下载免费PDF全文
A first-principles method based on density functional theory(DFT),a generalized gradient approximation(GGA),and a projector-augmented wave(PAW) are used to study the structual and band properties of wurtzite Zn1-xCdxO and Zn1-xMgxO(0 ≤x≤1) ternary alloys.By taking into account all of the possible structures,the band gaps of Zn1-xCdxO and Zn1-xMgxO alloys are corrected and compared with experimental data. 相似文献
74.
In [A.L. Carey, J. Phillips, A. Rennie, Twisted cyclic theory and an index theory for the gauge invariant KMS state on Cuntz algebras. arXiv:0801.4605], we presented a K-theoretic approach to finding invariants of algebras with no non-trivial traces. This paper presents a new example that is more typical of the generic situation. This is the case of an algebra that admits only non-faithful traces, namely SUq(2) and also KMS states. Our main results are index theorems (which calculate spectral flow), one using ordinary cyclic cohomology and the other using twisted cyclic cohomology, where the twisting comes from the generator of the modular group of the Haar state. In contrast to the Cuntz algebras studied in [A.L. Carey, J. Phillips, A. Rennie, Twisted cyclic theory and an index theory for the gauge invariant KMS state on Cuntz algebras. arXiv:0801.4605], the computations are considerably more complex and interesting, because there are non-trivial ‘eta’ contributions to this index. 相似文献
75.
Sie-Tiong Ha Teck-Ming Koh Guan-Yeow Yeap Hong-Cheu Lin Siew-Ling Lee Yip-Foo Win 《Phase Transitions》2013,86(3):195-204
A series of new rod-shaped mesomorphic compounds, 6-ethoxy-2-(4-alkanoyloxybenzylidenamino)benzothiazoles, consisting of a 2,6-disubstituted benzothiazole core and a Schiff base central linkage, were synthesized and their structures were ascertained via elemental analysis and spectroscopic techniques. Their mesomorphic properties were studied using differential scanning calorimetry (DSC), polarized optical microscopy (POM) and X-ray diffraction (XRD) analysis. All compounds showed enantiotropic mesomorphism. Whilst the lower members of the series, hexanoyloxy and octanoyloxy derivatives exhibited nematic phase, the higher members (decanoyloxy, dodecanoyloxy, tetradecanoyloxy, hexadecanoyloxy and octadecanoyloxy derivatives) exhibited nematic and smectic C phases. 相似文献
76.
ABSTRACTThis work presents an electro-optic effect-based design for the widely used Hamming code for checking single bit errors in the received data. The structure is based on Mach-Zehnder Interferometer, designed using Titanium-diffused Lithium Niobate-based waveguides. The proposed device has been successfully tested using the beam propagation method. For a received 7-bit code, the three simultaneously generated check bits are combined to check the error position. Critical performance parameters like extinction ratio (24.39dB), contrast ratio (25.711dB), insertion loss (0.041dB), and amplitude modulation (0.079dB) calculated for the overall device are within acceptable limits for the feasibility of the device. 相似文献
77.
《Composite Interfaces》2013,20(8-9):787-803
Poly(amide)-6/clay nanocomposites are investigated by means of modulated temperature differential scanning calorimetry. The importance of polymer–filler interaction is explored by comparing nanocomposites based on untreated and organically modified clay. During quasi-isothermal crystallization experiments, an excess contribution is observed in the recorded heat capacity signal due to reversible melting and crystallization. The magnitude of this excess contribution depends on the nanocomposite investigated. We suggest that it is directly related to the segmental mobility of the polymer chains in the interphase region. As such, the magnitude of this excess contribution can be used to quantify the efficiency of the polymer–clay interaction. Depending on the clay type used, differences in interfacial interaction can be achieved, which is of great importance with respect to the improvement of material properties. Based on thermal analysis results, a simple interphase model is proposed that is able to account for both the thermal and mechanical properties of poly(amide)-6/clay nanocomposites. 相似文献
78.
79.
Fluid and plastic flow dynamics of the critical state for a strongly pinned 2D superconductor 总被引:2,自引:0,他引:2
D. Monier L. Fruchter 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,17(2):201-205
The frequency of the Raman active A1g radial breathing mode has been widely used as a tool to estimate the distribution of diameters of single wall carbon nanotubes
(SWNT). However, the relation between frequency and diameter is not straightforward and results are model-dependent. Because
most of the experiments are performed on bundles and not on isolated tubes, the model should especially take into account
the van der Waals intertube interactions. Here, we use a pair-potential approach to account for such interactions and we derive
a nonlinear relation between the SWNT diameter and the frequency of the A1g radial breathing modes. We demonstrate a good agreement between calculations and the diameters derived from diffraction experiments
on the same samples.
Received 22 December 1999 and Received in final form 17 July 2000 相似文献
80.
E. Chappel M.D. Núñez-Regueiro G. Chouteau O. Isnard C. Darie 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,17(4):615-622
NaNiO2 has been studied by neutron-powder diffraction, magnetic susceptibility and submillimeter wave ESR. The monoclinic structure
at room temperature is characterised by a ferrodistorsive orbital ordering due to the Jahn-Teller (JT) effect of the Ni3+ ions in the low spin state. NaNiO2 undergoes a structural transition at around 480 K, above which the orbital ordering disappears. The high temperature phase
is rhombohedral with the layered -NaFeO2 structure ( space group). The magnetic susceptibility exhibits hysteresis and we observe a change of the Curie-Weiss law parameters above
the JT transition. The anisotropy of the g-factor at 200 K can be attributed to the JT effect which favours the orbital occupation. Finally, the interplay between the magnetic and structural properties of NaNiO2 and Li1-xNi1+xO2 is discussed.
Received 29 May 2000 相似文献